公开(公告)号：US09363997B2

公开(公告)日：2016-06-14

申请号：US14681938

申请日：2015-04-08

申请人： Michael S. Harvey ,  Jonathan N. Howarth

发明人： Michael S. Harvey ,  Jonathan N. Howarth

IPC分类号： A61K31/19 ,  A01N37/16 ,  C11D3/39 ,  C11D11/00 ,  A01N59/00 ,  C11D3/395 ,  D06L3/02

CPC分类号： A01N37/16 ,  A01N37/12 ,  A01N59/00 ,  B01J19/24 ,  B01J2219/24 ,  C11D3/3947 ,  C11D3/3955 ,  C11D3/3956 ,  C11D11/0041 ,  D06L4/15 ,  A01N37/02 ,  A01N2300/00

摘要： Methods for the generation of non-equilibrium solutions of peroxyacetic acid are disclosed. These methods comprise introducing triacetin sad aqueous hydrogen peroxide to water, mixing, and then adding an aqueous source of an alkali metal or earth alkali metal hydroxide. Triacetin is converted rapidly and with a high conversion rate into peracetic acid. These methods produce solutions with a high level of peracetic acid.

摘要翻译： 公开了产生过氧乙酸的非平衡溶液的方法。 这些方法包括将三醋酸甘油难溶性过氧化氢引入水中，混合，然后加入碱金属或碱土金属氢氧化物的水源。 三醋酸甘油酯快速转化并以高转化率转化成过乙酸。 这些方法产生具有高水平过乙酸的溶液。

公开(公告)号：US08975219B2

公开(公告)日：2015-03-10

申请号：US13472526

申请日：2012-05-16

申请人： Margherita Scartozzi ,  Luca Sarcinelli ,  Sophie Anne Marguerite Goellner ,  Enza Ceccobelli ,  Leo Gagliardi

发明人： Margherita Scartozzi ,  Luca Sarcinelli ,  Sophie Anne Marguerite Goellner ,  Enza Ceccobelli ,  Leo Gagliardi

IPC分类号： C11D7/32 ,  C11D7/34 ,  C11D7/54 ,  C11D3/30 ,  D06L3/02 ,  C11D3/34 ,  C11D3/42 ,  C11D3/40

CPC分类号： C11D3/30 ,  C11D3/3481 ,  C11D3/349 ,  C11D3/3945 ,  C11D3/395 ,  C11D3/40 ,  C11D3/42 ,  C11D7/3209 ,  C11D7/34 ,  D06L4/12 ,  D06L4/13 ,  D06L4/15 ,  D06L4/614 ,  D06L4/686 ,  D06L4/75

摘要： A fabric cleaning composition comprising from 1% to 20% by weight of the fabric cleaning composition of an oxygen-based bleaching source and a hueing agent, and wherein the neat composition has a pH between 2.5 and 5.5, and a method of using said fabric cleaning composition.

摘要翻译： 一种织物清洁组合物，其包含1至20重量％的所述织物清洁组合物的氧基漂白源和调色剂，并且其中所述纯组合物的pH为2.5至5.5，以及使用所述织物的方法 清洁组合物。

公开(公告)号：US08962294B2

公开(公告)日：2015-02-24

申请号：US13657575

申请日：2012-10-22

申请人： E. I. du Pont de Nemours and Company

发明人： Robert Dicosimo ,  Mark Payne Scott ,  John Edward Gavagan

IPC分类号： C12N9/18 ,  C12N1/20 ,  C12N15/00 ,  C07H21/04 ,  C12P7/40 ,  D21C9/16 ,  D06L1/04 ,  D06L3/02 ,  D06M16/00 ,  C11D3/386 ,  C11D3/39

CPC分类号： C12N9/18 ,  C11D3/386 ,  C11D3/38654 ,  C11D3/38681 ,  C11D3/3945 ,  C12P7/40 ,  C12Y301/01072 ,  D06L1/04 ,  D06L4/15 ,  D06M16/00 ,  D21C9/166

摘要： An acetyl xylan esterase variant having perhydrolytic activity is provided for producing peroxycarboxylic acids from carboxylic acid esters and a source of peroxygen. More specifically, a Thermotoga maritima acetyl xylan esterase gene was modified using error-prone PCR and site-directed mutagenesis to create an enzyme catalyst characterized by an increase in specific activity. The variant acetyl xylan esterase may be used to produce peroxycarboxylic acids suitable for use in a variety of applications such as cleaning, disinfecting, sanitizing, bleaching, wood pulp processing, and paper pulp processing applications.

