SYSTEMS AND METHODS FOR DIESEL OXIDATION CATALYST WITH DECREASED SO3 EMISSIONS
    52.
    发明申请
    SYSTEMS AND METHODS FOR DIESEL OXIDATION CATALYST WITH DECREASED SO3 EMISSIONS 审中-公开
    具有减少的SO3排放的柴油氧化催化剂的系统和方法

    公开(公告)号:US20160030885A1

    公开(公告)日:2016-02-04

    申请号:US14793252

    申请日:2015-07-07

    Abstract: A diesel oxidation catalyst (DOC) catalytic converter for at least the conversion of carbon monoxide and hydrocarbons, removal of a fraction of particulate matter, and decrease of sulfur trioxide emissions within exhaust gases from an engine and consequently of sulfuric acid, is disclosed. The DOC may include any suitable configuration including at least a substrate and a washcoat, where the substrate has a plurality of channels, suitable porosity, offers a three-dimensional support for the washcoat, and is made of any suitable material. The washcoat may be deposited on the substrate by any suitable method, and may include a mixture of at least one or more carrier material oxides and one or more catalysts. Suitable materials for the carrier material oxides may include titanium dioxide, tin dioxide, and zirconium dioxide, among others, excluding aluminum oxide (Al2O3), which may serve for a decrease of sulfur trioxide emissions and consequently of sulfuric acid mist. Suitable catalysts within the washcoat may include platinum, palladium, rhodium, and iridium, among others.

    Abstract translation: 公开了一种柴油氧化催化剂(DOC)催化转化器,用于至少转化一氧化碳和烃,去除一部分颗粒物质,以及减少来自发动机和因此的硫酸的废气中的三氧化硫排放。 DOC可以包括至少包括基材和修补基面涂层的任何合适的构型,其中基底具有多个通道,合适的孔隙率为修补基面涂层提供三维支撑,并由任何合适的材料制成。 修补基面涂层可以通过任何合适的方法沉积在基底上,并且可以包括至少一种或多种载体材料氧化物和一种或多种催化剂的混合物。 用于载体材料氧化物的合适材料可以包括二氧化钛,二氧化锡和二氧化锆,其中除了氧化铝(Al 2 O 3)以外,其可以用于减少三氧化硫排放物,从而导致硫酸雾。 修补基面涂层中的合适的催化剂可包括铂,钯,铑和铱等。

    System and Apparatus for a Laboratory Scale Reactor
    53.
    发明申请
    System and Apparatus for a Laboratory Scale Reactor 审中-公开
    实验室规模反应堆的系统和装置

    公开(公告)号:US20150316524A1

    公开(公告)日:2015-11-05

    申请号:US14800216

    申请日:2015-07-15

    CPC classification number: G01N33/0073 G01N31/10

    Abstract: The present disclosure may include a device for testing catalysts, and a method for controlling the flow rate and temperature parameters during the process. The device may separate mass flow control through heating elements from the mass flow through the sample, as well as separate banks for mixing oxidizing elements, carbon dioxide, and diluent gas as well as reducing agents, nitric oxide, and diluent gas. The device disclosed here may also use mass control units of a sufficiently high speed so as to allow the desired testing conditions.

    Abstract translation: 本公开可以包括用于测试催化剂的装置,以及用于在该过程期间控制流速和温度参数的方法。 该装置可以通过加热元件从通过样品的质量流中分离出质量流量控制,以及用于混合氧化元素,二氧化碳和稀释气体以及还原剂,一氧化氮和稀释气体的单独的组。 这里公开的装置还可以使用足够高速度的质量控制单元,以便允许期望的测试条件。

    Method for Improving Lean Performance of PGM Catalyst Systems: Synergized PGM
    54.
    发明申请
    Method for Improving Lean Performance of PGM Catalyst Systems: Synergized PGM 有权
    提高PGM催化剂体系精益性能的方法:协同PGM

