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公开(公告)号:US20200308382A1
公开(公告)日:2020-10-01
申请号:US16768176
申请日:2018-12-07
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Johannes Peter Antonius Martens , Jana Hrachova , Lidia Jasinska-Walc , Ronald Julianus Peter Schipper , Robbert Duchateau
IPC: C08L23/12 , B32B7/12 , B32B27/08 , B32B27/32 , B32B27/20 , B29C71/04 , B29C65/48 , B29C65/00 , B62D25/14 , B62D33/023 , B62D29/04 , E05B85/10
Abstract: The invention relates to a composition comprising a) a propylene homopolymer and/or a propylene copolymer consisting of at least 70.0 wt % of propylene monomer units and at most 30.0 wt % of comonomer units selected from ethylene monomer units and α-olefin monomer units having 4 to 10 carbon atoms, b) an optional ethylene-α-olefin copolymer, c) glass fibers and d) a reaction product of d1) a functionalized polypropylene and d2) a polyetheramine, wherein the total amount of a) and b) is 10.0 to 80.0 wt % or 20.0 to 80.0 wt % with respect to the total composition, the amount of c) is 5.0 to 50.0 wt % with respect to the total composition, the amount of d2) is at least 5.0 wt % with respect to the total composition and the weight ratio of d2) to d1) is at least 0.050.
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公开(公告)号:US20200262983A1
公开(公告)日:2020-08-20
申请号:US15781628
申请日:2016-11-21
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Robbert Duchateau , Lidia Jasinska-Walc , Miloud Bouyahyi
Abstract: The present invention relates to a process for the preparation of polyolefin-based graft copolymers comprising a first functionalized short chain branched polyolefin block and one or multiple polymer side chains. The functionalized short chain branched polyolefin is produced via the copolymerization of an olefin monomer and an olefin bearing a main group metal hydrocarbyl functionality. Subsequently the graft copolymers according to the invention can be produced for example by ring-opening polymerization of cyclic monomers or by transesterification of a preformed transesterifiable polymer, especially polyesters or polycarbonates. The invention moreover relates to polyolefin-based graft copolymers obtained by said process.
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公开(公告)号:US10550254B2
公开(公告)日:2020-02-04
申请号:US15576341
申请日:2016-05-18
Applicant: SABIC Global Technologies B.V.
Inventor: Robbert Duchateau , Jelle Terpsma , Henrica Norberta Alberta Maria Steenbakkers-Menting , Lidia Jasinska-Walc , Miloud Bouyahyi
Abstract: The present invention relates to a composition comprising: a heterophasic polypropylene containing i) a matrix phase of a propylene homopolymer and/or a propylene copolymer with up to 3 wt. % of ethylene and/or at least one C4-C8 α-olefin, the wt. % based on the weight of the copolymer and ii) a disperse phase of an ethylene-C3-C8 α-olefin copolymer, wherein the ethylene content is at least 40 wt. % based on the weight of the ethylene-C3-C8 α-olefin copolymer, one or more of a compatibilizer, wherein the compatibilizer is i) a non-aromatic polyester having an average M/E ratio of at least 10 and/or ii) a block copolymer comprising a polypropylene block and a polyester block, said polyester being a non-aromatic polyester and having an average M/E ratio of at least 10, wherein M is the number of backbone carbon atoms in the polyester, not including the carbonyl carbons and E is the number of ester groups in the polyester.
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公开(公告)号:US10533075B2
公开(公告)日:2020-01-14
申请号:US15537226
申请日:2015-12-17
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Lidia Jasinska-Walc , Miloud Bouyahyi , Robbert Duchateau , Lukasz Szymon Rutkowski , Arkadiusz Zych
IPC: C08G81/02
Abstract: The present invention relates to a process for the preparation of a block copolymer comprising a first type of polyolefin block and at least one type of second polymer block, the process comprising the steps of: A) polymerizing at least one type of olefin monomer using a catalyst system to obtain a first polyolefin block containing a main group metal on at least one chain end; the catalyst system comprising: i) a metal catalyst or metal catalyst precursor comprising a metal from Group 3-10 of the IUPAC Periodic Table of elements; and ii) at least one type of chain transfer agent; and iii) optionally a co-catalyst; B) reacting the first polyolefin block containing a main group metal on at least one chain end obtained in step A) with at least one type of oxidizing agent and subsequently at least one type of metal substituting agent to obtain a first polyolefin block containing at least one functionalized chain end; C) forming at least one second polymer block on the first polyolefin block, wherein as an initiator the functionalized chain end of the first polyolefin block obtained in step B) is used to obtain the block copolymer.
