摘要:
In various embodiments, rapid, sensitive detection of molecular hydrogen is achieved by chemically converting hydrogen to water vapor and then detecting the water vapor as a surrogate for the hydrogen. Detection may be enhanced by dampening variation in ambient water vapor and rapidly actively modulating a hydrogen-derived water vapor component. For example, the detector may receive sample gas that includes ambient water vapor and hydrogen, dry the sample gas to dampen variation in the ambient water vapor, divide the sample gas into a chemical conversion flow and a bypass flow, chemically convert hydrogen in the chemical conversion flow to water vapor, alternate between measuring water vapor in the converted chemical conversion flow or the bypass flow to produce a water vapor signal, separate the water vapor signal in the time domain to extract a hydrogen-derived water vapor signal, and output a hydrogen signal based on the hydrogen-derived water vapor signal.
摘要:
In various embodiments, rapid, sensitive detection of molecular hydrogen is achieved by receiving sample gas that includes ambient water vapor and hydrogen, passing the sample gas through a gas dryer, chemically converting hydrogen in the sample gas to water vapor to produce converted sample gas, measuring water vapor in the converted sample gas to produce a water vapor signal, separating the water vapor signal in the time domain into an ambient water vapor signal and a hydrogen-derived water vapor signal, wherein the gas dryer dampens variation in the ambient water vapor signal, and outputting a hydrogen signal that describes molecular hydrogen in the sample gas that is based on the hydrogen-derived water vapor signal.
摘要:
Coherent light such as a laser beam is spatially modulated by causing it to interact at a photosensitive material such as a crystal with a focussed image of non-coherent light. An electric potential is applied to the crystal either transversely to the direction of the light or in line with the direction of the light according to either the Kerr effect or the Pockels effect. Typical crystals include Bismuth-silicon-oxide and strontium-barium-niobate.
摘要:
Methods and apparatus are disclosed for studying motion of an object or element, to determine not only quantities of motion but also direction of motion. A laser beam or the like is circularly polarized and directed to two or more retroreflectors and then to a detector. Beams of different frequencies are established and determination of relative direction of motion of the retroreflectors is made from the increase or decrease of frequency of beats of one beam against the other. In one embodiment, left and right circularly polarized light is reflected, and one of the beams is frequency-shifted. The light, being circularly polarized, is insensitive to rotational orientation of the test object, while maintaining directional and motion information.
摘要:
In various embodiments, both very high speed and very high sensitivity hydrogen detection is achieved by controlling water vapor concentration over the catalyst used to convert hydrogen in sample gas (e.g., ambient air) to water vapor, to provide a substantially stable water vapor mixing level at a target mixing ratio. The naturally-occurring water vapor in the sample gas, without further steps, typically would vary over time within a wide range (e.g., due to changing atmospheric conditions). By controlling a level of water vapor over the catalyst to be substantially equal to a target mixing ratio that is not too low as to impair response time, and not too high as to impair sensitivity, both very high speed and very high sensitivity can be provided.
摘要:
In one embodiment, a photoacoustic effect measurement instrument for measuring a species (e.g., a species of PM) in a gas employs a pair of differential acoustic cells including a sample cell that receives sample gas including the species, and a reference cell that receives a filtered version of the sample gas from which the species has been substantially removed. An excitation light source provides an amplitude modulated beam to each of the acoustic cells. An array of multiple microphones is mounted to each of the differential acoustic cells, and measures an acoustic wave generated in the respective acoustic cell by absorption of light by sample gas therein to produce a respective signal. The microphones are isolated from sample gas internal to the acoustic cell by a film. A preamplifier determines a differential signal and a controller calculates concentration of the species based on the differential signal.
摘要:
In one embodiment, an apparent equilibrium constant involving a clumped isotope in a gaseous sample is measured by acquiring sample spectra of portions of the gaseous sample at different pressures. An external bulb coupled to a sample cell is filled with the gaseous sample. A first portion of the gaseous sample is transferred from the external bulb to the sample cell, where it is at a first pressure. A first sample spectrum is obtained. Then, a second portion of the gaseous sample is transferred from the external bulb to the sample cell, where it is at a second, different pressure. A second sample spectrum is obtained. An apparent equilibrium constant for the clumped isotope is calculated by determining a first isotopic ratio at the first pressure, determining a second isotopic ratio at the second pressure, and taking a product of the first isotopic ratio and the second isotopic ratio.
摘要:
In one embodiment, an improved multi-pass cell for a long path-length spectrometer is designed to include a perturbing mirror that causes a base pattern of reflections to be repeated multiple times, where each subsequent base pattern of reflections is rotated about the axis at an angle from a prior base pattern, to circulate the base patters about the cell. The base pattern may be a Herriott cell pattern. The improved multi-pass cell may be constructed with a concave front mirror centered along an axis of the cell, and a concave back mirror centered along the axis and facing the front mirror. The perturbing mirror may be centered along the axis, facing the front mirror and located at a perturbing mirror spacing in front of the back mirror or behind the back mirror, depending on the implementation.
摘要:
This invention overcomes the disadvantages of the prior art by providing a power generating system particularly suitable for field use in remote locations, which is fuel-efficient, relatively quiet, tolerant of dust, capable of operating on low-grade logistics and diesel-like fuels and capable of generating between 500 W and 2 KW of continuous electrical power. This generating system employs a two-cycle MICE generator having a piston that operates within a cylinder, and an interconnected, axially moving piston shaft that oscillates an alternator coil within a magnetic core. The piston shaft is attached to, and resisted by, the free end of a strong spring with a second, opposing end fixed to the MICE casing. To control operation of the MICE generator a clipper circuit is employed with a set threshold to resolve peaks and an adjustable harshness for applying load to the coil based upon an amps/volt harshness setting. The engine can also be controlled dynamically throughout the cycle using the added feedback from the proportional and integral elements of a PID controller in conjunction with an energy dissipating and/or storing circuit to load the coil. The dynamic control can be based on a switching power supply implementation. Various engine operating parameters can be derived from coil voltage, current and resistance, and used to control and/or monitor the engine's performance.
摘要:
A non-contact, extractive sampling system and method is provided for measuring the exhaust gas composition and fine particle composition of exhaust emissions of various types of vehicles under actual operating conditions. A portion (or sample) of an exhaust plume of a vehicle is pulled or extracted through an extraction sampling tube, via a vacuum pump, to a remote trace gas detection system where the concentration of one or more constituents present in the sample of exhaust plume may be measured. In this regard, the invention enables vehicle emissions measurements to be made at a location remote from roadway, rather than using known, “cross-path” remote emissions sensing systems.