摘要:
A method of producing an active material powder includes (i) an attachment step of obtaining a powder including an active material particle, which stores and releases lithium ions at a potential of 4.5 V or higher based on Li, and a coating layer precursor, which is attached to a surface of the active material particle, by attaching an alkoxide solution containing lithium ions and niobium ions to the surface of the active material particle and drying the attached alkoxide solution; and (ii) a heating step of forming a coating layer on the surface of the active material particle by heating the powder obtained in the attachment step to be within a temperature range of 120° C. to 200° C.
摘要:
A sulfide solid electrolyte material contains glass ceramics that contains Li, A, X, and S, and has peaks at 2θ=20.2° and 23.6° in X-ray diffraction measurement with CuKα line. A is at least one kind of P, Si, Ge, Al, and B, and X is a halogen. A method for producing a sulfide solid electrolyte material includes amorphizing a raw material composition containing Li2S, a sulfide of A, and LiX to synthesize sulfide glass, and heating the sulfide glass at a heat treatment temperature equal to or more than a crystallization temperature thereof to synthesize glass ceramics having peaks at 2θ=20.2° and 23.6° in X-ray diffraction measurement with CuKα line, in which a ratio of the LiX contained in the raw material composition and the heat treatment temperature are controlled to obtain the glass ceramics.
摘要:
The object of the present invention is to provide a battery system in which reductive decomposition of a Ge-containing solid electrolyte material is restricted. The present invention attains the object by providing a battery system including a battery and a control apparatus, wherein the battery has a cathode active material layer containing a cathode active material, an anode active material layer containing a Si-containing anode active material, and an electrolyte layer formed between the cathode active material layer and the anode active material layer, at least one of the anode active material layer and the electrolyte layer contains a Ge-containing solid electrolyte material, and the control apparatus is an apparatus to control an electric potential of the Si-containing anode active material so as to be reduction potential or less of the Ge-containing solid electrolyte material.
摘要:
Provided is an all solid state battery having improved charge-discharge capacity. The all solid state battery has a structure in which a current collector layer, an electrode body layer and a solid electrolyte layer are laminated in that order, wherein the electrode body layer has an active material layer and a conductive member, the active material layer contacts the solid electrolyte layer, the conductive member contacts the current collector layer and has a protruding portion, and the protruding portion protrudes towards the solid electrolyte layer from at least a portion of the surface of the current collector layer on the electrode body layer side, and contacts the surface of the active material layer in the direction of thickness thereof.
摘要:
The present invention aims to provide a sulfide solid electrolyte material with favorable ion conductivity, in which charge and discharge efficiency may be inhibited from decreasing. The object is attained by providing a sulfide solid electrolyte material, including: a Li element; a P element; and a S element, characterized in that the material has a peak at a position of 2θ=30.21°±0.50° in X-ray diffraction measurement using a CuKα ray, and the sulfide solid electrolyte material does not substantially include a metallic element belonging to the third group to the sixteenth group.
摘要:
An all-solid-state battery that makes it possible to improve the cycling properties is provided. The all-solid-state battery includes an anode; a cathode; a solid electrolyte layer that is arranged between the anode and the cathode; an anode collector that is connected to the anode; and a cathode collector that is connected to the cathode. In the all-solid-state battery, a metal layer is arranged between the anode and the anode collector and/or between the cathode and the cathode collector, and metal that does not undergo an electrochemical reaction with metal ions under a potential environment where an active material stores and releases the metal ions, and whose percent elongation is no less than 22% is used for the metal layer.
摘要:
The main object of the present invention is to provide a sulfide solid electrolyte material with high Li ion conductivity. The present invention solves the problem by providing a sulfide solid electrolyte material comprising an ion conductor with an ortho-composition, and LiI, characterized in that the sulfide solid electrolyte material is glass with a glass transition point.
摘要:
An object of the present invention is to provide a solid lithium secondary battery in which occurrence of short-circuit is suppressed during charging. The object is attained by providing a solid lithium secondary battery comprising an anode current collector, a solid electrolyte layer, a cathode active material layer, and a cathode current collector in this order, wherein the solid electrolyte layer is provided on a surface of the anode current collector, the solid electrolyte layer contains a sulfide solid electrolyte particle, a surface shape of the solid electrolyte layer, which faces the anode current collector, is formed in correspondence with a surface shape of the anode current collector, and 10-point average roughness (Rz) of the surface of the anode current collector on a solid electrolyte layer side, and 10-point average roughness (Rz) of a surface of the solid electrolyte layer on an anode current collector side are in a range of 1.8 μm to 2.5 μm, respectively.
摘要:
Provided is an all solid state battery system with a high energy density. The all solid state battery system comprises an all solid state battery, and a discharging control unit that controls discharging of the all solid state battery, a cathode active material layer contains a cathode active material particle, and a sulfide solid electrolyte particle, and a ratio (T/t) of an actual thickness “T” of the cathode active material layer to an effective thickness “t” of the cathode active material layer which is calculated by the following Expression satisfies a relationship of 0.01≦T/t≦0.15; t=V/i×κ′ (in which, V represents an operation voltage width (V), i represents a current density (mA/cm2) during discharging, and κ′ represents effective Li ion conductivity (S/cm) of the cathode active material layer).
摘要:
The invention provides a method of producing a solid state lithium battery module in which the occurrence of short circuit caused by dendrites is suppressed. The invention solves this problem by providing a method of producing a solid state lithium battery module, including steps of: a pressing step of pressing a sulfide glass having an ion conductor containing a Li element, a P element, and a S element, and forming a solid electrolyte layer; and a restraining step of restraining a solid state lithium battery including the solid electrolyte layer, using restraining member, wherein, in the pressing step, the solid electrolyte layer is formed such that the average pore radius obtained by a mercury intrusion method is R (μm), and in the restraining step, the solid state lithium battery is restrained such that when the confining pressure is designated as P(MPa), the relationship: P≦−5900R+74 is satisfied.