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    Fibre-reactive dyes, their preparation and their use
    31.
    发明授权
    Fibre-reactive dyes, their preparation and their use 有权
    纤维活性染料，其制备及其用途

    公开(公告)号：US07572301B2

    公开(公告)日：2009-08-11

    申请号：US10592976

    申请日：2005-03-09

    申请人： Athanassios Tzikas ,  Georg Roentgen ,  Hubert Jean Luc Christnacher

    发明人： Athanassios Tzikas ,  Georg Roentgen ,  Hubert Jean Luc Christnacher

    IPC分类号： C09B67/00 ,  C09B62/00

    CPC分类号： C09B62/09 ,  C09B62/475 ,  C09B62/513

    摘要： Reactive dyes of formula wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, D1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D2 has the same definition as D1 or is a radical of formula wherein (Q3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo and Z1 is a radical of formula —SO2—Y   (3a), —NH—CO—(CH2)m—SO2—Y  (3b), —CONH—(CH2)n—SO2—Y  (3c), —NH—CO—CH(Hal)-CH2-Hal  (3d) or —NH—CO—C(Hal)=CH2  (3e), Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.

    摘要翻译： 式的活性染料其中Q1和Q2各自独立于另一个氢或未取代或取代的C1-C4烷基，D1是重氮组分的基团，其本身是单或二偶氮染料或含有这种染料D2 具有与D1相同的定义或其为式（Ⅵ）的基团，其中（Q3）0-3表示0至3个选自卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，羧基和磺基的相同或不同的取代基，Z 1为基团 公式<？in-line-formula description =“In-line Formulas”end =“lead”？> - SO2-Y（3a），<？in-line-formula description =“In-line Formulas”end =“ - 尾数“？> <？in-line-formula description =”In-line formula“end =”lead“？ - NH-CO-（CH2）m-SO2-Y（3b） 描述=“在线公式”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> - CONH-（CH2）n-SO2-Y ），<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> - NH-CO -CH（Hal）-CH 2-Hal（3d） 或<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> - NH-CO- C（Hal）= CH2（3e），<？在线公式描述=“内联式”末端=“尾”→Y是乙烯基或-CH 2 -CH 2 -U基，U是 在碱性条件下是可除去的，m和n各自独立地为数2，3或4，Hal为卤素，适用于染色含纤维素或含酰胺基的纤维材料。

    Mixtures of reactive dyes and their use
    35.
    发明申请
    Mixtures of reactive dyes and their use 审中-公开
    活性染料的混合物及其用途

    公开(公告)号：US20060191082A1

    公开(公告)日：2006-08-31

    申请号：US10544165

    申请日：2004-01-27

    申请人： Athanassios Tzikas ,  Georg Roentgen ,  Herbert Klier

    发明人： Athanassios Tzikas ,  Georg Roentgen ,  Herbert Klier

    IPC分类号： C09B62/00

    CPC分类号： D06P3/66 ,  D06P1/38 ,  D06P3/028 ,  D06P3/58 ,  D06P5/30

    摘要： Dye mixtures comprising a reactive dye having at least one structural unit of formula (1) together with a reactive dye of formula (2), wherein (Q1)0-3 and (Q2)0-3 each independently of the other denote from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo, Z1 and Z2 are each independently of the other a fibre-reactive radical, at least one fibre-reactive radical being contained in the dye of formula (1) and the dye of formula (2) containing at least one fibre-reactive radical Z1 or Z2, are suitable for dyeing cellulosic or nitrogen-containing fibre materials.

