INTEGRATED PROPYLENE PRODUCTION
    51.
    发明申请
    INTEGRATED PROPYLENE PRODUCTION 有权
    综合丙烯生产

    公开(公告)号:US20100041930A1

    公开(公告)日:2010-02-18

    申请号:US12540109

    申请日:2009-08-12

    IPC分类号: C07C4/06

    摘要: A process for the production of propylene, the process including: fractionating a hydrocarbon stream comprising n-butenes, isobutylene, and paraffins into at least two fractions including a light C4 fraction comprising isobutylene and a heavy C4 fraction comprising n-butenes and paraffins; contacting at least a portion of the heavy C4 fraction with a metathesis catalyst to form a metathesis product comprising ethylene, propylene, C4+ olefins, and paraffins; fractionating the metathesis product into at least four fractions including an ethylene fraction, a propylene fraction, a C4 fraction comprising C4 olefins and paraffins, and a C5+ fraction; cracking the light C4 fraction and the C5+ fraction to produce a cracking product comprising ethylene, propylene, and heavier hydrocarbons; and fractionating the cracking product into at least two fractions including a light fraction comprising propylene and a fraction comprising C5 to C6 hydrocarbons.

    摘要翻译: 一种生产丙烯的方法,该方法包括:将包含正丁烯,异丁烯和链烷烃的烃流分馏成至少两个馏分,包括含有异丁烯的轻馏分C4馏分和包含正丁烯和链烷烃的重C4馏分; 使至少一部分重C4馏分与复分解催化剂接触以形成包含乙烯,丙烯,C 4 +烯烃和链烷烃的复分解产物; 将复分解产物分馏成至少四个馏分,包括乙烯馏分,丙烯馏分,包含C4烯烃和石蜡的C4馏分和C5 +馏分; 裂解光C4馏分和C5 +级分以产生包含乙烯,丙烯和较重烃的裂化产物; 并将裂化产物分馏成至少两个馏分,包括包含丙烯的轻馏分和包含C5至C6烃的馏分。

    Process for the double bond hydroisomerization of butenes
    52.
    发明授权
    Process for the double bond hydroisomerization of butenes 有权
    丁烯双键加氢异构化方法

    公开(公告)号:US07576251B2

    公开(公告)日:2009-08-18

    申请号:US11107649

    申请日:2005-04-15

    IPC分类号: C07C5/25 C07C5/27

    摘要: A process is disclosed for the preferential conversion to 2-butene of a stream containing C4 compounds including 1-butene and 2-butene. The process involves mixing the C4 stream with a first hydrogen stream to form a feed stream, hydroisomerizing the feed stream in the presence of a first hydroisomerization catalyst in order to convert at least a portion of the 1-butene to 2-butene, thereby producing a hydroisomerization effluent, passing the hydroisomerization effluent through a fractionation column to form a top stream comprising isobutane and isobutylene and a bottoms stream comprising 2-butene, withdrawing a recycle stream from said fractionation column at a location above the feed point at which the weight ratio of 1-butene to 2-butene is high, and combining the recycle stream with at least one of the C4 stream and the feed stream upstream from the hydroisomerization catalyst. A corresponding apparatus also is disclosed.

    摘要翻译: 公开了一种优选转化为包含1-丁烯和2-丁烯的C4化合物的物流的2-丁烯的方法。 该方法包括将C4流与第一氢气流混合以形成进料流,在第一加氢异构化催化剂存在下使进料流加氢异构化,以将至少一部分1-丁烯转化为2-丁烯,从而产生 加氢异构化流出物,使加氢异构化流出物通过分馏塔以形成包含异丁烷和异丁烯的顶部料流和含有2-丁烯的塔底料流,在进料点上方的位置上取出来自所述分馏塔的再循环料流, 的1-丁烯与2-丁烯的摩尔比高,并且将再循环流与加氢异构化催化剂上游的C 4流和进料流中的至少一个混合。 也公开了相应的装置。

    Cracked gas processing and conversion for propylene production
    53.
    发明授权
    Cracked gas processing and conversion for propylene production 有权
    丙烯生产裂解气处理和转化

    公开(公告)号:US06420619B1

    公开(公告)日:2002-07-16

    申请号:US09769871

    申请日:2001-01-25

    IPC分类号: C07C522

    摘要: The C3 to C6 cut from a cracking process containing propylene, butane, 1-butene, 2-butene and acetylenic and diene components including butadiene are preferentially converted to propylene. The cut is simultaneously fractionated and catalytically hydrogenated to hydrogenate the acetylenic and diene components. The fractionation and subsequent separation recovers a C4 component comprising a mixture of isobutene, 1-butene and 2-butene. This C4 component is then further simultaneously fractionated and catalytically hydrogenated and hydroisomerized to hydrogenate remaining butadiene, remove isobutene overhead and convert 1-butene to 2-butene leaving a bottoms of 2-butene. The 2-butene is then injected with ethylene and catalytically metathesized to form propylene.

    摘要翻译: 从包含丙烯,丁烷,1-丁烯,2-丁烯和包含丁二烯的炔属和二烯组分的裂化过程中切割的C3至C6优先转化为丙烯。 切割同时分馏并催化氢化以氢化炔属和二烯组分。 分馏和随后的分离回收了包含异丁烯,1-丁烯和2-丁烯的混合物的C4组分。 然后将该C4组分进一步同时分馏并催化氢化并加氢异构化以氢化剩余的丁二烯,去除异丁烯塔顶馏分并将1-丁烯转化为2-丁烯,留下2-丁烯的底部。 然后将2-丁烯注入乙烯并进行催化复分解以形成丙烯。