公开(公告)号：US06617299B1

公开(公告)日：2003-09-09

申请号：US09539756

申请日：2000-03-31

申请人： Riccardo Filippo Carina ,  Bernard Lucas Feringa ,  Ronald Hage ,  Catherine Hemmert ,  Jean Hypolites Koek ,  Rene Marcel LaCrois ,  Bernard Meunier ,  Michael Renz ,  Johannes Gerhardus Roelfes ,  Ebe Pieter Schudde ,  Rob Thijssen ,  Robin Stefan Twisker ,  Charon Zondervan

发明人： Riccardo Filippo Carina ,  Bernard Lucas Feringa ,  Ronald Hage ,  Catherine Hemmert ,  Jean Hypolites Koek ,  Rene Marcel LaCrois ,  Bernard Meunier ,  Michael Renz ,  Johannes Gerhardus Roelfes ,  Ebe Pieter Schudde ,  Rob Thijssen ,  Robin Stefan Twisker ,  Charon Zondervan

IPC分类号： C11D3395

CPC分类号： C07D401/14 ,  C07D213/38 ,  C07D213/55 ,  C11D3/3932 ,  D06L4/12 ,  D06L4/13 ,  D06L4/15

摘要： The invention relates to catalytically bleaching substrates, especially laundry fabrics, with atmospheric oxygen or air. A method of bleaching a substrate is provided that comprises applying to the substrate, in an aqueous medium, a specified ligand from a selected class which forms a complex with a transition metal, the complex catalysing bleaching of the substrate by atmospheric oxygen. Also provided is an aqueous bleaching composition substantially devoid of peroxygen bleach or a peroxy-based or -generating bleach system. Also provided is a method of treating a textile such as a laundry fabric whereby a complex catalyses bleaching of the textile by atmospheric oxygen after the treatment. The catalyst may be used in dry form, or in a liquor that is then dried, such as an aqueous spray-on fabric treatment fluid or a wash liquor for laundry cleaning, or a non-aqueous dry cleaning fluid or spray-on aerosol fluid. The method can confer cleaning benefits to the textile after the treatment. Also provided is a dry textile having a catalyst applied or deposited thereon, whereby bleaching by atmospheric oxygen is catalysed on the textile.

摘要翻译： 本发明涉及用大气中的氧气或空气催化漂洗底物，特别是洗衣织物。 提供了一种漂白底物的方法，其包括在水性介质中向所述底物施加与过渡金属形成络合物的所选类别的特定配体，所述复合物通过大气氧催化底物的漂白。 还提供了基本上不含过氧漂白剂或过氧基或生成漂白体系的水性漂白组合物。 还提供了一种处理织物如洗衣布的方法，由此复合物在处理后通过大气氧催化织物的漂白。 催化剂可以以干式形式使用，也可以在随后干燥的液体中使用，例如水性喷涂织物处理流体或用于衣物清洗的洗涤液，或非水性干洗液或喷雾气溶胶流体 。 该方法可以在处理后赋予纺织品清洁效果。 还提供了具有施加或沉积在其上的催化剂的干织物，由此通过大气氧气漂白在织物上被催化。