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公开(公告)号：US07183250B2
公开(公告)日：2007-02-27
申请号：US10464365
申请日：2003-06-17
申请人： Klein A. Rodrigues , Kevin Beairsto
发明人： Klein A. Rodrigues , Kevin Beairsto
CPC分类号： C11D3/3773 , C11D1/22 , C11D1/29 , C11D1/72 , C11D1/83 , C11D3/323 , C11D3/34 , C11D3/3418 , C11D3/37 , C11D3/3765
摘要： The present invention is related to a concentrated surfactant composition containing a hydrophobically modified polymer and/or a hydrotrope. The addition of the polymer or hydrotrope to the concentrated surfactant changes the physical properties of the concentrated surfactant, making it easier to process.
摘要翻译： 本发明涉及含有疏水改性聚合物和/或水溶助长剂的浓缩表面活性剂组合物。 将聚合物或水溶助长剂加入浓缩的表面活性剂改变了浓缩的表面活性剂的物理性质，使其更容易加工。
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公开(公告)号：US06924259B2
公开(公告)日：2005-08-02
申请号：US10124358
申请日：2002-04-17
IPC分类号： C11D3/37 , C11D17/00 , D06M15/263 , D06M15/267 , D06M15/29 , D06M15/356 , D06P5/08 , C11D1/02 , C11D1/66
CPC分类号： D06P5/08 , C11D3/3769 , C11D3/3776 , C11D17/0039 , C11D17/0082 , D06M15/263 , D06M15/267 , D06M15/29 , D06M15/356
摘要： The present invention relates to a detergent composition having from 3 to 75 percent by weight of at least one surfactant; and from 0.01 to 5 percent by weight percent of a copolymer composed of from 25 to 75 mole percent of at least one amine-functional monomer, and from 75 to 25 mole percent of at least one hydrophobic ethylenically unsaturated monomer, wherein said amine-functional monomer is not a quaternized amine, and wherein said copolymer has been at least partially neutralized. The detergent composition having the copolymers provides color protection and anti-pill properties in laundry applications.
摘要翻译： 本发明涉及一种具有3至75重量％的至少一种表面活性剂的洗涤剂组合物; 和0.01至5重量％的由25至75摩尔％的至少一种胺官能单体组成的共聚物和75至25摩尔％的至少一种疏水性烯属不饱和单体，其中所述胺官能团 单体不是季铵化的胺，并且其中所述共聚物已被至少部分中和。 具有共聚物的洗涤剂组合物在洗衣应用中提供了颜色保护和抗丸性质。
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23.发明授权Textile manufacturing and treating processes comprising a hydrophobically modified polymer 失效包含疏水改性聚合物的纺织品制造和处理方法公开(公告)号：US06537327B2
公开(公告)日：2003-03-25
申请号：US09881269
申请日：2001-06-14
申请人： Klein A. Rodrigues
发明人： Klein A. Rodrigues
IPC分类号： D06M13402
CPC分类号： D06P5/158 , D06L1/14 , D06L4/12 , D06M11/40 , D06M15/03 , D06M15/09 , D06M15/227 , D06M15/233 , D06M15/263 , D06M15/27 , D06M15/285 , D06M15/333 , D06M15/353 , D06M15/3562 , D06M15/3566 , D06M15/53 , D06P1/16 , D06P1/228 , D06P1/48 , D06P1/50 , D06P1/5207 , D06P1/5221 , D06P1/5228 , D06P1/5242 , D06P1/525 , D06P1/5257 , D06P1/613 , D06P5/08
摘要： A method to prevent the backstaining of denim during a stonewashing process comprising treating the denim with a solution or dispersion of a hydrophobically modified polymer having a hydrophilic backbone and at least one hydrophobic moiety, wherein said hydrophilic backbone is prepared from at least one monomer selected from the group consisting of ethylenically unsaturated hydrophilic monomer selected from the group consisting of amide, ether, alcohol, aldehyde, anhydride, ketone and ester; polymerizable hydrophilic cyclic monomer; non-ethylenically unsaturated polymerizable hydrophilic monomer which is selected from the group consisting of glycerol and other polyhydric alcohols; and combinations thereof, wherein said hydrophilic backbone is optionally substituted with one or more amino, amine, amide, sulfonate, sulfate, phosphonate, hydroxy, carboxyl or oxide groups; wherein said hydrophobic moiety is prepared from at least one hydrophobic monomer or a chain transfer agent, said hydrophobic monomer is selected from the group consisting of a siloxane, hydrophobic alkoxygroup, alkyl sulfonate, aryl sulfonate, and combinations thereof, and said chain transfer agent has 1 to 24 carbon atoms and is selected from the group consisting of a mercaptan, amine, alcohol, and combinations thereof, wherein said hydrophobically modified polymer is present in an amount of from 0.001 to 50 weight percent, based on the total weight of the solution or dispersion.
