公开(公告)号：US06387568B1

公开(公告)日：2002-05-14

申请号：US09559861

申请日：2000-04-27

Applicant: Jeremy Barker ,  M. Yazid Saidi ,  Jeffrey Swoyer

Inventor： Jeremy Barker ,  M. Yazid Saidi ,  Jeffrey Swoyer

IPC: H01M458

CPC classification number: H01M4/136 ,  C01B25/455 ,  H01M4/58 ,  H01M4/5825 ,  H01M10/0525 ,  H01M2004/028

Abstract: The invention provides new and novel lithium-metal-fluorophosphates which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-metal-fluorophosphates. The lithium-metal-fluorophosphates comprise lithium and at least one other metal besides lithium.

Abstract translation: 本发明提供了新的和新型的锂 - 金属 - 氟磷酸盐，其在电化学相互作用时释放锂离子，并且能够可逆地循环锂离子。 本发明提供一种可充电锂电池，其包括由新型锂金属 - 氟磷酸盐形成的电极。 除了锂之外，锂金属 - 氟磷酸盐还包含锂和至少一种其它金属。

公开(公告)号：US06203946B1

公开(公告)日：2001-03-20

申请号：US09204944

申请日：1998-12-03

Applicant: Jeremy Barker ,  M. Yazid Saidi

Inventor： Jeremy Barker ,  M. Yazid Saidi

IPC: H01M458

CPC classification number: H01M10/0525 ,  C01B25/45 ,  H01M4/0459 ,  H01M4/5825 ,  H01M10/05 ,  H01M2004/027 ,  H01M2004/028

Abstract: The invention provides an electrochemical cell which comprises a first electrode and a second electrode which is a counter electrode to said first electrode. The first electrode comprises a phosphorous compound of the nominal general formula Li3E′aE″b(PO4)3, desirably at least one E is a metal; and preferably, Li3M′M″(PO4)3. E′ and E″ are the same or different from one another. Where E′ and E″ are the same, they are preferably metals having more than one oxidation state. Where E′ and E″ are different from one another, they are preferably selected from the group of metals where at least one of E′ and E″ has more than one oxidation state.

公开(公告)号：US5869207A

公开(公告)日：1999-02-09

申请号：US762081

申请日：1996-12-09

Applicant: M. Yazid Saidi ,  Chariclea Scordilis-Kelley ,  Jeremy Barker

Inventor： M. Yazid Saidi ,  Chariclea Scordilis-Kelley ,  Jeremy Barker

IPC: C01G45/00 ,  H01M4/50 ,  H01M4/505 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/36

CPC classification number: H01M4/505 ,  C01G45/1221 ,  C01G45/1242 ,  H01M10/0567 ,  H01M4/62 ,  C01P2006/40 ,  H01M10/0525

Abstract: The present invention provides a novel composition and method for preventing decomposition of one or more electrochemical cell components comprising an electrode having an active material, and an electrolyte. The method of the invention, for the first time, effectively overcomes problems which arise between the interaction of cell components and contaminate water retained in a cell. Such contaminate water reacts with the electrolyte which comprises a salt of lithium in a solvent. Solubilizing of the salt in solution with attendant interaction between the salt and water causes formation of hydrogen-containing acids. The method of the invention effectively blocks decomposition of a lithium metal oxide cathode active material, and particularly lithium manganese oxide (LMO, nominally LiMn.sub.2 O.sub.4). Such decomposition is prevented by including in the cell a basic compound which forms an electron donor species in the electrolyte solution; and by neutralizing at least a portion of the acid by reacting the donor species with the hydrogen-containing acids thereby preventing decomposition of the lithium manganese oxide by the acid. The preservation of the lithium manganese oxide prevents degradation of other cell components by other mechanism.

Abstract translation: 本发明提供一种用于防止一种或多种电化学电池元件分解的新型组合物和方法，所述电化学电池组件包括具有活性材料的电极和电解质。 本发明的方法第一次有效地克服了细胞成分的相互作用和污染细胞中残留的水之间产生的问题。 这种污染水与包含锂在溶剂中的盐的电解质反应。 溶解盐中的盐与盐和水之间伴随的相互作用引起含氢酸的形成。 本发明的方法有效地阻止锂金属氧化物正极活性物质，特别是锰酸锂（LMO，名义上是LiMn 2 O 4）的分解。 通过在电解液中包含在电解质溶液中形成电子供体物质的碱性化合物来防止这种分解; 并且通过使供体物质与含氢酸反应从而中和酸的至少一部分，从而防止酸分解锰酸锂。 锂锰氧化物的保存通过其他机理防止其他电池组分的降解。