摘要翻译： 提供具有过水解活性的乙酰木聚糖酯酶变体，用于从羧酸酯和过氧源产生过氧羧酸。 更具体地，使用易错PCR和定点诱变来修饰热转录海马乙酰木聚糖酯酶基因，以产生特征在于比活性增加的酶催化剂。 变体乙酰木聚糖酯酶可用于制备适用于各种用途的过氧羧酸，例如清洁，消毒，消毒，漂白，木浆加工和纸浆加工应用。

公开(公告)号：US08546449B2

公开(公告)日：2013-10-01

申请号：US13065553

申请日：2011-03-24

申请人： Michael S. Harvey ,  Jonathan N. Howarth

发明人： Michael S. Harvey ,  Jonathan N. Howarth

IPC分类号： A61K31/19

CPC分类号： A01N37/16 ,  A01N37/12 ,  A01N59/00 ,  B01J19/24 ,  B01J2219/24 ,  C11D3/3947 ,  C11D3/3955 ,  C11D3/3956 ,  C11D11/0041 ,  D06L4/15 ,  A01N37/02 ,  A01N2300/00

摘要： Methods and compositions for the generation of a peroxyacetic acid sanitizer in proximity to the point-of-use are disclosed. These methods comprise introducing a hydrogen peroxide-acetyl precursor solution to water, mixing, and then adding an aqueous source of a alkali metal or earth alkali metal hydroxide. Triacetin is a preferred acetyl precursor and is converted rapidly and with a high conversion rate into peracetic acid. These methods produce solutions with a high level of peracetic acid. Methods for preparing the hydrogen peroxide-acetyl precursor solution are also provided. Also disclosed are solid compositions comprising a liquid acetyl precursor, a water-soluble source of hydrogen peroxide, and a water-soluble source of alkalinity. The solid composition is a freely-flowable solid that is used as a bleaching agent and a stain remover for the treatment of articles such as fabrics, dentures, textile garments, and equipment used in the food and beverage industry.

摘要翻译： 公开了在使用点附近产生过氧乙酸消毒剂的方法和组合物。 这些方法包括将过氧化氢 - 乙酰基前体溶液引入水中，混合，然后加入碱金属或碱土金属氢氧化物的水源。 三醋精是优选的乙酰基前体，并迅速转化并以高转化率转化成过乙酸。 这些方法产生具有高水平过乙酸的溶液。 还提供了制备过氧化氢 - 乙酰前体溶液的方法。 还公开了固体组合物，其包含液体乙酰基前体，水溶性过氧化氢源和水溶性碱度源。 固体组合物是可自由流动的固体，其用作漂白剂和用于处理食品和饮料工业中使用的织物，假牙，纺织品衣服和设备的制品的去污剂。

公开(公告)号：US08546119B2

公开(公告)日：2013-10-01

申请号：US13657603

申请日：2012-10-22

申请人： E. I. Du Pont De Nemours and Company

发明人： Robert DiCosimo ,  Mark Scott Payne ,  John Edward Gavagan

IPC分类号： C12N9/18 ,  C12P7/40 ,  A61L9/00

CPC分类号： A01N37/16 ,  C11D1/667 ,  C11D3/2093 ,  C11D3/221 ,  C11D3/226 ,  C11D3/38636 ,  C11D3/3869 ,  C11D3/3945 ,  C11D7/266 ,  C12N9/18 ,  C12P7/40 ,  D06L4/15 ,  D06L4/40 ,  D21C9/16 ,  Y10T428/13

摘要： An acetyl xylan esterase variant having perhydrolytic activity is provided for producing peroxycarboxylic acids from carboxylic acid esters and a source of peroxygen. More specifically, a Thermotoga maritima acetyl xylan esterase gene was modified using error-prone PCR and site-directed mutagenesis to create an enzyme catalyst characterized by an increase in specific activity. The variant acetyl xylan esterase may be used to produce peroxycarboxylic acids suitable for use in a variety of applications such as cleaning, disinfecting, sanitizing, bleaching, wood pulp processing, and paper pulp processing applications.

