PROCESS FOR ACYLATION OF A HYDROXYLATED SOLID MATERIAL

    公开(公告)号:US20230265613A1

    公开(公告)日:2023-08-24

    申请号:US18020353

    申请日:2020-08-13

    Inventor: Daniel SAMAIN

    CPC classification number: D21H17/18 D21H21/16 D21H19/12 D21H27/002

    Abstract: A process for acylation of a solid material (3, 9) bearing reactogenic hydroxyls includes at least one fatty acid chloride (1) is distributed at least on the surface of the solid material (3, 9) using a distributor device (2) having an application surface. At least one fatty acid chloride (1) is distributed at least on the surface of the solid material (3, 9) is heated at a temperature, referred to as acylation temperature, below the vaporization temperature of the at least one fatty acid chloride (1), so as to enable an acylation of the solid material (3, 9). A stream of a gaseous composition (6) is directed over the said solid material (3, 9) at the acylation temperature, so as to entrain at least one portion of gaseous hydrochloric acid (7) formed by the acylation reaction
    The application surface of the distributor device (2) is a velvet provided with velvet filiform elements that are suitable for taking up the at least one fatty acid chloride (1) by contact with the at least one fatty acid chloride, and releasing at least one fatty acid chloride by bringing the filiform elements of the velvet into contact with the solid material (3, 9). The distribution step (12, 14) is carried out so as to distribute over the solid material (3, 9) an amount of the at least one fatty acid chloride (1) of between 20 mg/m2 and 1 g/m2 surface area of the solid material (3, 9).

    Method for producing modified cellulose
    13.
    发明授权
    Method for producing modified cellulose 有权
    生产改性纤维素的方法

    公开(公告)号:US09181653B2

    公开(公告)日:2015-11-10

    申请号:US14069171

    申请日:2013-10-31

    Abstract: The present invention provides a method for producing modified nanofibrillated cellulose characterized by bringing cellulosic material into a fiber suspension, adsorbing a cellulose derivative or polysaccharide or polysaccharide derivative onto fibers in said fiber suspension under special conditions and subjecting the obtained fiber suspension derivative to mechanical disintegration. A modified nanofibrillated cellulose obtainable by a method of the present invention is provided. Furthermore, the invention relates to the use of said modified nanofibrillated cellulose.

    Abstract translation: 本发明提供一种生产改性纳米纤维素纤维素的方法,其特征在于将纤维素材料进入纤维悬浮液中,在特殊条件下将纤维素衍生物或多糖或多糖衍生物吸附在所述纤维悬浮液中的纤维上,并使得到的纤维悬浮衍生物进行机械崩解。 提供了通过本发明的方法获得的改性的纳米纤维化纤维素。 此外,本发明涉及所述改性纳米纤维化纤维素的用途。

    Crosslinkable creping adhesive formulations applied to a dryer surface or to a cellulosic fiber
    15.
    发明授权

    公开(公告)号:US06663942B1

    公开(公告)日:2003-12-16

    申请号:US08955733

    申请日:1997-10-22

    Abstract: Disclosed are adhesive formulations as creping process aids for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of adhesive compositions comprising polymers having at least one primary or secondary amine group in the backbone such as chitosan, plolyvinylamine, polyvinyl alcohol-vinyl amine and polyaminoamide in combination with crosslinking agents such as zirconium compounds having a valence of plus four including ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate and sodium zirconium tartrate and creping said treated web from said thermal drying means. In the method for producing the absorbent creped cellulosic sheets, the zirconium crosslinking agent is advantageously applied directly and separately on the Yankee dryer at the time the base polymer is applied to the surface. The crosslinking agent functions to crosslink the polymer to the fibrous web. The absorbent paper products are used as bathroom tissue and towels.

