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110 条记录 (耗时 0.024 秒)

    Oligo (2-alkenyl azlactones)
    57.
    发明授权
    Oligo (2-alkenyl azlactones) 失效
    低聚（2-链烯基吖内酯）

    公开(公告)号：US5091489A

    公开(公告)日：1992-02-25

    申请号：US734925

    申请日：1991-07-24

    申请人： Steven M. Heilmann ,  Dean M. Moren ,  Jerald K. Rasmussen ,  Larry R. Krepski ,  Sadanand V. Pathre

    发明人： Steven M. Heilmann ,  Dean M. Moren ,  Jerald K. Rasmussen ,  Larry R. Krepski ,  Sadanand V. Pathre

    IPC分类号： C07D263/42 ,  C07D498/04 ,  C07D498/14 ,  C08F4/20

    CPC分类号： C07D263/42

    摘要： This invention provides novel azlactone-functional oligomers of 2-alkenyl azlactones in which oligomerization has occurred predominantly via the 2-alkenyl group. Oligomerization of the 2-alkenyl group provides oligomers having 2 to 15 mer units with predominantly carbon-carbon backbone segments. Oligomerized in this fashion, the novel compositions possess azlactone groups which can be reacted with nucleophiles in the normal ring-opening sense. The oligomers are prepared by a novel process in which both Lewis and Bronsted acidic catalysts are effective. The reactive oligomers find utility as crosslinking agents for polymers containing azlactone-reactable nucleophilic groups.

    摘要翻译： 本发明提供2-链烯基吖内酯的新型吖内酯官能低聚物，其中低聚主要通过2-链烯基发生。 2-烯基的低聚提供了具有主要为碳 - 碳骨架链段的2至15个mer单元的低聚物。 以这种方式低聚，新型组合物具有吖内酯基团，其可以以正常的开环方式与亲核试剂反应。 低聚物通过其中Lewis和Bronsted酸性催化剂都有效的新方法制备。 反应性低聚物可用作用于含有吖内酯可反应的亲核基团的聚合物的交联剂。

    Curable acrylamido oligomer compositions with initiator, and cured products
    58.
    发明授权
    Curable acrylamido oligomer compositions with initiator, and cured products 失效
    具有引发剂的固化丙烯酰氨基低聚物组合物和固化产物

    公开(公告)号：US4996243A

    公开(公告)日：1991-02-26

    申请号：US465041

    申请日：1990-01-16

    申请人： Jerald K. Rasmussen ,  Steven M. Heilmann ,  Frederick J. Palensky

    发明人： Jerald K. Rasmussen ,  Steven M. Heilmann ,  Frederick J. Palensky

    IPC分类号： C08F2/50 ,  C08F299/02 ,  C09D4/00 ,  C09J4/00

    CPC分类号： C09D4/00 ,  C08F299/024 ,  C09J4/00

    摘要： A composition of matter comprising an acrylamido-acyl or methacrylamido-acyl oligomer derived from at least one nucleophilic oligomer having at least one amino-, hydroxyl-, or thiol-substituted polyoxyalkylene, polyalkyleneimine, polyester, polyolefin, polyacrylate, or polysiloxane oligomer, said nucleophilic oliogmer having a molecular weight in the range of 200 to 20,000 is disclosed. Also disclosed are free radially polymerizable monomer-containing compositions containing said oligomers as well as acrylamido- and methacrylamido-acylated polymers which are the thermal or photocured products of said oligomers. In addition, a process is disclosed for providing said acrylamido- and methacrylamido-acylated oligomers which are useful, for example, in coatings, films, printing inks, adhesives, and saturants.

    摘要翻译： 包含衍生自至少一种具有至少一个氨基，羟基或硫醇取代的聚氧化烯，聚亚烷基亚胺，聚酯，聚烯烃，聚丙烯酸酯或聚硅氧烷低聚物的亲核低聚物的丙烯酰氨基 - 酰基或甲基丙烯酰氨基 - 酰基低聚物的物质组合物， 公开了分子量在200至20,000范围内的亲核醇。 还公开了含有所述低聚物以及作为所述低聚物的热或光固化产物的丙烯酰氨基和甲基丙烯酰氨基酰化聚合物的自由的可径向聚合的含单体组合物。 此外，公开了一种用于提供所述丙烯酰氨基和甲基丙烯酰氨基酰化的低聚物的方法，其可用于例如涂料，膜，印刷油墨，粘合剂和饱和物。