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公开(公告)号：US08388867B2
公开(公告)日：2013-03-05
申请号：US12855114
申请日：2010-08-12
IPC分类号： H01M4/48
CPC分类号： H01M4/48 , C01G49/00 , C01G49/0018 , C01P2002/72 , C01P2002/85 , C01P2004/04 , C01P2006/40 , H01B1/24 , H01M4/485 , H01M4/623 , H01M4/625 , H01M10/0525 , H01M10/054 , Y02E60/122 , Y02P70/54
摘要： A composition comprising: a metal oxide of a first metal ions and second metal ions; an electrically conductive material; and a binder material. The second metal ions have a higher oxidation state than the first metal ions. The presence of the second metal ion increases the number of metal cation vacancies. A method of: dissolving salts of a first metal ion and a second metal ion in water to form a solution; heating the solution to a temperature of about 80-90° C.; and adding a base to the solution to precipitate nanoparticles of a metal oxide of the first metal ion and the second metal ion.
摘要翻译： 一种组合物，其包含：第一金属离子和第二金属离子的金属氧化物; 导电材料; 和粘合剂材料。 第二金属离子具有比第一金属离子更高的氧化态。 第二金属离子的存在增加了金属阳离子空位的数量。 一种方法：将第一金属离子和第二金属离子的盐溶解在水中以形成溶液; 将溶液加热至约80-90℃的温度; 并向溶液中加入碱以沉淀第一金属离子和第二金属离子的金属氧化物的纳米颗粒。
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公开(公告)号：US20110091723A1
公开(公告)日：2011-04-21
申请号：US12954800
申请日：2010-11-26
申请人： Jeffrey W. Long , Jeffrey C. Owrutsky , Christopher N. Chervin , Debra R. Rolison , Joseph S. Melinger
发明人： Jeffrey W. Long , Jeffrey C. Owrutsky , Christopher N. Chervin , Debra R. Rolison , Joseph S. Melinger
CPC分类号： C23C18/1283 , B82Y30/00 , C01G55/004 , C23C18/1216 , C23C18/1225 , C23C18/1245 , C23C18/1291 , C23C18/1295 , Y10S977/773 , Y10T428/265
摘要： Disclosed herein is an article having: a substrate and a RuO2 coating having nanoparticles of RuO2. Also disclosed herein is an article having: a substrate and a RuO2 coating. The coating is made by: immersing the substrate in a solution of RuO4 and a nonpolar solvent at a temperature that is below the temperature at which RuO4 decomposes to RuO2 and warming the substrate and solution to ambient temperature under ambient conditions to cause the formation of the coating.
摘要翻译： 本文公开了具有：具有RuO 2纳米颗粒的基底和RuO 2涂层的制品。 本文还公开了具有：基底和RuO 2涂层的制品。 涂层是通过以下步骤制成的：将RuO4和非极性溶剂的溶液浸入RuO4分解成RuO 2的温度，并将底物和溶液在环境条件下升温至环境温度，从而形成 涂层。
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53.发明申请公开(公告)号：US20100189991A1
公开(公告)日：2010-07-29
申请号：US12620541
申请日：2009-11-17
申请人： Justin C. Lytle , Jeffrey W. Long , Amanda June Barrow , Matthew Paul Saunders , Debra R. Rolison , Jennifer L. Dysart
发明人： Justin C. Lytle , Jeffrey W. Long , Amanda June Barrow , Matthew Paul Saunders , Debra R. Rolison , Jennifer L. Dysart
CPC分类号： H01B1/04 , C04B35/52 , C04B35/83 , C04B38/0032 , C04B2111/00844 , C04B2235/422 , C04B2235/48 , C04B2235/5248 , Y10T428/249921 , Y10T428/249978 , C04B38/0054
摘要： A method is disclosed to fabricate carbon foams comprising a bicontinuous network of disordered or irregular macropores that are three-dimensionally interconnected via nanoscopic carbon walls. The method accounts for (1) the importance of wetting (i.e., matching the surface energies of fiber to sol) and (2) the viscosity of the microheterogeneous fluid filling the voids in the carbon paper. Carbon fiber papers are mildly oxidized by plasma etching, which greatly enhances the uniform uptake of resorcinol-formaldehyde (RF) mixtures. The RF solutions are oligomerized prior to infiltration and are cured into continuous polymeric webs that hang supported between adjacent carbon fibers; the polymer-fiber composites are pyrolyzed and retain a sponge-like morphology with 10-1000-nm pores and integrated electronic pathways
