摘要:
Alkyl ester end-capped polycarbonates have improved release properties and may be produced by a method comprising the step of combining a polycarbonate having free terminal OH groups with an end-capping reagent comprising a symmetrical activated carbonate and an alkyl ester, whereby the end-capping reagent reacts with at least some of the free hydroxyl end groups of the polycarbonate to produce an end-capped polycarbonate comprising optionally substituted aliphatic ester end groups.
摘要:
A polycarbonate copolymer comprising structural units derived from a cyclohexylidene bis(alkylphenol) of the formula: wherein A1 is a trisubstituted aromatic radical having the formula C6H3R2, wherein R2 is selected from the group consisting of C1-C6 alkyl radicals, and combinations comprising at least one of the foregoing radicals; a long chain alkyl-substituted bisphenol of the formula wherein A2 is a substituted or unsubstituted aromatic radical; and R1 is selected from the group consisting of C13-C22 alkyl radicals; a carbonic acid diester; and optionally at least one aromatic dihydroxy compound of the formula: HO—A3—OH, wherein A3 is selected from divalent substituted and unsubstituted aromatic radicals.
摘要翻译:包含衍生自下式的亚环己基双(烷基苯酚)的结构单元的聚碳酸酯共聚物:其中A 1是具有式C 6 H 3 R 2的三取代芳族基团,其中R 2选自C1- C6烷基和包含至少一个上述基团的组合; 式Ⅳa的长链烷基取代双酚是取代或未取代的芳基; 并且R 1选自C 13 -C 22烷基; 碳酸二酯; 和任选的至少一种下式的芳族二羟基化合物:其中A 3选自二价取代和未取代的芳族基团。
摘要:
The disclosure relates to articles using polycarbonates produced by a melt transesterification polymerization method using bis(hydroxyaryl)cyclohexanes. Such polycarbonates have suitable glass transition temperatures and outstanding dimensional stabilities, thus making them particularly useful for making articles possessing high temperature stability, particularly for use in optical articles such as high density optical data storage and recordable media.
摘要:
A poly(carbonate-co-ester) block copolymer is synthesized using synthetic strategies that can be incorporated into conventional melt facilities that are commonly used in the production of polycarbonate polymers. The polycarbonate block of the poly(carbonate-co-ester) copolymer is derived from a polycarbonate reaction mixture comprising an aromatic dihydroxy compound and a carbonic acid diester, such as bisphenol A and diphenyl carbonate, respectively. The second block of the copolymer is derived from a polyester prepolymer, the polyester prepolymer comprising a diol, diacid or diester, and at least one monomer that is selected to advantageously incorporate desired properties into the poly(carbonate-co-ester) copolymer. The polyester prepolymer is introduced to the polycarbonate reaction mixture to form the poly(carbonate-co-ester) copolymer. Properties of the copolymer can be altered by varying numerous conditions of the reaction.
摘要:
A polycarbonate composition for an electrophotographic photoreceptor coating, wherein the polycarbonate includes 1 to 100 mole percent of first units of the formula and 0 to 99 mole percent of one or more second units of the formula and wherein the polycarbonate has a weight average molecular weight of at least 50,000 g/mole, and a polydispersity index of 1 to 5.
摘要:
An article and thermoplastic composition including polycarbonate, a polysiloxane-polycarbonate and an x-ray detectable or metal detectable agent having good magnetic permeability and/or electrical conductivity wherein the composition may be used in articles for food preparation. The thermoplastic compositions are useful in forming molds for manufacturing a food product, such as chocolate molds.
摘要:
Disclosed are polymer compositions including polycarbonates, polyphosphonates, copoly(phosphonate carbonate)s, and organic salts and/or silicone containing compounds that exhibit a superior combination of properties compared to prior art.
摘要:
Methods of forming polycarbonate graft copolymers are provided. In particular, a polycarbonate polymer or copolymer containing allyl groups provides the backbone for the graft copolymer, and pendant chains are attached to the copolymer through the allyl groups. The graft copolymers exhibit a combination of high transparency, good graft levels, good scratch resistance, and/or good anti-fog properties.
摘要:
Polycarbonate compositions are disclosed. The compositions comprise an optional polycarbonate polymer (A); a polycarbonate-polysiloxane copolymer (B); a phosphorous-containing flame retardant (C); and a reinforcing agent (D). The resulting compositions have an improved combination of properties, particularly Vicat softening temperature and high flame retardance in thin walls.
摘要:
Disclosed herein is are thermoplastic compositions comprising a blend of a homopolycarbonate comprising units derived from an aromatic dihydroxy compound and a copolymer comprising isosorbide units and siloxane units. The copolymer comprising isosorbide units and siloxane units can further comprise non-isosorbide aliphatic units derived from a C14-44 aliphatic diacid, a C14-44 aliphatic diol or combination of these, aromatic units, aliphatic units derived from an oligomer having a weight average molecular weight of 900 to 4000 or a combination of some or all of the foregoing additional units.