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195 条记录 (耗时 0.055 秒)

    Branched Vinyl Terminated Polymers And Methods For Production Thereof
    81.
    发明申请
    Branched Vinyl Terminated Polymers And Methods For Production Thereof 有权
    支链乙烯基终端聚合物及其生产方法

    公开(公告)号：US20120245299A1

    公开(公告)日：2012-09-27

    申请号：US13411929

    申请日：2012-03-05

    申请人： Peijun Jiang ,  Patrick Brant

    发明人： Peijun Jiang ,  Patrick Brant

    IPC分类号： C08F255/02 ,  C08F8/00 ,  C08F4/76

    CPC分类号： C08F110/06 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/02 ,  C08F210/06 ,  C08F255/02 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/20 ,  C08F4/65927 ,  C08F222/06

    摘要： This invention relates to a process for polymerization, comprising (i) contacting, at a temperature greater than 35° C., one or more monomers comprising ethylene and/or propylene, with a catalyst system comprising a metallocene catalyst compound and an activator, (ii) converting at least 50 mol % of the monomer to polyolefin; and (iii) obtaining a branched polyolefin having greater than 50% allyl chain ends, relative to total unsaturated chain ends. The invention also relates to the branched polyolefins and functionalized branched polyolefins.

    摘要翻译： 本发明涉及一种聚合方法，其包括（i）在大于35℃的温度下使一种或多种包含乙烯和/或丙烯的单体与包含茂金属催化剂化合物和活化剂的催化剂体系接触（ ii）将至少50mol％的单体转化成聚烯烃; 和（iii）获得相对于总不饱和链末端具有大于50％烯丙基链端的支链聚烯烃。 本发明还涉及支链聚烯烃和官能化支化聚烯烃。

    Diblock Copolymers Prepared by Cross Metathesis
    82.
    发明申请
    Diblock Copolymers Prepared by Cross Metathesis 有权
    通过交叉复分解制备的二嵌段共聚物

    公开(公告)号：US20120245290A1

    公开(公告)日：2012-09-27

    申请号：US13072383

    申请日：2011-03-25

    申请人： John R. Hagadorn ,  Charles J. Ruff ,  Renuka N. Ganesh ,  Patrick Brant

    发明人： John R. Hagadorn ,  Charles J. Ruff ,  Renuka N. Ganesh ,  Patrick Brant

    IPC分类号： C08F299/00 ,  C08L53/00

    CPC分类号： C08G61/04 ,  C08G2261/419 ,  C08L65/00

    摘要： This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO—C(R11)(R12)—C(R13)═C(R14)—C(R15)(R16)—PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio “Z”=0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.

    摘要翻译： 本发明涉及一种组合物，其包含由式：PO-C（R 11）（R 12）-C（R 13）= C（R 14）-C（R 15）（R 16）-PO *表示的多嵌段聚烯烃或其异构体， 其中R11，R12，R13，R14，R15和R16各自独立地为取代或未取代的C1至C4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9至4000个碳原子的取代或未取代的烃基，条件是PO和PO *中的至少一个为C20或更大，所述聚烯烃具有：1）如13 C NMR所示的内部不饱和度 在约128至约132ppm之间的峰; 2）Mn比“Z”= 0.1〜10，其中Z为Mn（通过13 C NMR测定）除以Mn（根据使用聚苯乙烯标准品的凝胶渗透色谱法测定）; 和3）任选地，通过1 H NMR光谱确定的每1000个碳的0.3（J）和0.75（J）内部不饱和度，其中J是成为PO和PO的乙烯基封端的聚烯烃的混合物的每1000个碳的反应性数 *，在它们通过烯烃复分解催化剂偶合之前。

    Phase separator and monomer recycle for supercritical polymerization process
    83.
    发明授权
    Phase separator and monomer recycle for supercritical polymerization process 有权
    用于超临界聚合过程的相分离器和单体循环