摘要翻译： 公开了一种制造碳泡沫的方法，其包括通过纳米级碳壁三维互连的无序或不规则大孔的双连续网络。 该方法考虑了（1）润湿的重要性（即，将纤维的表面能量匹配到溶胶）和（2）填充碳纸中的空隙的微不均匀流体的粘度。 碳纤维纸通过等离子体蚀刻轻度氧化，大大增强了间苯二酚 - 甲醛（RF）混合物的均匀摄取。 RF溶液在渗透之前被低聚，并固化成连续的聚合物网，其悬挂在相邻的碳纤维之间; 聚合物纤维复合材料被热解并保留具有10-1000nm孔隙和集成电子通路的海绵状形态
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54.发明申请Carbon nanopipes and ductwork with nanometric walls and methods of making the same 有权具有纳米壁的碳纳米管和管道系统及其制造方法公开(公告)号：US20090047452A1
公开(公告)日：2009-02-19
申请号：US12188285
申请日：2008-08-08
CPC分类号： D03D15/00 , B05D5/12 , B32B1/08 , B82Y30/00 , B82Y40/00 , C01B32/00 , C01B32/05 , C04B35/62873 , C04B35/62897 , C04B2235/5232 , C04B2235/5288 , C04B2235/6028 , C23C16/01 , C23C16/26 , D04H13/00 , H01M4/587 , Y10S427/101 , Y10T428/13 , Y10T428/1303 , Y10T428/1352 , Y10T428/1359 , Y10T428/139 , Y10T428/2918 , Y10T442/3065 , Y10T442/612
摘要： A method of making a carbon nanopipe and ensemble of carbon nanopipes, comprising the steps of flowing a carbon precursor over silica fibers and thereby depositing a durable graphitizable carbon coating of tunable thickness of about 10-500 nm onto the silica fibers and etching away the silica fibers to yield a three-dimensional mat of electronically networked, hollow carbon tubules. A carbon nanopipe comprising a durable graphitizable carbon wall of tunable thickness of about 10-500 nm formed by exposing a silica fiber network to a carbon precursor vapor and thereby depositing a carbon film onto the silica fiber network at a temperature suitable for complete pyrolysis of the carbon precursor and removing the silica fibers.
摘要翻译： 一种制备碳纳米管和碳纳米管组合的方法，包括以下步骤：使碳前体在二氧化硅纤维上流动，从而在二氧化硅纤维上沉积约10-500nm可调厚度的耐用石墨化碳涂层并蚀刻除去二氧化硅 纤维，以产生电子网络化的中空碳素管的三维垫。 一种碳纳米管，其包括通过将二氧化硅纤维网络暴露于碳前体蒸气而形成的可调厚度为约10-500nm的耐久石墨化碳壁，从而在适于完全热分解的温度下将碳膜沉积到二氧化硅纤维网上 碳前体并除去二氧化硅纤维。
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55.发明申请Electroless deposition of nanoscale manganese oxide on ultraporous carbon nanoarchitectures 审中-公开纳米级氧化锰在超高碳纳米结构上的无电沉积公开(公告)号：US20080248192A1
公开(公告)日：2008-10-09
申请号：US11826361
申请日：2007-07-13
CPC分类号： H01M4/583 , B82Y30/00 , H01G11/30 , H01G11/32 , H01M4/1391 , H01M4/1393 , H01M2004/021 , H01M2004/023 , Y02E60/13 , Y10T29/43
摘要： A method of forming a composite comprising the steps of providing a porous carbon structure comprising a surface and pores and infiltrating the structure with a coating comprising MnO2 without completely filling or obstructing a majority of the pores. A method of storing charge comprising the steps of providing a capacitor comprising an anode, a cathode, and an electrolyte, wherein the anode, the cathode, or both comprise a composite comprising a porous carbon structure comprising a surface and pores and a coating on the surface comprising MnO2 wherein the coating does not completely fill or obstruct a majority of the pores and a current collector in electrical contact with the composite, and charging the capacitor.