摘要翻译： 一种防止在石洗过程中对牛仔布进行背面染色的方法，包括用具有亲水主链和至少一个疏水部分的疏水改性聚合物的溶液或分散体处理牛仔布，其中所述亲水性主链由至少一种选自 由选自酰胺，醚，醇，醛，酸酐，酮和酯的烯属不饱和亲水单体组成的组; 可聚合的亲水环状单体; 非烯属不饱和可聚合亲水单体，其选自甘油和其他多元醇; 其中所述亲水性骨架任选被一个或多个氨基，胺，酰胺，磺酸盐，硫酸盐，膦酸盐，羟基，羧基或氧化物基团取代; 其中所述疏水部分由至少一种疏水性单体或链转移剂制备，所述疏水性单体选自硅氧烷，疏水性烷氧基，烷基磺酸酯，芳基磺酸酯及其组合，所述链转移剂具有 1至24个碳原子，并且选自硫醇，胺，醇及其组合，其中所述疏水改性聚合物的存在量为基于溶液总重量的0.001至50重量％ 或分散体。
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24.发明授权公开(公告)号：US06211299B1
公开(公告)日：2001-04-03
申请号：US09368512
申请日：1999-08-05
IPC分类号： C08F26704
CPC分类号： C11D3/3788 , C08F257/02 , C08F267/02 , C08F267/04 , C08F291/00 , C08L71/02 , C08L2666/04 , C08L2666/24
摘要： In situ solvent free methods for making anhydride based graft copolymers which involve mixing an ethylenically unsaturated monomer, an anhydride monomer, either a monofunctional polyglycol having a hydroxyl or amine terminal group or a polyfunctional polyglycol having a weight average molecular weight of greater than 5,000 and at least one terminal hydroxyl group, and a free radical initiator to form a mixture. The mixture is heated to form a copolymer having repeat units derived from the ethylenically unsaturated monomer and anhydride monomer, and a copolymer grafted polyglycol comprising a main polyglycol backbone having copolymer side chains which are heated to form an anhydride based graft copolymer. The anhydride based graft copolymers are especially useful as soil release agents in detergent formulations.
摘要翻译： 用于制备基于酸酐的接枝共聚物的原位无溶剂方法，其包括将烯键式不饱和单体，酸酐单体，具有羟基或胺末端基团的单官能聚乙二醇或重均分子量大于5,000的多官能聚二醇混合， 至少一个末端羟基和自由基引发剂形成混合物。 将混合物加热以形成具有衍生自烯键式不饱和单体和酸酐单体的重复单元的共聚物，以及包含主要聚乙二醇主链的共聚物接枝聚乙二醇，其具有加热形成基于酸酐的接枝共聚物的共聚物侧链。 基于酸酐的接枝共聚物特别用作洗涤剂配方中的去污剂。
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公开(公告)号：US06180589B2
公开(公告)日：2001-01-30
申请号：US09225809
申请日：1999-01-05
IPC分类号： C11D337
CPC分类号： C11D3/3707 , C08G65/22
摘要： The invention provides novel polyether hydroxycarboxylate copolymers which are effective sequestering agents. The polyether hydroxycarboxylate copolymer when used in a cleaning composition enhances or “builds” the cleaning efficiency of the surfactant by inactivating hardness ions. In addition, the polyether hydroxycarboxylate copolymers assist in cleaning by dispersing and suspending soils to prevent the redeposition of soils. The polyether hydroxycarboxylate copolymer has the structure wherein M+ is a cation wherein M is independently selected from hydrogen, ammonia, alkali metals, alkaline earth metals, zinc, copper, organic amines, amino acids, and amino saccharides; R2 and R3 are independently hydrogen or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms; n is from about 2 to about 100; x1 and x2 are independently 0 or 1; a is from 0 to 99 mole percent; and b is from 100 to 1 mole percent, provided that (a+b) is 100 mole percent.