公开(公告)号：US5789110A

公开(公告)日：1998-08-04

申请号：US723241

申请日：1996-09-27

Applicant: Mohamed-Yazid Saidi ,  Jeremy Barker ,  Eileen S. Saidi

Inventor： Mohamed-Yazid Saidi ,  Jeremy Barker ,  Eileen S. Saidi

IPC: H01M4/131 ,  H01M4/133 ,  H01M4/36 ,  H01M4/48 ,  H01M4/485 ,  H01M4/50 ,  H01M4/505 ,  H01M4/52 ,  H01M4/525 ,  H01M4/58 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/058 ,  H01M10/36

CPC classification number: H01M4/485 ,  H01M10/0525 ,  H01M10/058 ,  H01M4/364 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/587 ,  H01M10/0565 ,  H01M4/131 ,  H01M4/133 ,  Y02T10/7011

Abstract: A solid secondary lithium electrochemical cell comprises a physical mixture of Li.sub.x n.sub.2 O.sub.4 (spinel) (0

Abstract translation: 固体二次锂电化学电池包括Lixn2O4（尖晶石）（0

公开(公告)号：US5759715A

公开(公告)日：1998-06-02

申请号：US723195

申请日：1996-09-27

Applicant: Jeremy Barker ,  Mohamed-Yazid Saidi ,  Jeffrey L. Swoyer ,  Feng Gao

Inventor： Jeremy Barker ,  Mohamed-Yazid Saidi ,  Jeffrey L. Swoyer ,  Feng Gao

IPC: H01M2/16 ,  H01M4/48 ,  H01M4/58 ,  H01M10/40

CPC classification number: H01M10/0566 ,  H01M10/05 ,  H01M10/0525 ,  H01M10/0569 ,  H01M4/133 ,  H01M4/485 ,  H01M4/587 ,  H01M4/623 ,  H01M4/667 ,  H01M2/1613 ,  H01M2/1653 ,  H01M2300/0025 ,  H01M2300/004 ,  H01M2300/0082 ,  H01M2300/0085 ,  H01M4/131 ,  H01M4/505 ,  H01M4/661 ,  H01M4/663

Abstract: The invention provides an electrochemical cell which is at least partially charged and which comprises a first electrode having an active material in particle form consisting essentially of at least partially lithiated graphite. The lithiated graphite particles are prepared by chemically or electrochemically inserting lithium ions into the particles prior to assembly of the cell. A second electrode which is a counter electrode to the first electrode has an active material consisting essentially of vanadium oxide.

Abstract translation: 本发明提供了至少部分带电的电化学电池，其包括具有主要由至少部分锂化石墨组成的颗粒形式的活性材料的第一电极。 在组装电池之前，通过化学或电化学地将锂离子插入颗粒中来制备锂化石墨颗粒。 作为与第一电极相对的电极的第二电极具有主要由氧化钒组成的活性材料。

公开(公告)号：US5744265A

公开(公告)日：1998-04-28

申请号：US665106

申请日：1996-06-13

Applicant: Jeremy Barker ,  M. Yazid Saidi

Inventor： Jeremy Barker ,  M. Yazid Saidi

IPC: C01B31/02 ,  H01M4/131 ,  H01M4/133 ,  H01M4/1393 ,  H01M4/36 ,  H01M4/48 ,  H01M4/485 ,  H01M4/50 ,  H01M4/505 ,  H01M4/58 ,  H01M10/0525 ,  H01M10/36

CPC classification number: H01M4/485 ,  H01M10/0525 ,  H01M4/131 ,  H01M4/364 ,  H01M4/505 ,  H01M4/581 ,  C01P2004/80 ,  C01P2004/82 ,  C01P2006/40 ,  H01M4/133 ,  H01M4/1393 ,  Y02P70/54

Abstract: The invention provides a new positive electrode active material having increased capacity and a method for operating an electrochemical lithium cell or battery which has the new positive electrode active material composition. The positive electrode comprises first and second lithium-containing active materials which are different from one another. The invention provides the ability to overcome first cycle inefficiency typically observed when using a single lithium-containing metal chalcogenide by adding a small amount of a second lithium-containing metal chalcogenide, preferably lithium copper oxide.