    摘要翻译： 包含具有式（1）的至少一个结构单元的反应性染料与式（2）的活性染料一起的染料混合物，其中（Q 1→N 3） 和各自独立地表示0〜3个相同或不同的选自卤素，C 1〜N个取代基的取代基。 C 1 -C 4烷基，C 1 -C 4烷氧基，羧基和磺基，Z 1和Z 2， 另一个纤维反应性基团各自独立地相同，至少一个纤维反应性基团包含在式（1）的染料中，而式（2）的染料含有至少一个纤维 - 反应性基团Z 1或Z 2 2适用于染色纤维素或含氮纤维材料。

    Azo dyes, a process for their preparation and their use in the production of colored plastics or polymeric color particles, and in the dyeing or printing of hydrophobic fiber materials
    36.
    发明授权
    Azo dyes, a process for their preparation and their use in the production of colored plastics or polymeric color particles, and in the dyeing or printing of hydrophobic fiber materials 失效
    偶氮染料，其制备方法及其在生产有色塑料或聚合物着色颗粒中的用途，以及染色或印刷疏水性纤维材料

    公开(公告)号：US07029502B2

    公开(公告)日：2006-04-18

    申请号：US10470040

    申请日：2002-01-18

    申请人： Antoine Clément ,  Anton Andreoli ,  Urs Lauk ,  Athanassios Tzikas

    发明人： Antoine Clément ,  Anton Andreoli ,  Urs Lauk ,  Athanassios Tzikas

    IPC分类号： C09B29/42 ,  D06P1/16

    CPC分类号： C09B29/3639 ,  Y10S8/922

    摘要： The present invention relates to an azo dye of formula wherein D is the radical of a diazo component of the benzene, naphthalene, diphenyl, thiophene, benzothiazole, benzisothiazole, thiadiazole, indazole, benzotriazole, pyrazole, anthraquinone, naphthalic acid imide, chromone, phthalimide or diphenylene oxide series, R1 is an unsubstituted or substituted aryl radical and R2 is an unsubstituted or substituted aryl radical, with the exception of the compounds of formulae (1a) and (1b) to a process for its preparation and to its use in a process for the production of mass-colored plastics or polymeric color particles, and in the dyeing or printing of semi-synthetic or synthetic hydrophobic fiber materials.

    摘要翻译： 本发明涉及下式的偶氮染料，其中D是苯，萘，二苯基，噻吩，苯并噻唑，苯并异噻唑，噻二唑，吲唑，苯并三唑，吡唑，蒽醌，萘二甲酰亚胺，色酮，邻苯二甲酰亚胺的重氮组分 或二苯醚系列，R 1是未取代或取代的芳基，R 2是未取代或取代的芳基，除式（1a）化合物外， 和（1b）的制备方法及其在生产大量着色的塑料或聚合物着色颗粒的方法中的用途，以及在半合成或合成疏水纤维材料的染色或印刷中。

    Fibre-reactive azo dyes, their preparation and their use
    37.
    发明申请
    Fibre-reactive azo dyes, their preparation and their use 失效
    纤维反应偶氮染料，其制备及其用途

    公开(公告)号：US20050241080A1

    公开(公告)日：2005-11-03

    申请号：US10523241

    申请日：2003-07-15

    申请人： Athanassios Tzikas ,  Bernhard Muller ,  Georg Roentgen

    发明人： Athanassios Tzikas ,  Bernhard Muller ,  Georg Roentgen

    IPC分类号： B41J2/01 ,  B41M5/00 ,  C07D251/50 ,  C07D487/22 ,  C07D498/04 ,  C09B62/08 ,  C09B62/09 ,  C09B62/44 ,  C09B62/507 ,  C09B62/513 ,  C09D11/00 ,  D06P1/382 ,  D06P3/66 ,  C09B1/00

    CPC分类号： C09B62/4411

    摘要： Reactive dyes of formula (I), wherein A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, Q1, and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1,-C4alkyl, (Q3)n denotes n substituents selected from the group C1,-C4alkyl, C1-C4alkoxy, halogen and sulfo, X is halogen, 3-carboxypyridin-1-yl, 3-carbamoylpyridin-1-yl, hydroxy, C1-C4alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C1-C4alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms, Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, k is a number 2, 3, 4, 5 or 6, m is a number 0 or 1, and n is a number 0, 1 or 2, with the proviso that when A denotes a monoazo chromophore it is not directly linked to the triazinyl radical through a hydroxynaphthalenesulfonic acid coupling component and does not denote a radical of formula (II), are suitable for dyeing cellulosic or nitrogen-containing fibre materials.