摘要翻译： 本发明提供了新的聚醚羟基羧酸酯共聚物，它们是有效的螯合剂。 当用于清洁组合物时，聚醚羟基羧酸酯共聚物通过钝化硬度离子增强或“增强”表面活性剂的清洁效率。 此外，聚醚羟基羧酸酯共聚物通过分散和悬浮土壤来帮助清洁以防止土壤的再沉积。 聚醚羟基羧酸酯共聚物具有其中M +是阳离子的结构，其中M独立地选自氢，氨，碱金属，碱土金属，锌，铜，有机胺，氨基酸和氨基糖; R2和R3独立地是氢或取代或未取代的具有1至4个碳原子的烷基; n为约2至约100; x1和x2独立为0或1; a为0〜99摩尔％ b为100〜1摩尔％，条件是（a + b）为100摩尔％。
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26.发明授权Laundry detergents containing styrene-anhydride copolymers grafted with polyethylene glycol 失效洗涤剂含有用聚乙二醇接枝的苯乙烯 - 酐共聚物
公开(公告)号：US6075093A
公开(公告)日：2000-06-13
申请号：US94104
申请日：1998-06-09
申请人： Klein A. Rodrigues
发明人： Klein A. Rodrigues
IPC分类号： C08F2/44 , C08F257/02 , C08F267/02 , C08F267/04 , C08F283/06 , C08F291/00 , C08L71/02 , C11D3/37 , C08L35/06 , D06M15/00
CPC分类号： C11D3/3788 , C08F257/02 , C08F267/02 , C08F267/04 , C08F291/00 , C08L71/02
摘要： A laundry detergent composition comprising a surfactant, builder and from about 0.1 to about 25 weight percent, based on the total weight of the laundry detergent composition, of a styrene-anhydride copolymer grafted with polyethylene glycol which is prepared by reacting in a solvent styrene monomer selected from styrene and substituted styrene, with an anhydride monomer selected from maleic anhydride and itaconic anhydride, to form a styrene-anhydride copolymer which is reacted with polyethylene glycol, to form a styrene-anhydride copolymer grafted with polyethylene glycol. The styrene-anhydride copolymers grafted with polyethylene glycol when used in a laundering process, remove soil from fabrics, inhibit soil deposition on fabrics, and provide soil resistance to fabrics.
摘要翻译： 一种洗衣洗涤剂组合物，其包含表面活性剂，助洗剂和约0.1至约25重量％，基于洗衣洗涤剂组合物的总重量，接枝有聚乙二醇的苯乙烯 - 酐共聚物，其通过在溶剂苯乙烯单体 选自苯乙烯和取代的苯乙烯，与酸酐单体选自马来酸酐和衣康酸酐，形成与聚乙二醇反应的苯乙烯 - 酐共聚物，形成用聚乙二醇接枝的苯乙烯 - 酐共聚物。 当用于洗涤过程中时，用聚乙二醇接枝的苯乙烯 - 酐共聚物，从织物上除去污垢，抑制织物上的污垢沉积，并提供对织物的抗污性。
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公开(公告)号：US6008316A
公开(公告)日：1999-12-28
申请号：US146873
申请日：1998-09-03
IPC分类号： C11D3/26 , C07C279/00 , C07C279/26 , C08G73/00 , C08G73/02 , C11D3/00 , C11D3/37 , C11D3/386 , C11D3/39 , D06M15/61 , D06P1/52 , D06P5/06 , D06P5/08 , C08G12/00 , D06M13/256
CPC分类号： C11D3/386 , C08G73/00 , C08G73/02 , C11D3/0021 , C11D3/3723 , D06P1/5278 , D06P1/5285 , D06P5/06 , D06P5/08 , C11D3/39 , C11D3/3905
摘要： A functionalized polyamine comprising the reaction product of (A) a cyano- or guanidino-containing compound selected from the group consisting of cyanamides or salts thereof, dicyanamides or salts thereof, dicyandiamides or salts thereof, guanidines or salts thereof, biguanidines or salts thereof, and combinations thereof, and (B) a polyamine prepared from at least one monomeric amine, wherein the cyano- or guanidino-functional groups are attached to the polyamine or incorporated therein to form the functionalized polyamine, provided that the monomeric amine and the cyano- or guanidino-containing compound are present in the functionalized polyamine in a molar ratio of from 1.1:1 to 100:1, respectively. The functionalized polyamines are especially useful as anti-dye transfer and color protection agents in laundry detergent compositions.
