POLYMER PRODUCTION APPARATUS AND POLYMER PRODUCTION METHOD
    53.
    发明申请
    POLYMER PRODUCTION APPARATUS AND POLYMER PRODUCTION METHOD 有权
    聚合物生产设备和聚合物生产方法

    公开(公告)号:US20150141611A1

    公开(公告)日:2015-05-21

    申请号:US14542804

    申请日:2014-11-17

    IPC分类号: C08G63/08 B01J19/24 C08G64/30

    摘要: A polymer production apparatus, including: supplying unit containing first supplying unit to supply raw materials containing monomer, and second supplying unit to supply compressive fluid; contacting unit to bring the monomer and the compressive fluid into contact together; and outlet configured to discharge reaction product of the monomer, wherein reaction unit is provided between the contacting unit and the outlet, where the reaction unit is to pass the monomer from the contacting unit side to the outlet side, while allowing the monomer to carry out a polymerization reaction in the presence of the compressive fluid, and wherein the reaction unit contains circulation unit containing first pipe and second pipe, where a fluid is passed through the first pipe from the contacting unit side to the outlet side, and the second pipe is to return the fluid from return port provided upstream extrusion unit to inlet provided upstream the return port.

    摘要翻译: 一种聚合物制造装置,包括:含有第一供给单元的供给单元,供给含有单体的原料,第二供给单元供给压缩流体; 接触单元使单体和压缩流体接触在一起; 和排出口,用于排出单体的反应产物,其中反应单元设置在接触单元和出口之间,其中反应单元将单体从接触单元侧通过到出口侧,同时允许单体进行 在压缩流体存在下的聚合反应,其中反应单元包含含有第一管和第二管的循环单元,其中流体从接触单元侧通过第一管至出口侧,第二管为 将流体从提供的上游挤出单元的返回口返回到在返回端口上游提供的入口。

    METHOD FOR CONTINUOUS PRODUCTION OF HIGH MOLECULAR WEIGHT POLYCARBONATE RESIN
    54.
    发明申请
    METHOD FOR CONTINUOUS PRODUCTION OF HIGH MOLECULAR WEIGHT POLYCARBONATE RESIN 有权
    连续生产高分子量聚碳酸酯树脂的方法

    公开(公告)号:US20150133611A1

    公开(公告)日:2015-05-14

    申请号:US14400640

    申请日:2013-05-14

    IPC分类号: C08G64/30 C08G64/06

    摘要: A high molecular weight polycarbonate resin is continuously produced by subjecting an aromatic polycarbonate prepolymer and an aliphatic diol compound to a linking and highly polymerizing reaction. Even an aliphatic diol compound having a comparatively low boiling point can be allowed to efficiently contribute to the linking and highly polymerizing reaction. An aromatic polycarbonate prepolymer is produced by a polycondensation reaction between an aromatic dihydroxy compound and a diester carbonate, adding an aliphatic diol compound having an aliphatic group bonding to a terminal hydroxyl group to obtain a prepolymer mixture, and subjecting the resulting prepolymer mixture to a linking and highly polymerizing reaction under reduced pressure. The aliphatic diol compound is added at a pressure exceeding 200 torr, and the prepolymer mixture is subjected to a linking and highly polymerizing reaction before the terminal hydroxyl group concentration of the aromatic polycarbonate prepolymer in the prepolymer mixture reaches 2000 ppm.

    摘要翻译: 通过使芳族聚碳酸酯预聚物和脂族二醇化合物进行连接和高度聚合反应来连续制备高分子量聚碳酸酯树脂。 甚至可以使具有较低沸点的脂族二醇化合物有效地促进连接和高度聚合反应。 通过芳香族二羟基化合物与碳酸二酯之间的缩聚反应生成芳香族聚碳酸酯预聚物,加入具有与末端羟基键合的脂肪族二醇化合物,得到预聚物混合物,将所得预聚物混合物进行连接 并在减压下进行高度聚合反应。 在超过200托的压力下加入脂族二醇化合物,预聚物混合物在预聚物混合物中的芳族聚碳酸酯预聚物的末端羟基浓度达到2000ppm之前进行连接和高度聚合反应。

    CARBON DIOXIDE FIXATION METHOD USING CONDENSATION POLYMERIZATION, POLYMER MATERIAL PREPARED THEREBY, METHOD FOR RECOVERING CARBON FROM SAID POLYMER MATERIAL, AND GRAPHITE GENERATED BY SAID CARBON RECOVERY METHOD
    56.
    发明申请
    CARBON DIOXIDE FIXATION METHOD USING CONDENSATION POLYMERIZATION, POLYMER MATERIAL PREPARED THEREBY, METHOD FOR RECOVERING CARBON FROM SAID POLYMER MATERIAL, AND GRAPHITE GENERATED BY SAID CARBON RECOVERY METHOD 有权
    使用聚合聚合的二氧化碳固定方法,其制备的聚合物材料,用于从固体聚合物材料回收碳的方法和由碳化碳回收方法生成的石墨

    公开(公告)号:US20140308196A1

    公开(公告)日:2014-10-16

    申请号:US14365817

    申请日:2012-12-04

    发明人: Jang-Gyu Kim

    IPC分类号: C08G64/30 C08G64/02 C01B31/04

    摘要: This invention relates to a method of fixing carbon dioxide by condensation polymerization in an acidic aqueous medium, thereby increasing fixation efficiency and remarkably reducing the volume of generated material compared to conventional carbon dioxide fixation methods; a polymer material prepared by the method; and a method of recovering carbon therefrom. According to the current invention, the method of fixing carbon dioxide is characterized by introducing carbon dioxide pressurized to a pressure higher than atmospheric pressure into a reactor containing a acidic aqueous medium, so that carbonic acid resulting from dissolving carbon dioxide is made into a polymer material by condensation polymerization, thereby fixing carbon dioxide, and heating the polymer material so as to recover carbon.

