Abstract:
The invention relates to copolymers comprising a chain of siloxane repeat units of at least two different types, a first type of siloxane repeat unit comprising at least one —OH group on the silicon atom of the siloxane repeat unit and a second type of repeat unit comprising at least one pendant chain on the silicon atom of said repeat unit, this pendant chain consisting of a polymer chain comprising a chain of repeat units carrying at least one group of formula —PO3R1R2 wherein R1 and R2 independently represent a hydrogen atom, an alkyl group or a cation.
Abstract translation:本发明涉及包含至少两种不同类型的硅氧烷重复单元链的共聚物,第一类型的硅氧烷重复单元,其在硅氧烷重复单元的硅原子上包含至少一个-OH基团,第二类型的重复单元包括 所述重复单元的硅原子上的至少一个侧链,该侧链由包含至少一个式-PO 3 R 1 R基团的重复单元链的聚合物链组成,其中R 1和R 2独立地表示氢原子,烷基 或阳离子。
Abstract:
The invention describes an ion exchange membrane formed from a biaxially orientated single or multiple-layered β-porous polypropylene film which comprises at least one β-nucleating agent and an ion-conducting polymer and has a Gurley value of at least 10000 s.
Abstract:
A method of improving Faradaic efficiency in an electrochemical device includes providing a catalyst at an electrode of the electrochemical device. The catalyst includes a nanoparticle comprising a metal or metal alloy. The nanoparticle is selected to improve catalytic performance in the electrochemical device. The catalyst further includes an electron-conductive nano-zeolitic framework encasing the nanoparticle. The nano-zeolitic framework includes a hollow three-dimensional framework defining a catalyst surface, an internal cavity in which the nanoparticle is disposed, and a plurality of pores extending through the nano-zeolitic framework. The plurality of pores have a size and shape selected to block molecules corresponding to undesired reactions in the electrochemical device. The method further includes selectively promoting a desired reaction at the catalyst surface and selectively blocking the undesired reactions at the catalyst surface.
Abstract:
An electrode catalyst of the present invention contains an electrically conductive material carrying a metal or a metal oxide, and has an electrical conductivity at 30° C. of 1×10−13 Scm−1 or more.
Abstract:
The present invention relates to a direct alcohol fuel cell comprising a housing containing a proton exchange membrane (PEM) separating an anode section from a cathode section, which anode section and which cathode section are contained in the housing, the cathode section comprising a cathode collection element having one or more ventilation holes, which cathode collection element is electrically connected to a cathode catalyst, which cathode catalyst is in diffusive communication with a gaseous oxidant, and the anode section comprising an anode collection element electrically connected to an anode catalyst, the DAFC comprising an oleophobic filter covering the ventilation hole(s). The oleophobic filter may be held in place using any appropriate means as desired. The fuel cell is suited for a microelectronic device.
Abstract:
A fuel cell system includes a hotbox configured to house a fuel cell stack, the fuel cell stack including a temperature sensor configured to detect temperature inside the fuel cell stack. The system includes a first tank including a first valve and configured to store methanol. The system includes a second tank including a second valve and configured to store water. The system includes a controller communicatively coupled to receive signals from the temperature sensor and control each of the first valve and the second valve. The controller is configured to set a dosing rate of methanol, based on a temperature of the fuel cells stack, to a predefined dosing rate and initiate operating at least one of the first valve and the second valve to deliver a mixture of methanol and water at the predefined dosing rate to prevent re-oxidation of an anode of the fuel cell stack.
Abstract:
The present disclosure provides a membrane electrode assembly (MEA) with high-efficiency water and heat management for a direct ethanol fuel cell (DEFC), and a fabrication method therefor, and belongs to the technical field of fuel cells. In the MEA for a DEFC in the present disclosure, a cathode catalyst layer is designed to be convex and ordered and an anode catalyst layer is designed to be concave and ordered, which is conducive to the timely discharge of the generated heat. The MEA for a DEFC can be fabricated by gradually fabricating each layer of the MEA on an inner surface and an outer surface of a proton-exchange membrane (PEM) or by step-by-step dip coating on an anode support tube. The present disclosure can effectively improve the working capacity of the cell.
Abstract:
A direct alcohol fuel cell having an inner housing, and a proton exchange membrane separating an anode section from a cathode section. The anode section contains an anode collection element electrically connected to an anode catalyst that is in diffusive communication with a fuel supply. The cathode section contains a cathode collection element having one or more ventilation holes is electrically connected to a cathode catalyst. An oleophobic filter and/or an anion-exchange membrane is provided, which cathode catalyst via the one or more ventilation holes and the oleophobic filter and/or the anion-exchange membrane is in diffusive communication with a gaseous oxidant. The inner housing has a bottom and walls extending from the bottom to contain the anode section, the PEM and the cathode section, the bottom and/or the walls having holes allowing fluid communication from a fuel supply to the anode section. The fuel cell is suited for microelectronic devices.
Abstract:
Provided are membranes useful for electrochemical or fuel cells. A membrane may be formed of or include a sulfonated polymer whereby the sulfonated polymer is covalently or ionically associated with a multi-nitrogen containing heterocyclic molecule. The resulting membranes possess excellent ion conductivity and selectivity.
Abstract:
A reformer assembly includes a vortex tube receiving heated fuel mixed with steam. A catalyst coats the inner wall of the main tube of the vortex tube and a hydrogen-permeable tube is positioned in the middle of the main tube coaxially with the main tube. With this structure the vortex tube outputs primarily Hydrogen from one end and Carbon-based constituents from the other end. In some embodiments a second vortex tube receives the Carbon output of the first vortex tube to establish a water gas shift reactor, producing Hydrogen from the Carbon output of the first vortex tube.