    公开(公告)号：US08242237B2

    公开(公告)日：2012-08-14

    申请号：US11854936

    申请日：2007-09-13

    申请人： Chris B. Friedersdorf ,  Patrick Brant ,  Gabor Kiss

    发明人： Chris B. Friedersdorf ,  Patrick Brant ,  Gabor Kiss

    IPC分类号： C08F6/26 ,  C08F10/06

    CPC分类号： C08F10/06 ,  C08F4/65927 ,  C08F210/06 ,  Y02P20/544 ,  C08F2/06 ,  C08F2/14 ,  C08F210/14

    摘要： A process for polymerizing olefins, comprising the steps of: (a) contacting in a dense-fluid-homogeneous-polymerization system (“PS”), >30 wt % C3+ olefins with: catalyst, activator, 0-50 mol % comonomer, and 0-40 wt % diluent/solvent, at a temperature > PS Tc and a pressure no lower than 1 MPa below the PS cloud point pressure and the polymer or above 80° C., whichever is higher; (f) separating the monomer-rich phase from the polymer-rich phase; (g) recycling the separated monomer-rich phase and recovering polymer from the polymer-rich phase.

    摘要翻译： 一种聚合烯烃的方法，包括以下步骤：（a）在稠密 - 液体均相聚合体系（“PS”）中，> 30wt％的C 3+烯烃与催化剂，活化剂，0-50mol％共聚单体， 和0-40重量％稀释剂/溶剂，温度> PS Tc和低于PS浊点压力和<200MPa的不低于1MPa的压力; （b）形成包含聚合物 - 单体混合物的反应器流出物; （c）任选地加热混合物（b）; （d）在分离容器中收集混合物（b）; （e）降低压力以形成两相混合物，其中反应器中的压力高于分离容器中的压力为7-100MPa，分离容器中的温度>聚合物或高于80℃， 以较高者为准; （f）从富含聚合物的相分离富单体相; （g）循环分离的富含单体的相并从富含聚合物的相回收聚合物。

    In-line process for producing plasticized polymers and plasticized polymer blends
    86.
    发明授权
    In-line process for producing plasticized polymers and plasticized polymer blends 有权
    用于生产增塑聚合物和增塑聚合物共混物的在线方法

    公开(公告)号：US07928162B2

    公开(公告)日：2011-04-19

    申请号：US12283045

    申请日：2008-09-09

    申请人： Gabor Kiss ,  Alan Anthony Galuska ,  Robert Patrick Reynolds, Jr. ,  John W. Chu ,  Bryan R. Chapman ,  Patrick Brant ,  Sudhin Datta

    发明人： Gabor Kiss ,  Alan Anthony Galuska ,  Robert Patrick Reynolds, Jr. ,  John W. Chu ,  Bryan R. Chapman ,  Patrick Brant ,  Sudhin Datta

    IPC分类号： C08F2/12 ,  C08F6/00 ,  C08L23/02

    CPC分类号： C08F10/00 ,  B01J2219/00038 ,  B01J2219/0004 ,  C08F210/16 ,  C08J3/18 ,  C08F2/01 ,  C08F2/001 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/20

    摘要： A process for fluid phase in-line blending of plasticized polymers is provided. The process includes providing two or more reactor trains configured in parallel and a separator for product blending and product-feed separation, wherein one or more of the reactor trains produces one or more polymers and one or more of the reactor trains produces one or more plasticizers; contacting in at least one of the parallel reactor trains olefin monomers, catalyst systems, optional comonomers, optional scavengers, and optional diluents or solvents, at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa; forming a reactor effluent including a homogeneous fluid phase polymer-monomer mixture and plasticizer-monomer mixture in each parallel reactor train; passing the reactor effluents through the separator; maintaining the temperature and pressure within the separator above the solid-fluid phase transition point but below the cloud point pressure and temperature to form a fluid-fluid two-phase system including a plasticized polymer-rich blend phase and a monomer-rich phase; and separating the monomer-rich phase from the plasticized polymer-rich blend phase. The polymer-rich blend phase is conveyed to a downstream finishing stage for further monomer stripping, drying and/or pelletizing to form a plasticized polymer product blend. Suitable plasticizers for in-line production and blending include polyalphaolefin oligomers, polybutenes, low glass transition temperature polymers and combinations thereof.