公开(公告)号：US20130137620A1

公开(公告)日：2013-05-30

申请号：US13641445

申请日：2011-04-15

申请人： Ronald Hage ,  Fabien Pierre Guy Gaulard ,  Kimberly Soraya Yang

发明人： Ronald Hage ,  Fabien Pierre Guy Gaulard ,  Kimberly Soraya Yang

IPC分类号： D06L3/02

CPC分类号： D06L3/025 ,  B01J31/182 ,  B01J2231/70 ,  B01J2531/0216 ,  B01J2531/72 ,  C11D3/3932 ,  D06L4/12 ,  D06L4/15

摘要： The present invention concerns the treatment of substrates with a preformed transition metal catalyst in an aqueous solution. The transitional metal catalyst is a dinuclear Mn transitional metal catalyst and its ligand has the following formula (I): and p is 3.

摘要翻译： 本发明涉及在水溶液中用预成型的过渡金属催化剂处理基材。 过渡金属催化剂是双核Mn过渡金属催化剂，其配体具有下式（I）：p为3。

公开(公告)号：US20130102670A1

公开(公告)日：2013-04-25

申请号：US13657603

申请日：2012-10-22

申请人： E. I. Du Pont De Nemours And Company

发明人： ROBERT DICOSIMO ,  MARK SCOTT PAYNE ,  JOHN EDWARD GAVAGAN

IPC分类号： C12N9/18 ,  C12N1/19 ,  C12N1/21 ,  C12N15/63 ,  D21C9/16 ,  C12N15/55 ,  A01N37/16 ,  A01P1/00 ,  C11D3/395 ,  D06L3/02 ,  C12N1/15 ,  C12P7/24

CPC分类号： A01N37/16 ,  C11D1/667 ,  C11D3/2093 ,  C11D3/221 ,  C11D3/226 ,  C11D3/38636 ,  C11D3/3869 ,  C11D3/3945 ,  C11D7/266 ,  C12N9/18 ,  C12P7/40 ,  D06L4/15 ,  D06L4/40 ,  D21C9/16 ,  Y10T428/13

摘要： An acetyl xylan esterase variant having perhydrolytic activity is provided for producing peroxycarboxylic acids from carboxylic acid esters and a source of peroxygen. More specifically, a Thermotoga maritima acetyl xylan esterase gene was modified using error-prone PCR and site-directed mutagenesis to create an enzyme catalyst characterized by an increase in specific activity. The variant acetyl xylan esterase may be used to produce peroxycarboxylic acids suitable for use in a variety of applications such as cleaning, disinfecting, sanitizing, bleaching, wood pulp processing, and paper pulp processing applications.

公开(公告)号：US06830592B2

公开(公告)日：2004-12-14

申请号：US10370096

申请日：2003-02-21

申请人： Kanke Fuminori

发明人： Kanke Fuminori

IPC分类号： D06L302

CPC分类号： D06L4/15 ,  D06L4/13

摘要： The invention provides a bleaching method of natural fibers. By the invention, it is possible to bleach raw cotton fibers without dewaxing. The method of the invention is to bring the natural fibers on each of which wax adhere, into contact with water solution containing hydroxy percarboxilic acid for bleaching. The natural fibers may be raw cotton fibers. The hydroxy percarboxilic acid may be perlactic acid. The water solution may contain hydroxy carboxilic acid, hydrogen peroxide and alkali agent with hydroxy percarboxilic acid.