    Abstract translation: 公开了作为起皱加工助剂的粘合剂制剂,其用于生产具有高水平表面感觉柔软性的吸收性起皱纤维素片材,其包括连续地形成纤维素造纸纤维网,通过粘合剂组合物将所述纤维网粘附到热干燥装置,所述粘合剂组合物包含聚合物 在主链中具有至少一个伯胺或仲胺基团,例如壳聚糖,聚乙烯胺,聚乙烯醇 - 乙烯基胺和聚氨基酰胺与交联剂,例如具有四价的锆化合物,包括碳酸锆锆,乙酰丙酮酸锆,乙酸锆 ,碳酸锆,硫酸锆,磷酸锆,碳酸钾锆,磷酸锆钠和酒石酸锆钠,并从所述热干燥装置起皱所述处理的纤维网。 在制造吸收性起皱纤维素片的方法中,锆基交联剂有利地在将基础聚合物施加到表面上时在Yankee干燥器上分开施用。 交联剂用于将聚合物交联至纤维网。 吸水纸产品用作卫生纸和毛巾。

    Manufacture of an Impregnated Paper or Non-Woven
    19.
    发明申请
    Manufacture of an Impregnated Paper or Non-Woven 审中-公开
    浸渍纸或无纺布的制造

    公开(公告)号:US20080199666A1

    公开(公告)日:2008-08-21

    申请号:US11916515

    申请日:2006-06-06

    Abstract: A method for manufacturing an impregnated paper or non-woven substrate (10) for use as or in a decorative laminate, comprises the steps of: (a) applying a monomer or oligomer to a paper or non-woven substrate (10), in a dry process step (20), which monomer or oligomer forms a film and/or filler bound to the substrate; (b) thereafter applying (30) to the substrate (10) having said film and/or filler of monomer or oligomer; a polymer resin compatible with and cross-linkable with the monomer or oligomer; and (c) treating (40) the resin whereby it forms a cross-link bond with the monomer or oligomer.

    Abstract translation: 用于制造用于装饰层压板或装饰层压板的浸渍纸或非织造基材(10)的方法包括以下步骤:(a)将单体或低聚物施加到纸或无纺基底(10)上, 干法加工步骤(20),其中单体或低聚物形成与基材结合的膜和/或填料; (b)然后将(30)施加到具有单体或低聚物的所述膜和/或填料的基材(10)上; 与单体或低聚物相容并可交联的聚合物树脂; 和(c)处理(40)树脂,由此与单体或低聚物形成交联键。

    Crosslinkable creping adhesive formulations
    20.
    发明授权
    Crosslinkable creping adhesive formulations 失效
    可交联起皱粘合剂配方

    公开(公告)号:US06812281B2

    公开(公告)日:2004-11-02

    申请号:US09904102

    申请日:2001-07-13

    Abstract: Disclosed are adhesive formulations as creping process aids for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of adhesive compositions comprising polymers having at least one primary or secondary amine group in the backbone such as chitosan, polyvinylamine, polyvinyl alcohol-vinyl amine and polyaminoamide in combination with crosslinking agents such as dialdehydes or zirconium compounds having a valence of plus four including ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate and sodium zirconium tartrate and creping said treated web from said thermal drying means. In the method for producing the absorbent creped cellulosic sheets, the zirconium crosslinking agent is advantageously applied directly and separately on the Yankee dryer at the time the base polymer is applied to the surface. Alternatively, when using dialdehydes, the dialdehydes are mixed with the base polymer just prior to application to the Yankee dryer surface without having the crosslinking reaction take place with the base polymer prior to reaching the heated Yankee surface. These sheets are useful in the manufacture of tissue and towel.

    Abstract translation: 公开了作为起皱加工助剂的粘合剂制剂,其用于生产具有高水平表面感觉柔软性的吸收性起皱纤维素片材,其包括连续地形成纤维素造纸纤维网,通过粘合剂组合物将所述纤维网粘附到热干燥装置,所述粘合剂组合物包含聚合物 在骨架中具有至少一个伯胺或仲胺基团,例如壳聚糖,聚乙烯胺,聚乙烯醇 - 乙烯基胺和聚氨基酰胺,与交联剂如具有四价的二醛或锆化合物的组合,包括碳酸锆锆,乙酰丙酮酸锆, 乙酸锆,碳酸锆,硫酸锆,磷酸锆,碳酸钾锆,磷酸锆钠和酒石酸锆钠,并从所述热干燥装置起皱所述处理过的纤维网。 在制造吸收性起皱纤维素片的方法中,锆基交联剂有利地在将基础聚合物施加到表面上时在Yankee干燥器上分开施用。 或者,当使用二醛时,二恶醛在施用于扬克烘缸表面之前与基础聚合物混合,而不会在到达加热的扬基表面之前与基础聚合物发生交联反应。 这些片材在组织和毛巾的制造中是有用的。

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