    摘要翻译： 提供了一种用于增塑聚合物的流体相在线共混的方法。 该方法包括提供并联配置的两个或多个反应器列和用于产物共混和产物 - 进料分离的分离器，其中一个或多个反应器列产生一种或多种聚合物，并且一个或多个反应器列产生一种或多种增塑剂 ; 在高于聚合体系的固体 - 流体相转变温度的温度下，在至少一个平行反应器系列烯烃单体，催化剂体系，任选的共聚单体，任选的清除剂和任选的稀释剂或溶剂中接触，并且压力不低于10 MPa低于聚合体系的浊点压力，小于1500MPa; 在每个平行的反应器列中形成包含均相流体相聚合物 - 单体混合物和增塑剂 - 单体混合物的反应器流出物; 使反应器流出物通过分离器; 将分离器内的温度和压力保持在固体 - 流体相转变点之上但低于浊点压力和温度，以形成包括增塑的富含聚合物的共混相和富单体相的流体 - 流体两相系统; 并将富单体相与增塑的富聚合物相分离。 富含聚合物的共混相被输送到下游整理阶段以用于进一步的单体汽提，干燥和/或造粒以形成增塑的聚合物产物混合物。 用于在线生产和共混的合适的增塑剂包括聚α-烯烃低聚物，聚丁烯，低玻璃化转变温度聚合物及其组合。

    Polymer production at supercritical conditions
    89.
    发明申请
    Polymer production at supercritical conditions 审中-公开
    聚合物在超临界条件下的生产

    公开(公告)号：US20080153997A1

    公开(公告)日：2008-06-26

    申请号：US11714546

    申请日：2007-03-06

    申请人： Gary L. Casty ,  Raymond A. Cook ,  Gabor Kiss ,  Patrick Brant

    发明人： Gary L. Casty ,  Raymond A. Cook ,  Gabor Kiss ,  Patrick Brant

    IPC分类号： C08F4/42 ,  C08F2/00 ,  C08F4/46

    CPC分类号： C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  Y02P20/544 ,  C08F4/64144 ,  C08F2/06 ,  C08F2500/20 ,  C08F2500/17 ,  C08F2500/09 ,  C08F2500/03

    摘要： This invention relates to a process to polymerize olefins comprising contacting, at a temperature of 60° C. or more and a pressure of at least 15 MPa, one or more olefin monomers having three or more carbon atoms, with: 1) a catalyst system comprising one or more activators and one or more nonmetallocene metal-centered, heteroaryl ligand catalyst compounds, where the metal is chosen from the Group 4, 5, 6, the lanthanide series, or the actinide series of the Periodic Table of the Elements, 2) optionally one or more comonomers, 3) optionally diluent or solvent, and 40 optionally solvent, wherein: a) the olefin monomers and any comonomers are present in the polymerization system at 40 weight % or more, b) the monomer having three or more carbon atoms is present at 80 wt % or more based upon the weight of all monomers and comonomers present in the feed, c) the polymerization occurs at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa, in the event the solid-fluid phase transition temperature of the polymerization system cannot be determined then the polymerization occurs at a temperature above the fluid fluid phase transition temperature.

    摘要翻译： 本发明涉及一种聚合烯烃的方法，包括在60℃或更高的温度和至少15MPa的压力下使一种或多种具有三个或更多个碳原子的烯烃单体与以下物质接触：1）催化剂体系 包含一种或多种活化剂和一种或多种非金属茂金属中心的杂芳基配位体催化剂化合物，其中金属选自第4,5,6族，镧系元素或元素周期表的锕系元素，2 ）任选的一种或多种共聚单体，3）任选的稀释剂或溶剂，以及40任选溶剂，其中：a）烯烃单体和任何共聚单体在40重量％或更多的重量％存在于聚合体系中，b）具有三个或更多个的单体 基于进料中存在的所有单体和共聚单体的重量，碳原子存在于80重量％以上，c）聚合在高于聚合体系的固体 - 流体相转变温度的温度下进行， 肯定不低于聚合体系的浊点压力10MPa以下，并且小于1500MPa，在聚合体系的固体流体相转变温度不能确定的情况下，聚合在高于流体流体相的温度下发生 转变温度。