摘要:
An electrode material for a lithium-ion rechargeable battery of the present invention is an electrode material for a lithium-ion rechargeable battery formed by coating a surface of an electrode active material represented by General Formula LiFexMn1-x-yMyPO4 (here, M represents at least one element selected from Mg, Ca, Co, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, and rare earth elements, 0.05≤x≤1.0, 0≤y≤0.14) with a carbonaceous film, in which an angle of repose is in a range of 35° or more and 50° or less.
摘要:
A method of manufacturing the positive electrode material for a lithium ion secondary battery includes a first step of mixing Li3PO4, LiOH, H3PO4, an Fe source, a Mn source, and an M source to prepare raw material slurry, and a second step of subjecting the raw material slurry to a reaction under a high temperature and a high pressure. In the first step, mixing amounts of Li and P are set to 3.00≦Li/(Fe+Mn+M)≦3.10 and 1.00≦P/(Fe+Mn+M)≦1.10, mixing amounts of LiOH and H3PO4 are set to 0
摘要:
[Problems]To provide an electrode material for a lithium-ion rechargeable battery having a high mass energy density at a low temperature or in a high-speed charge and discharge.[Means for Solving the Problems]An electrode material for a lithium-ion rechargeable battery includes particles which are made of LiFexMn1-w-x-y-zMgyCazAwPO4 (here, A represents at least one element selected from Co, Ni, Zn, Al, and Ga, 0≦w≦0.05, 0.05≦x≦0.35, 0.01≦y≦0.10, and 0.0001≦z≦0.002), have an orthorhombic crystal structure, and have a space group of Pmna, in which a change ratio (V1−V2)/V1 between a lattice volume V1 of LiFexMn1-w-x-y-zMgyCazAwPO4 and a lattice volume V2 of FexMn1-w-x-y-zMgyCazAwPO4 obtained by chemically deintercalating Li from LiFexMn1-w-x-y-zMgyCazAwPO4 is in a range of 0.06 to 0.09.
摘要:
To provide a positive electrode material for lithium ion secondary batteries capable of reducing waste loss, a method of producing the same, a positive electrode for lithium ion secondary batteries and a lithium ion secondary battery which contain the above-described positive electrode material for lithium ion secondary batteries. A positive electrode material for lithium ion secondary batteries, wherein the positive electrode material includes inorganic particles whose surfaces are coated with a carbonaceous film, the inorganic particles being represented by a formula LiFexMn1-x-yMyPO4 (0.05≦x≦1.0, 0≦y≦0.14, where M represents at least one selected from the group consisting of Mg, Ca, Co, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, and rare earth elements), a specific surface area is 6 m2/g to 20 m2/g, a lightness L* is 0 to 40, and a chroma C* is 0 to 3.5.