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    PROCESSES AND CATAYLSTS FOR THE SELECTIVE HYDROGENATION OF COMPOUNDS HAVING CARBONYL CARBON ATOMS
    4.
    发明申请
    PROCESSES AND CATAYLSTS FOR THE SELECTIVE HYDROGENATION OF COMPOUNDS HAVING CARBONYL CARBON ATOMS 有权

    公开(公告)号：US20220064136A1

    公开(公告)日：2022-03-03

    申请号：US17421492

    申请日：2020-01-09

    申请人： Archer Daniels Midland Company

    发明人： James Brazdil ,  Chi-Cheng Ma

    IPC分类号： C07D307/42 ,  B01D3/40 ,  C07C45/64

    摘要： Selective hydrogenation processes are disclosed that can upgrade impure feeds, such as those obtained from biomass and containing a number of small (e.g., 2-6 carbon atom) molecules having aldehyde and/or ketone carbon atoms. For example, whereas glycolaldehyde and its methylated derivative, hydroxyacetone (acetol) are both high value intermediates for certain downstream processing reactions, they are normally recovered in a condensate from pyrolysis of carbohydrates (e.g., aldose-containing sugars) together with glyoxal and its methylated derivative, pyruvaldehyde. The selective hydrogenation of these compounds bearing two carbonyl carbon atoms, without over-hydrogenation to ethylene glycol and propylene glycol, can increase the concentration of the desired intermediates. These beneficial effects of selective hydrogenation may be achieved through the use of a hydrogenation catalyst comprising noble metals such as Ru and Pt.

    DIETARY FIBER PRODUCTION USING A GLYCOSYL-TRANSFERASE
    6.
    发明申请
    DIETARY FIBER PRODUCTION USING A GLYCOSYL-TRANSFERASE 有权

    公开(公告)号：US20210403967A1

    公开(公告)日：2021-12-30

    申请号：US17280852

    申请日：2019-09-27

    申请人： Archer Daniels Midland Company

    发明人： Wu-Li Bao ,  Leif Solheim

    IPC分类号： C12P19/18 ,  A23L29/30 ,  A23L33/21 ,  A23L33/125 ,  C12N9/10

    摘要： Methods are disclosed for the production of soluble dietary fiber from a starch, including, e.g., corn and wheat starch. The methods comprise adding an acid to a soluble starch, mixing and heating the starch to form a starch substrate, and placing the starch substrate in contact with a glycosyl-transferase, thus producing a soluble dietary fiber composition having a higher a higher soluble dietary content than a composition without the addition of the glycosyl-transferase.

    PROCESS FOR SEPARATION AND PURIFICATION OF A DICARBOXYLIC ACID CONTAINING MIXTURE
    8.
    发明申请
    PROCESS FOR SEPARATION AND PURIFICATION OF A DICARBOXYLIC ACID CONTAINING MIXTURE 有权

    公开(公告)号：US20210147332A1

    公开(公告)日：2021-05-20

    申请号：US16623535

    申请日：2018-06-20

    申请人： Archer Daniels Midland Company

    发明人： Pam Anklam ,  William Chris Hoffman ,  Mitchell Schultz ,  John G. Soper

    IPC分类号： C07C51/47 ,  B01D15/36

    摘要： A method is provided for separating a dicarboxylic acid product from a mixture containing such dicarboxylic acids. The method involves: providing a dicarboxylic acid-containing mixture of which at least 35% of the carboxylic acid content of the mixture is a dicarboxylic acid product of interest; running an extraction of said dicarboxylic acid-containing mixture through a chromatographic column configured with an amphoteric resin, such that the dicarboxylic acid product elutes preferentially from the dicarboxylic acid-containing mixture. In certain embodiments, the dicarboxylic acid product of interest can be a glucaric or gluconic acid product from a mixture of either or both of these with still other carboxylic acids.