摘要翻译： 一种形成复合材料的方法，包括以下步骤：提供包含表面和孔隙的多孔碳结构，并用包含MnO 2的涂层渗透该结构，而不完全填充或阻挡大部分孔。 一种存储电荷的方法，包括提供包括阳极，阴极和电解质的电容器的步骤，其中阳极，阴极或两者包括包含多孔碳结构的复合体，所述多孔碳结构包括表面和孔，以及涂层 包括MnO 2 SiO 2的表面，其中涂层不完全填充或阻挡大部分孔，并且集电器与复合材料电接触，并对电容器充电。
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56.发明授权Carbon nanoarchitectures with ultrathin, conformal polymer coatings for electrochemical capacitors 有权碳纳米结构与电化学电容器的超薄，保形聚合物涂层公开(公告)号：US07255924B2
公开(公告)日：2007-08-14
申请号：US10756887
申请日：2004-01-13
申请人： Jeffrey W. Long , Debra R. Rolison
发明人： Jeffrey W. Long , Debra R. Rolison
IPC分类号： B32B9/00
CPC分类号： C25D13/12 , H01G11/26 , H01G11/36 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T428/29 , Y10T428/30
摘要： A composite having an electroactive polymer coating on a porous carbon structure is disclosed. The composite may be used in capacitor electrodes. The composite may be made by self-limiting electropolymerization of a monomer on the carbon structure.
摘要翻译： 公开了一种在多孔碳结构上具有电活性聚合物涂层的复合材料。 复合材料可用于电容器电极。 复合材料可以通过单体在碳结构上的自限电聚合来制备。
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57.发明授权Silica mesoporous aerogels having three-dimensional nanoarchitecture with colloidal gold-protein superstructures nanoglued therein 有权具有三维纳米结构的硅胶介孔气凝胶与胶体金 - 蛋白质超结构纳米凝胶公开(公告)号：US07238729B2
公开(公告)日：2007-07-03
申请号：US10923151
申请日：2004-08-18
CPC分类号： C12N11/14 , C07K14/80 , Y10T428/2991
摘要： This disclosure describes the first viable non-enzyme protein encapsulated within an aerogel. In this, a large excess of cyt c is added to a commercial buffered Au sol solution ( ) which results in the formation of a gold˜protein-protein superstructure in the absence of separation techniques which destroy the superstructure.The gold˜protein-protein superstructure is then nanoglued into a silica framework during the sol to gel transition. To form the gel, the Au˜cyt. c superstructure in buffered medium is added to a silica sol and the composite gels are washed with acetone followed by liquid carbon dioxide and then supercritically dried to form the aerogel.The biocomposite aerogels have a multiplicity of applications particularly in the realm of sensing and energy transformation.
摘要翻译： 本公开描述了包封在气凝胶内的第一种可行的非酶蛋白。 在这种情况下，大量过量的cyt c被添加到商业缓冲Au溶液（）中，这导致在没有破坏上层结构的分离技术的情况下形成金 - 蛋白质 - 蛋白质上层结构。 然后，金 - 蛋白质 - 蛋白质上层结构在溶胶凝胶转变过程中纳米晶化成二氧化硅框架。 为了形成凝胶，Au〜cyt。 将缓冲介质中的c上层结构加入二氧化硅溶胶中，并用丙酮洗涤复合凝胶，然后用液态二氧化碳洗涤，然后超临界干燥形成气凝胶。 生物复合气凝胶具有多种应用，特别是在感测和能量转化领域。
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公开(公告)号：US5397447A
公开(公告)日：1995-03-14
申请号：US156752
申请日：1993-11-24
CPC分类号： B01J35/0033 , B01J19/087
摘要： In a system and method for enhancing chemical reactions, a reactant is brought in contact with a stable, non-soluble, porous, electronically non-conductive solid (reaction enhancer) in a fluidic medium to form a reaction mixture of low ionic strength. The reaction mixture so formed is then subjected to an electrifying force thereby enhancing the chemical reaction. Reaction products are then collected.
摘要翻译： 在用于增强化学反应的系统和方法中，使反应物与流体介质中的稳定的，不可溶的多孔的电子非导电固体（反应增强剂）接触以形成低离子强度的反应混合物。 然后将如此形成的反应混合物进行通电，从而增强化学反应。 然后收集反应产物。
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