    公开(公告)号:US20150147251A1

    公开(公告)日:2015-05-28

    申请号:US14500387

    申请日:2014-09-29

    Abstract: Synergized Platinum Group Metals (SPGM) catalyst system for TWC application is disclosed. Disclosed SPGM catalyst system may include a washcoat with a Cu—Mn spinel structure and an overcoat that includes PGM supported on carrier material oxides, such as alumina. SPGM catalyst system shows significant improvement in nitrogen oxide reduction performance under stoichiometric operating conditions and especially under lean operating conditions, which allows a reduced consumption of fuel. Additionally, disclosed SPGM catalyst system also enhances the reduction of carbon monoxide and hydrocarbon within catalytic converters. Furthermore, disclosed SPGM catalyst systems are found to have enhanced catalyst activity compared to commercial PGM catalyst system, showing that there is a synergistic effect among PGM catalyst and Cu—Mn spinel within the disclosed SPGM catalyst system.

    Abstract translation: 公开了用于TWC应用的协同铂族金属(SPGM)催化剂体系。 公开的SPGM催化剂体系可以包括具有Cu-Mn尖晶石结构的修补基面涂层和包含负载在载体材料氧化物如氧化铝上的PGM的外涂层。 SPGM催化剂体系在化学计量操作条件下,特别是在稀薄的操作条件下显示出氮氧化物还原性能的显着改善,这允许减少燃料消耗。 另外,所公开的SPGM催化剂体系还增强了催化转化器中一氧化碳和碳氢化合物的还原。 此外,发现所公开的SPGM催化剂体系与商业PGM催化剂体系相比具有增强的催化剂活性,表明在所公开的SPGM催化剂体系内PGM催化剂和Cu-Mn尖晶石之间具有协同效应。

    Thermally Stable Compositions of OSM Free of Rare Earth Metals
    55.
    发明申请
    Thermally Stable Compositions of OSM Free of Rare Earth Metals 有权
    不含稀土金属的OSM的热稳定组合物

    公开(公告)号:US20150105246A1

    公开(公告)日:2015-04-16

    申请号:US14333846

    申请日:2014-07-17

    Abstract: The effect of aging temperature on oxygen storage materials (OSM) substantially free from platinum group (PGM) and rare earth (RE) metals is disclosed. Samples of ZPGM-ZRE metals OSM, hydrothermally aged at a plurality of high temperatures are found to have significantly high oxygen storage capacity (OSC) and phase stability than conventional PGM catalysts with Ce-based OSM. ZPGM-ZRE metals OSM includes a formulation of Cu—Mn stoichiometric spinel structure deposited on Nb—Zr oxide support and may be converted into powder to be used as OSM application or coated onto catalyst substrate. ZPGM-ZRE metals OSM, after aging condition, presents enhanced level of thermal stability and OSC property which shows improved catalytic activity than conventional PGM catalysts including Ce-based OSM. ZPGM-ZRE metals OSM may be suitable for a vast number of applications, and more particularly in underfloor catalyst systems.

    Abstract translation: 公开了老化温度对基本上不含铂族(PGM)和稀土(RE)金属的储氧材料(OSM)的影响。 发现在多个高温下水热老化的ZPGM-ZRE金属OSM样品具有比具有Ce基OSM的常规PGM催化剂显着高的储氧能力(OSC)和相稳定性。 ZPGM-ZRE金属OSM包括沉积在Nb-Zr氧化物载体上的Cu-Mn化学计量的尖晶石结构的配方,并且可以转化为粉末以用作OSM应用或涂覆到催化剂衬底上。 ZPGM-ZRE金属OSM在老化条件下表现出比常规PGM催化剂(包括Ce基OSM)更高的热稳定性和OSC性能,其显示出更好的催化活性。 ZPGM-ZRE金属OSM可能适用于广泛的应用,尤其适用于地板下的催化剂体系。

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