    摘要翻译： 式（I）的活性染料，其中A是单偶氮，多偶氮，金属络合物偶氮，蒽醌，酞菁，甲an或二恶嗪发色团，Q 1和Q 2的基团， 各自独立地为另一个氢或未取代或取代的C 1 -C 4烷基，（Q 3 N）n 表示选自C 1〜C 4烷基，C 1 -C 4烷基的n个取代基， 烷氧基，卤素和磺基，X是卤素，3-羧基吡啶-1-基，3-氨基甲酰基吡啶-1-基，羟基，C 1 -C 4烷氧基 在烷基部分中未被取代或被取代的苯基部分中未被取代或取代的苯氧基，未取代的或在烷基部分被取代的未取代或取代的C 1 -C 4烷基硫基，未取代或取代的氨基， 或可以含有或不含有其它杂原子的N-杂环，Y为乙烯基或基团-CH 2 -CH 2 -NU，U为可以在 碱性条件下，k是nu mber 2，3，4，5或6，m是数字0或1，n是数字0,1或2，条件是当A表示单偶氮发色团时，它不直接与三嗪基直接相连，通过 羟基萘磺酸偶联组分并不表示式（II）的基团，适用于染色纤维素或含氮纤维材料。

    Reactive dyes, their preparation and use
    39.
    发明授权
    Reactive dyes, their preparation and use 失效
    活性染料，其制备和用途

    公开(公告)号：US5984978A

    公开(公告)日：1999-11-16

    申请号：US19635

    申请日：1998-02-06

    申请人： Herbert Klier ,  Athanassios Tzikas

    发明人： Herbert Klier ,  Athanassios Tzikas

    IPC分类号： C09B62/09 ,  D06P3/66 ,  C09B67/26

    CPC分类号： C09B62/09

    摘要： There are described reactive dyes of formula ##STR1## wherein the variables are as defined in the claims. The reactive dyes of formula (1) are suitable especially for dyeing or printing cellulosic fiber materials.

    摘要翻译： 描述了式的活性染料，其中变量如权利要求中所定义。 式（1）的活性染料特别适用于染色或印花纤维素纤维材料。

    Process for dyeing or printing cellulosic fibre materials and novel reactive dyes
    40.
    发明授权
    Process for dyeing or printing cellulosic fibre materials and novel reactive dyes 失效
    染色或印刷纤维素纤维材料和新型活性染料的方法

    公开(公告)号：US5964900A

    公开(公告)日：1999-10-12

    申请号：US100002

    申请日：1998-06-17

    申请人： Edmond Ruhlmann ,  Athanassios Tzikas ,  Herbert Klier

    发明人： Edmond Ruhlmann ,  Athanassios Tzikas ,  Herbert Klier

    IPC分类号： C09B62/513 ,  D06P1/384 ,  D06P3/66 ,  D06P5/00 ,  C09B62/00

    CPC分类号： C09B62/513 ,  D06P1/384 ,  Y10S8/918 ,  Y10S8/921

    摘要： A process for dyeing or printing cellulosic fiber materials, which comprises using at least one reactive dye of formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently of one another hydrogen, halogen, sulfo, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy,R.sub.5 and R.sub.6 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkanoylamino, ureido, or C.sub.1 -C.sub.4 alkoxy which is unsubstituted or substituted in the alkyl moiety by hydroxyl, sulfato or C.sub.1 -C.sub.4 alkoxy,Z.sub.1 and Z.sub.2 are each independently of the other vinyl or the radical --CH.sub.2 --CH.sub.2 --U, andU is a leaving group.

    摘要翻译： 一种用于染色或印刷纤维素纤维材料的方法，其包括使用至少一种下式的活性染料，其中R 1，R 2，R 3和R 4各自独立地为氢，卤素，磺基，C 1 -C 4烷基或C 1 -C 4烷氧基，R 5和 R 6各自独立地为氢，卤素，C 1 -C 4烷基，C 2 -C 4烷酰基氨基，脲基或被烷基部分被羟基，硫酸根或C 1 -C 4烷氧基取代的C 1 -C 4烷氧基，Z 1和Z 2各自独立地为 另一个乙烯基或基团-CH 2 -CH 2 -U，U是离去基团。