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公开(公告)号:US10450450B2
公开(公告)日:2019-10-22
申请号:US15576339
申请日:2016-05-18
Applicant: SABIC Global Technologies B.V.
Inventor: Robbert Duchateau , Lidia Jasinska-Walc , Miloud Bouyahyi , Deliani Lovera , Maria Soliman
Abstract: The present invention relates to a composition comprising polypropylene, polyethylene and a compatibiliser, wherein said compatibiliser is a block copolymer comprising a polypropylene block and a polyester block, said polyester being a non-aromatic polyester and having an average M/E ratio of at least 10, wherein M is the number of backbone carbon atoms in the polyester not including the carbonyl carbons and E is the number of ester groups in the polyester.
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公开(公告)号:US20180179368A1
公开(公告)日:2018-06-28
申请号:US15576336
申请日:2016-05-18
Applicant: SABIC Global Technologies B.V.
Inventor: Lidia Jasinska-Walc , Robbert Duchateau , Miloud Bouyahyi , Piotr Wisniewski , Marta Urszula Przybysz , Mateusz Krzysztof Kozak , Magdalena Malec
IPC: C08L23/12
CPC classification number: C08L23/12 , C08L23/06 , C08L2205/02 , C08L2205/03 , C08L2205/08 , C08L2207/066 , C08L67/00
Abstract: The present invention relates to a composition comprising polypropylene, polyethylene and a compatibiliser, wherein said compatibiliser is a non-aromatic polyester having an average M/E ratio of at least 10, wherein M is the number of backbone carbon atoms in the polyester not including the carbonyl carbons and E is the number of ester groups in the polyester.
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公开(公告)号:US20170349710A1
公开(公告)日:2017-12-07
申请号:US15537226
申请日:2015-12-17
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Lidia Jasinska-Walc , Miloud Bouyahyi , Robbert Duchateau , Lukasz Szymon Rutkowski , Arkadiusz Zych
IPC: C08G81/02
Abstract: The present invention relates to a process for the preparation of a block copolymer comprising a first type of polyolefin block and at least one type of second polymer block, the process comprising the steps of: A) polymerizing at least one type of olefin monomer using a catalyst system to obtain a first polyolefin block containing a main group metal on at least one chain end; the catalyst system comprising: i) a metal catalyst or metal catalyst precursor comprising a metal from Group 3-10 of the IUPAC Periodic Table of elements; and ii) at least one type of chain transfer agent; and iii) optionally a co-catalyst; B) reacting the first polyolefin block containing a main group metal on at least one chain end obtained in step A) with at least one type of oxidizing agent and subsequently at least one type of metal substituting agent to obtain a first polyolefin block containing at least one functionalized chain end; C) forming at least one second polymer block on the first polyolefin block, wherein as an initiator the functionalized chain end of the first polyolefin block obtained in step B) is used to obtain the block copolymer.
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公开(公告)号:US20170320988A1
公开(公告)日:2017-11-09
申请号:US15537234
申请日:2015-12-17
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Lidia Jasinska-Walc , Robbert Duchateau , Miloud Bouyahyi , Lukasz Szymon Rutkowski , Shaneesh Vadake Kulangara , Arkadiusz Zych
IPC: C08F255/02
CPC classification number: C08F255/02 , C08F4/65912 , C08F216/04 , C08F216/10 , C08G63/08 , C08G64/18 , C08F210/06 , C08F4/65927 , C08F216/02 , C08F2500/15
Abstract: The present invention relates to a process for the preparation of a graft copolymer comprising a polyolefin main chain and one or multiple polymer side chains, the process comprising the steps of: copolymerizing at least one first type of olefin monomer and at least one second type of metal-pacified functionalized olefin monomer to obtain a polyolefin main chain having one or multiple metal-pacified functionalized short chain branches, and reacting the polyolefm main chain having one or multiple metal-pacified functionalized short chain branches with at least one metal substituting agent to obtain a polyolefin main chain having one or multiple functionalized short chain branches; and fonning one or multiple polymer side chains on the polyolefin main chain, wherein as initiators the functionalized short chain branches on the polyolefin main chain are used to obtain the graft copolymer. The invention also relates to the products obtained therefrom.
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