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    Olefin functionalization by metathesis reaction
    32.
    发明授权
    Olefin functionalization by metathesis reaction 有权
    烯烃通过复分解反应进行功能化

    公开(公告)号：US08283419B2

    公开(公告)日：2012-10-09

    申请号：US12488093

    申请日：2009-06-19

    Applicant: John R. Hagadorn ,  Matthew W. Holtcamp ,  Andrew G. Narvaez, Jr. ,  Donna J. Crowther ,  Patrick Brant

    Inventor： John R. Hagadorn ,  Matthew W. Holtcamp ,  Andrew G. Narvaez, Jr. ,  Donna J. Crowther ,  Patrick Brant

    IPC: C08F255/00 ,  C08F255/02 ,  C08F210/06 ,  C08F110/06

    CPC classification number: C08F210/06 ,  C08F210/16 ,  C08F220/06 ,  C08F220/14 ,  C08F255/02 ,  C08F2500/20 ,  C08F2500/02

    Abstract: This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)−83), when 70 to 90 mol % ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum.

    Abstract translation: 本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（加入的乙烯的摩尔％）+100），当共聚物中存在10至60mol％的乙烯时 - 低聚物，和2）X = 45，当共聚低聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83×（摩尔乙烯加入）-83），当70〜 共聚低聚物中存在90mol％的乙烯。 本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

    Metathesis catalyst and process for use thereof
    34.
    发明授权
    Metathesis catalyst and process for use thereof 有权
    复分解催化剂及其使用方法

    公开(公告)号：US08063232B2

    公开(公告)日：2011-11-22

    申请号：US12939054

    申请日：2010-11-03

    Applicant: John R. Hagadorn ,  Matthew W. Holtcamp ,  Matthew S. Bedoya

    Inventor： John R. Hagadorn ,  Matthew W. Holtcamp ,  Matthew S. Bedoya

    IPC: C07D207/04

    CPC classification number: C07F15/0046 ,  C07D207/06 ,  C10G3/00 ,  C10G2300/1014 ,  C10G2300/1088 ,  C10G2400/20 ,  C10G2400/22 ,  Y02E50/13

    Abstract: This invention relates to a catalyst compound comprising a combination of a cyclic alkyl amino carbene ligand and a benzylidene both attached to a Group 8 metal, preferably ruthenium atom.This invention also relates to a process to make linear alpha-olefins comprising contacting a feed material and an optional alkene (such as ethylene) with the catalyst described above, wherein the feed material is a triacylglyceride, fatty acid, fatty acid alkyl ester, and/or fatty acid ester, typically derived from seed oil (e.g., biodiesel).

    Abstract translation: 本发明涉及包含环烷基氨基卡宾配体和亚苄基的组合的催化剂化合物，它们都附着在第8族金属，优选钌原子上。 本发明还涉及制备线性α-烯烃的方法，包括使进料和任选的烯烃（如乙烯）与上述催化剂接触，其中进料是甘油三酯，脂肪酸，脂肪酸烷基酯和 /或脂肪酸酯，通常衍生自种子油（例如，生物柴油）。

    Olefin Functionalization By Metathesis Reaction
    35.
    发明申请
    Olefin Functionalization By Metathesis Reaction 有权
    烯烃功能化通过复分解反应

    公开(公告)号：US20090318647A1

    公开(公告)日：2009-12-24

    申请号：US12488093

    申请日：2009-06-19

    Applicant: John R. Hagadorn ,  Matthew W. Holtcamp ,  Andrew G. Narvaez, JR. ,  Donna J. Crowther ,  Patrick Brant

    Inventor： John R. Hagadorn ,  Matthew W. Holtcamp ,  Andrew G. Narvaez, JR. ,  Donna J. Crowther ,  Patrick Brant

    IPC: C08F4/80 ,  C08F118/02 ,  C08F210/02 ,  C08F220/06 ,  C08F4/72

    CPC classification number: C08F210/06 ,  C08F210/16 ,  C08F220/06 ,  C08F220/14 ,  C08F255/02 ,  C08F2500/20 ,  C08F2500/02

    Abstract: This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)−83), when 70 to 90 mol % ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum.

    Abstract translation: 本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（加入的乙烯的摩尔％）+100），当共聚物中存在10至60mol％的乙烯时 - 低聚物，和2）X = 45，当共聚低聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83×（摩尔乙烯加入）-83），当70〜 共聚低聚物中存在90mol％的乙烯。 本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

    Semi-Rigid Linked Diamines, Precursors Therefor, And Transition Metal Diamido Complexes As Catalysts For Olefin Polymerization Processes
    36.
    发明申请
    Semi-Rigid Linked Diamines, Precursors Therefor, And Transition Metal Diamido Complexes As Catalysts For Olefin Polymerization Processes 有权
    半刚性连接二胺，其前体和过渡金属二酰胺配合物作为烯烃聚合方法的催化剂

    公开(公告)号：US20090259085A1

    公开(公告)日：2009-10-15

    申请号：US12103355

    申请日：2008-04-15

    Applicant: John R. Hagadorn

    Inventor： John R. Hagadorn

    IPC: C07D311/82 ,  C07C2/08 ,  B01J31/16

    CPC classification number: C07F7/10 ,  B01J31/1805 ,  B01J2231/20 ,  B01J2531/0241 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/64072 ,  C08F2500/03 ,  C08F210/14

    Abstract: The invention relates to a process for producing a complex for use in olefin polymerization and oligomerization of the general formula (III): wherein Mt is a group 3 to 12 element in a +2 to +6 oxidation state with between 1 to 4 additional ligands (anionic and/or neutral) coordinated, wherein R1 and R2 are hydrogen, halogen, alkoxy, or a hydrocarbon group containing between 1 to 12 carbon atoms; E is a group 16 element, preferably O; Z is a direct bond between carbon atoms of the adjacent aromatic rings or a —CR3R4— or —SiR3R4— bridge between those carbon atoms, where R3 and R4 are hydrogen or a hydrocarbon groups with 1 to 10 carbons, R5, R6, R7 and R8 are hydrogen, halogen, alkoxy, or a hydrocarbon group containing between 1 to 10 carbon atoms and J1 and J2 are —NR9R10 or —PR9R10, where R9 is H or SiMe3 group and R10 is selected from a group consisting of alkyl, aryl, substituted aryl, heteroalkyl, and heteroaryl containing between 1 to 30 non-hydrogen atoms through a route involving novel precursors such as compounds represented by the general formula (I) where the various substitution options are adapted to produce the substituents shown for formula (III) above.

    Abstract translation: 本发明涉及一种用于制备用于通式（III）的烯烃聚合和低聚的络合物的方法：其中Mt是+2至+6氧化态的3至12族元素，具有1至4个另外的配体 （阴离子和/或中性）配位，其中R 1和R 2是氢，卤素，烷氧基或含有1至12个碳原子的烃基; E是16族元素，优选O; Z是相邻芳环的碳原子之间的直接键或这些碳原子之间的-CR 3 R 4 - 或-SiR 3 R 4 - 桥，其中R 3和R 4是氢或具有1至10个碳的烃基，R 5，R 6，R 7和 R8是氢，卤素，烷氧基或含有1至10个碳原子的烃基，J1和J2是-NR9R10或-PR9R10，其中R9是H或SiMe3基团，R10选自烷基，芳基， 取代的芳基，杂烷基和含有1至30个非氢原子的杂芳基通过涉及新型前体的途径，例如由通式（I）表示的化合物，其中各种取代选项适于产生式（III）所示的取代基 以上。

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