摘要翻译： 一种官能化多胺，其包含（A）选自氰基或胍基的化合物的反应产物，所述化合物选自氰酰胺或其盐，二氰胺或其盐，双氰胺或其盐，胍或其盐，双胍或其盐， 及其组合，和（B）由至少一种单体胺制备的多胺，其中氰基或胍基官能团连接到多胺或并入其中以形成官能化的多胺，条件是单体胺和氰基 - 或含胍基的化合物分别以1.1:1至100:1的摩尔比存在于官能化的多胺中。 官能化的多胺特别可用作衣物洗涤剂组合物中的抗染料转移和颜色保护剂。
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公开(公告)号：US5421879A
公开(公告)日：1995-06-06
申请号：US242389
申请日：1994-05-13
申请人： Klein A. Rodrigues
发明人： Klein A. Rodrigues
CPC分类号： C09K8/46 , C04B24/2652
摘要： Cement set retarding additives, set retarded hydraulic cement compositions and methods of using the cement compositions for cementing zones in wells are provided. The set retarding additives are copolymers containing monomer units formed from a first monomer of acrylic acid or methacrylic acid and a second monomer of acrylamide or a derivative of acrylamide.
摘要翻译： 提供了水泥减阻添加剂，凝固阻滞水硬性水泥组合物和使用水泥组合物在井中固井区域的方法。 凝固阻滞添加剂是含有由丙烯酸或甲基丙烯酸的第一单体和丙烯酰胺的第二单体或丙烯酰胺的衍生物形成的单体单元的共聚物。
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公开(公告)号：US5398759A
公开(公告)日：1995-03-21
申请号：US171543
申请日：1993-12-21
CPC分类号： C04B24/003 , C04B24/16 , C04B28/02 , C09K8/46 , C04B2111/00146
摘要： Set retarded ultra fine cement compositions which remain pumpable for a predictable period of time at temperatures up to about 400.degree. F. are provided. The compositions are basically comprised of an ultra fine hydraulic cement, sufficient water to form a pumpable slurry and a set retarder comprised of a water soluble aliphatic compound containing at least three carbon atoms and at least one phosphonic acid or phosphonate group.
摘要翻译： 提供在高达约400°F的温度下保持可泵送的可延迟的超细水泥组合物达可预测的时间段。 所述组合物基本上由超细水硬性水泥，足够的水形成可泵送的浆料组成，以及由含有至少三个碳原子的水溶性脂族化合物和至少一种膦酸或膦酸酯基组成的缓凝剂。
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公开(公告)号：US5341881A
公开(公告)日：1994-08-30
申请号：US4325
申请日：1993-01-14
申请人： Klein A. Rodrigues
发明人： Klein A. Rodrigues
CPC分类号： C09K8/46 , C04B24/2652
摘要： Cement set retarding additives, set retarded hydraulic cement compositions and methods of using the cement compositions for cementing zones in wells are provided. The set retarding additives are copolymers containing monomer units formed from a first monomer of acrylic acid or methacrylic acid and a second monomer of acrylamide or a derivative of acrylamide.
摘要翻译： 提供了水泥减阻添加剂，凝固阻滞水硬性水泥组合物和使用水泥组合物在井中固井区域的方法。 凝固阻滞添加剂是含有由丙烯酸或甲基丙烯酸的第一单体和丙烯酰胺的第二单体或丙烯酰胺的衍生物形成的单体单元的共聚物。
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