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    Hydroxyaryl functionalized polymers
    13.
    发明授权
    Hydroxyaryl functionalized polymers 有权
    羟基芳基官能化聚合物

    公开(公告)号：US08946355B2

    公开(公告)日：2015-02-03

    申请号：US13381331

    申请日：2010-06-30

    申请人： Yuan-Yong Yan ,  Zengquan Qin ,  Xiao-Dong Pan

    发明人： Yuan-Yong Yan ,  Zengquan Qin ,  Xiao-Dong Pan

    IPC分类号： C08F236/10 ,  C08L15/00 ,  C08L7/00 ,  C08F2/38 ,  C08C19/44

    CPC分类号： C08F2/38 ,  C08C19/44 ,  C08F236/10 ,  C08L7/00 ,  C08L15/00 ,  C08F4/545 ,  C08L2666/08

    摘要： A functionalized polymer includes the reaction product of a reactive polymer and a compound that includes an aryl group having at least one directly bonded OGp substituent, where Gp is a protecting group, and a substituent (Q) which is free of active hydrogen atoms and which is, or connects to the aryl group through, a moiety that includes a carbon-to-nitrogen multiple bond. The polymer can be provided from a solution that includes one or more types of ethylenically unsaturated monomers which include at least one type of polyene, particularly one or more conjugated dienes in certain embodiments. An active terminus of the resulting reactive polymer can react with the Q substituent of the compound so as to provide a polymer having as a terminal functionality the radical of a compound that includes an aryl group having at least one directly bonded OGp substituent.

    摘要翻译： 官能化聚合物包括反应性聚合物和包括具有至少一个直接键合的OGp取代基的芳基的化合物的反应产物，其中Gp是保护基，和不含活性氢原子的取代基（Q），其中 是或通过包含碳 - 氮多键的部分连接到芳基。 聚合物可以由包括一种或多种类型的烯键式不饱和单体的溶液提供，所述烯属不饱和单体在某些实施方案中包括至少一种类型的多烯，特别是一种或多种共轭二烯。 所得反应性聚合物的活性末端可与化合物的Q取代基反应，从而提供具有包含具有至少一个直接键合的OGp取代基的芳基的化合物基团作为末端官能团的聚合物。

    Polycarbonates made using highly selective catalysts
    18.
    发明申请
    Polycarbonates made using highly selective catalysts 有权
    使用高选择性催化剂制备的聚碳酸酯

    公开(公告)号：US20070255039A1

    公开(公告)日：2007-11-01

    申请号：US11812106

    申请日：2007-06-15

    申请人： Geoffrey Coates ,  Zengquan Qin ,  Claire Cohen

    发明人： Geoffrey Coates ,  Zengquan Qin ,  Claire Cohen

    IPC分类号： B01J31/00 ,  C08G67/02

    CPC分类号： C07F15/065 ,  B01J31/1805 ,  B01J2231/14 ,  B01J2531/0252 ,  B01J2531/845

    摘要： Poly(propylene carbonates) are prepared from propylene oxide and CO2 with less than 10% cyclic propylene carbonate by product using cobalt based catalysts of structure preferably in combination with salt cocatalyst, very preferably cocatalyst where the cation is PPN+ and the anion is Cl− or OBzF5−. Novel products include poly(propylene carbonates) having a stereoregularity greater than 90% and/or a regioregularity of greater than 90%.

    摘要翻译： 聚（丙烯碳酸酯）由环氧丙烷和CO 2与小于10％的环状碳酸亚丙酯制成，使用优选结合盐助催化剂的钴基催化剂，非常优选助催化剂，其中阳离子为 PPN + +和 - 阴离子是Cl - O - 或 - O - Z - 。 新产品包括立构规整度大于90％和/或大于90％的区域规整度的聚（丙烯碳酸酯）。