摘要翻译： 本发明提供天然纤维的漂白方法。 通过本发明，可以漂白原棉纤维而不脱蜡。 本发明的方法是使每一种蜡粘附的天然纤维与含有羟基过羧酸的水溶液接触以进行漂白。 天然纤维可以是原棉纤维。 羟基过羧酸可以是全乳酸。 水溶液可含有羟基羧酸，过氧化氢和碱性剂与羟基过碳酸。

公开(公告)号：US20030226209A1

公开(公告)日：2003-12-11

申请号：US10370096

申请日：2003-02-21

发明人： Kanke Fuminori

IPC分类号： D06L003/00

CPC分类号： D06L4/15 ,  D06L4/13

摘要： The invention provides a bleaching method of natural fibers. By the invention, it is possible to bleach raw cotton fibers without dewaxing. The method of the invention is to bring the natural fibers on each of which wax adhere, into contact with water solution containing hydroxy percarboxilic acid for bleaching. The natural fibers may be raw cotton fibers. The hydroxy percarboxilic acid may be perlactic acid. The water solution may contain hydroxy carboxilic acid, hydrogen peroxide and alkali agent with hydroxy percarboxilic acid.

摘要翻译： 本发明提供天然纤维的漂白方法。 通过本发明，可以漂白原棉纤维而不脱蜡。 本发明的方法是使每一种蜡粘附的天然纤维与含有羟基过羧酸的水溶液接触以进行漂白。 天然纤维可以是原棉纤维。 羟基过羧酸可以是全乳酸。 水溶液可含有羟基羧酸，过氧化氢和碱性剂与羟基过碳酸。

公开(公告)号：US06617299B1

公开(公告)日：2003-09-09

申请号：US09539756

申请日：2000-03-31

申请人： Riccardo Filippo Carina ,  Bernard Lucas Feringa ,  Ronald Hage ,  Catherine Hemmert ,  Jean Hypolites Koek ,  Rene Marcel LaCrois ,  Bernard Meunier ,  Michael Renz ,  Johannes Gerhardus Roelfes ,  Ebe Pieter Schudde ,  Rob Thijssen ,  Robin Stefan Twisker ,  Charon Zondervan

发明人： Riccardo Filippo Carina ,  Bernard Lucas Feringa ,  Ronald Hage ,  Catherine Hemmert ,  Jean Hypolites Koek ,  Rene Marcel LaCrois ,  Bernard Meunier ,  Michael Renz ,  Johannes Gerhardus Roelfes ,  Ebe Pieter Schudde ,  Rob Thijssen ,  Robin Stefan Twisker ,  Charon Zondervan

IPC分类号： C11D3395

CPC分类号： C07D401/14 ,  C07D213/38 ,  C07D213/55 ,  C11D3/3932 ,  D06L4/12 ,  D06L4/13 ,  D06L4/15

摘要： The invention relates to catalytically bleaching substrates, especially laundry fabrics, with atmospheric oxygen or air. A method of bleaching a substrate is provided that comprises applying to the substrate, in an aqueous medium, a specified ligand from a selected class which forms a complex with a transition metal, the complex catalysing bleaching of the substrate by atmospheric oxygen. Also provided is an aqueous bleaching composition substantially devoid of peroxygen bleach or a peroxy-based or -generating bleach system. Also provided is a method of treating a textile such as a laundry fabric whereby a complex catalyses bleaching of the textile by atmospheric oxygen after the treatment. The catalyst may be used in dry form, or in a liquor that is then dried, such as an aqueous spray-on fabric treatment fluid or a wash liquor for laundry cleaning, or a non-aqueous dry cleaning fluid or spray-on aerosol fluid. The method can confer cleaning benefits to the textile after the treatment. Also provided is a dry textile having a catalyst applied or deposited thereon, whereby bleaching by atmospheric oxygen is catalysed on the textile.

摘要翻译： 本发明涉及用大气中的氧气或空气催化漂洗底物，特别是洗衣织物。 提供了一种漂白底物的方法，其包括在水性介质中向所述底物施加与过渡金属形成络合物的所选类别的特定配体，所述复合物通过大气氧催化底物的漂白。 还提供了基本上不含过氧漂白剂或过氧基或生成漂白体系的水性漂白组合物。 还提供了一种处理织物如洗衣布的方法，由此复合物在处理后通过大气氧催化织物的漂白。 催化剂可以以干式形式使用，也可以在随后干燥的液体中使用，例如水性喷涂织物处理流体或用于衣物清洗的洗涤液，或非水性干洗液或喷雾气溶胶流体 。 该方法可以在处理后赋予纺织品清洁效果。 还提供了具有施加或沉积在其上的催化剂的干织物，由此通过大气氧气漂白在织物上被催化。