Abstract translation: 本发明提供了一种具有增加容量的新型正极活性材料和一种具有新型正极活性材料组合物的电化学锂电池或电池的操作方法。 正极包含彼此不同的第一和第二含锂活性物质。 本发明提供克服通过添加少量第二含锂金属硫族化物，优选氧化铜锂在使用单一含锂金属硫族化物时通常观察到的第一循环无效率的能力。

公开(公告)号：US5728489A

公开(公告)日：1998-03-17

申请号：US764824

申请日：1996-12-12

Applicant: Feng Gao ,  Porter H. Mitchell ,  Jeremy Barker ,  Jeffrey Swoyer

Inventor： Feng Gao ,  Porter H. Mitchell ,  Jeremy Barker ,  Jeffrey Swoyer

IPC: H01M4/62 ,  H01M6/16 ,  H01M10/36 ,  H01M6/18

CPC classification number: H01M10/0563 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/0525 ,  H01M4/62 ,  H01M6/168

Abstract: A method of improving the structural integrity of polymer electrolytes of electrochemical cell by employing lithiated zeolites, and optionally, inorganic fillers selected from SiO.sub.2, Al.sub.2 O.sub.3, TiO.sub.2 and ZrO is provided.

Abstract translation: 提供了通过使用锂化沸石和任选的选自SiO 2，Al 2 O 3，TiO 2和ZrO的无机填料来改善电化学电池的聚合物电解质的结构完整性的方法。

公开(公告)号：US5660948A

公开(公告)日：1997-08-26

申请号：US533882

申请日：1995-09-26

Applicant: Jeremy Barker

Inventor： Jeremy Barker

IPC: H01M2/16 ,  H01M4/133 ,  H01M4/48 ,  H01M4/58 ,  H01M4/583 ,  H01M4/62 ,  H01M4/66 ,  H01M10/0525 ,  H01M10/36 ,  H01M10/40

CPC classification number: H01M10/0569 ,  H01M10/05 ,  H01M10/0566 ,  H01M4/133 ,  H01M4/485 ,  H01M4/583 ,  H01M4/587 ,  H01M4/623 ,  H01M4/667 ,  H01M10/0525 ,  H01M2/1613 ,  H01M2/1653 ,  H01M2300/0025 ,  H01M2300/0082 ,  H01M2300/0085 ,  H01M4/661 ,  H01M4/663

Abstract: Non-aqueous electrochemical cells with improved performance can be fabricated by employing anodes comprising a composition having graphite particles that have a BET method specific surface area of about 6 to about 12 m.sup.2 /g and a crystallite height L.sub.c of about 100 nm to about 120 nm, and wherein at least 90% (wt) of the graphite particles are less than 16 .mu.m in size; a cathode; and a non-aqueous electrolyte containing a solvent and salt that is interposed between the anode and cathode. When employed in an electrochemical cell, the anode can attain a specific electrode capacity of at least 300 mAhr/g. The electrochemical cell has a cycle life of greater than 1500 cycles, and has a first cycle capacity loss of only about 10% to about 15%.

Abstract translation: 具有改进性能的非水电化学电池可以通过使用包含具有BET法比表面积为约6至约12m 2 / g的石墨颗粒和约100nm至约120nm的微晶高度Lc的组合物的阳极来制造 ，并且其中至少90％（重量）的石墨颗粒的尺寸小于16μm; 阴极 和含有介于阳极和阴极之间的溶剂和盐的非水电解质。 当用于电化学电池中时，阳极可达到至少300mAhr / g的特定电极容量。 电化学电池具有大于1500个循环的循环寿命，并且具有仅约10％至约15％的第一循环容量损失。

公开(公告)号：USD914912S1

公开(公告)日：2021-03-30

申请号：US29688205

申请日：2019-04-18

Applicant: Jeremy Barker

Designer： Jeremy Barker

公开(公告)号：US20190254429A1

公开(公告)日：2019-08-22

申请号：US15899136

申请日：2018-02-19

Applicant: Jeremy Barker

Inventor： Jeremy Barker

IPC: A47B96/16 ,  E06B5/10 ,  E05D7/081

Abstract: A concealed door hingedly-affixed to a concealed door frame adapted to resemble shelving and cabinets, the concealed door assembly simulated permanently-affixed shelving and cabinets, and comprising a playless hinge and various overlapping, double-stacked and interconnected components.