    摘要翻译: 本发明涉及一种在酸性水介质中通过缩聚固定二氧化碳的方法,从而与传统的二氧化碳固定方法相比,提高了固色效率和显着降低了生成物质的体积; 通过该方法制备的聚合物材料; 和从其中回收碳的方法。 根据本发明,固定二氧化碳的方法的特征在于将加压至高于大气压的压力的二氧化碳引入到含有酸性水性介质的反应器中,从而将由二氧化碳溶解得到的碳酸制成聚合物材料 通过缩聚,从而固定二氧化碳,并加热聚合物材料以回收碳。

    PROCESS FOR MANUFACTURING BRANCHED AROMATIC POLYCARBONATE RESIN WITH DESIRED DEGREE OF BRANCHING
    58.
    发明申请
    PROCESS FOR MANUFACTURING BRANCHED AROMATIC POLYCARBONATE RESIN WITH DESIRED DEGREE OF BRANCHING 有权
    制造分支式芳香族聚碳酸酯树脂的方法

    公开(公告)号:US20130317182A1

    公开(公告)日:2013-11-28

    申请号:US13984380

    申请日:2012-02-09

    IPC分类号: C08G64/42

    摘要: [Problem] To provide a process for manufacturing, easily and using a conventional branching agent, a branched aromatic polycarbonate resin which has both a sufficiently high molecular weight and a desired degree of branching. [Solution] A branched aromatic polycarbonate resin having a degree of branching (N value) controlled within a specific range is manufactured by subjecting an aromatic polycarbonate prepolymer that has a branched structure introduced using a specific amount of a branching agent to molecular-weight-increasing linking reaction with an aliphatic diol compound in the presence of a transesterification catalyst under the condition of a reduced pressure. The amount (A) of the branching agent used in adjusted on the basis of the correlation between the amount (A) of the branching agent used and the N value of the branched aromatic polycarbonate resin.

    摘要翻译: [问题]提供一种制造方法,容易地和使用常规的支化剂,具有足够高的分子量和所需的支化度的支链芳族聚碳酸酯树脂。 [解决方案]通过使具有特定量的支化剂导入的具有支化结构的芳族聚碳酸酯预聚物经分子量增加而制备具有控制在特定范围内的支化度(N值)的支化芳族聚碳酸酯树脂 在酯交换催化剂存在下,在减压条件下与脂肪族二醇化合物进行交联反应。 基于所使用的支化剂的量(A)和支化芳族聚碳酸酯树脂的N值之间的相关性调节的支化剂的量(A)。

    Processes for producing polycarbonate
    59.
    发明授权
    Processes for producing polycarbonate 有权
    生产聚碳酸酯的方法

    公开(公告)号:US08445624B2

    公开(公告)日:2013-05-21

    申请号:US12808058

    申请日:2008-12-10

    IPC分类号: C08G64/00 C08G63/02

    摘要: A subject for the invention is to provide a polycarbonate having excellent mechanical strength, heat resistance, a low refractive index, a large Abbe number, reduced birefringence, and excellent transparency. The invention relates to a polycarbonate characterized by being obtained by subjecting one or more dihydroxy compounds including a dihydroxy compound having at least one linking group —CH2—O— in the molecule thereof to melt polycondensation with a carbonic acid diester, and by having a reduced viscosity of from 0.40 dL/g to 1.70 dL/g and a formic acid content lower than 5 ppm by weight.

    摘要翻译: 本发明的主题是提供具有优异的机械强度,耐热性,低折射率,大的阿贝数,降低的双折射和优异的透明性的聚碳酸酯。 本发明涉及一种聚碳酸酯,其特征在于通过使一种或多种二羟基化合物(包括其分子中具有至少一个连接基团-CH 2 -O-的二羟基化合物)与碳酸二酯熔融缩聚得到,并通过使其还原 粘度为0.40dL / g至1.70dL / g,甲酸含量低于5ppm重量。

    ANTIMICROBIAL POLYMERS AND METHODS OF MANUFACTURE THEREOF
    60.
    发明申请
    ANTIMICROBIAL POLYMERS AND METHODS OF MANUFACTURE THEREOF 审中-公开
    抗微生物聚合物及其制备方法

    公开(公告)号:US20130011457A1

    公开(公告)日:2013-01-10

    申请号:US13619958

    申请日:2012-09-14

    摘要: Biodegradable cationic block copolymers are disclosed, comprising a hydrophilic block comprising first repeat units derived from a first cyclic carbonyl monomer by ring-opening polymerization, wherein more than 0% of the first repeat units comprise a side chain moiety comprising a quaternary amine group; a hydrophobic block comprising second repeat units derived from a second cyclic carbonyl monomer by ring-opening polymerization; an optional endcap group; and a chain fragment derived from an initiator for the ring opening polymerization. The cationic block copolymers form aqueous micelle mixtures suitable for antimicrobial applications.

    摘要翻译: 公开了可生物降解的阳离子嵌段共聚物,其包含亲水性嵌段,其包含通过开环聚合衍生自第一环状羰基单体的第一重复单元,其中多于0%的第一重复单元包含包含季胺基团的侧链部分; 疏水性嵌段,其包含通过开环聚合衍生自第二环状羰基单体的第二重复单元; 可选端帽组; 和衍生自用于开环聚合的引发剂的链片段。 阳离子嵌段共聚物形成适用于抗微生物应用的水性胶束混合物。