公开(公告)号：US4973477A

公开(公告)日：1990-11-27

申请号：US317501

申请日：1989-03-01

申请人： Osamu Isozaki ,  Naozumi Iwasawa ,  Toshiro Hirama ,  Hiroshi Iwai

发明人： Osamu Isozaki ,  Naozumi Iwasawa ,  Toshiro Hirama ,  Hiroshi Iwai

IPC分类号： C09D5/16

CPC分类号： C09D5/1668

摘要： Disclosed are a coating composition (A) for preventing adhesion of organisms which comprises as its vehicle component a homopolymer or a copolymer, the homopolymer being one prepared by homopolymerizing a phenol-modified unsaturated monomer obtained by reacting (a) an unsaturated monomer containing epoxy group and/or hydroxyl group with (b) an addition reaction product of a phenolic compound with a compound having one carboxylic anhydride group per molecule, and the copolymer being one prepared by copolymerizing said phenol-modified unsaturated monomer and a radically polymerizable unsaturated monomer, and also a coating composition (B) for preventing adhesion of organisms which comprises as its vehicle component a phenol-modified resin prepared by reacting (c) a resin containing epoxy group and/or hydroxyl group with (b) an addition reaction product of a phenolic compound with a compound having one carboxylic anhydride group per molecule.Also disclosed is a method for preventing adhesion of organisms, characterized by coating a substrate with the coating composition (A) or (B).

公开(公告)号：US06303701B1

公开(公告)日：2001-10-16

申请号：US09333024

申请日：1999-06-15

申请人： Osamu Isozaki ,  Shigeo Nishiguchi

发明人： Osamu Isozaki ,  Shigeo Nishiguchi

IPC分类号： C08F812

CPC分类号： C09D201/06

摘要： A stainproof resin composition comprising as an active ingredient a resin having at least one metal carboxylate group represented by the following formula: Rp—COO—M—OH  (A) wherein Rp is a substrate resin and M is a divalent metal atom.

摘要翻译： 一种防污树脂组合物，其包含作为活性成分的具有由下式表示的至少一种金属羧酸盐的树脂：其中Rp为基材树脂，M为二价金属原子。

公开(公告)号：US5882842A

公开(公告)日：1999-03-16

申请号：US800214

申请日：1997-02-12

申请人： Yu Akaki ,  Fumio Yamashita ,  Yasuo Takaya ,  Osamu Isozaki

发明人： Yu Akaki ,  Fumio Yamashita ,  Yasuo Takaya ,  Osamu Isozaki

IPC分类号： C08F2/46 ,  C08G59/68 ,  C08G65/14 ,  C08G65/18 ,  C09D133/06

CPC分类号： C08G65/18 ,  C08G59/68 ,  C08G65/14 ,  C09D133/068

摘要： An active energy ray-curable resin composition, particularly an active energy ray-curable coating composition, both comprising:(A) a resin having oxetane functional groups and epoxy groups in the molecule, and(B) a photo-induced cationic polymerization initiator.

摘要翻译： 一种活性能量射线固化性树脂组合物，特别是活性能量射线固化型涂料组合物，其特征在于，其包含：（A）分子中具有氧杂环丁烷官能团的树脂和环氧基，（B）光诱导性阳离子聚合引发剂。

公开(公告)号：US5635572A

公开(公告)日：1997-06-03

申请号：US548698

申请日：1995-10-26

申请人： Kazuhiko Ohnishi ,  Hirokazu Terashima ,  Osamu Isozaki

发明人： Kazuhiko Ohnishi ,  Hirokazu Terashima ,  Osamu Isozaki

IPC分类号： B05D3/10 ,  C09D5/16 ,  C09D7/12 ,  C09D127/12 ,  C09D161/20 ,  C09D175/04 ,  C08F283/04

CPC分类号： C09D7/125 ,  B05D3/107 ,  C09D175/04 ,  C09D7/1233 ,  C08K5/5415 ,  Y10S525/934 ,  Y10T428/31551

摘要： The present invention provides a topcoating composition prepared by incorporating a specified organosilicate and/or its condensate into a specified organic coating composition, a film formed from said topcoating composition being such that a surface of the film, which has been subjected to an acid treatment, shows a contact angle to water of 70.degree. or less; and a film-forming process which comprises coating said topcoating composition onto a substrate to form a film, followed by treating the surface of the film with an acid. The present invention provides such effects that the film obtained according to the present invention shows good weather resistance and good stain resistance.

摘要翻译： 本发明提供一种通过将特定的有机硅酸盐和/或其缩合物掺入指定的有机涂料组合物中制备的表面涂层组合物，由所述表面涂层组合物形成的膜使得已经进行了酸处理的膜的表面， 表示与水的接触角为70°以下; 以及成膜方法，其包括将所述表面涂层组合物涂覆在基材上以形成膜，然后用酸处理膜的表面。 本发明提供了这样的效果，即根据本发明获得的膜显示出良好的耐候性和良好的耐污染性。

公开(公告)号：US5609918A

公开(公告)日：1997-03-11

申请号：US477613

申请日：1995-06-07

申请人： Sachio Yamaguchi, deceased ,  Akimasa Nakahata ,  Satoshi Ikushima ,  Yasumasa Okumura ,  Haruhiko Aida ,  Shigeo Nishiguchi ,  Osamu Isozaki

发明人： Sachio Yamaguchi, deceased ,  Akimasa Nakahata ,  Satoshi Ikushima ,  Yasumasa Okumura ,  Haruhiko Aida ,  Shigeo Nishiguchi ,  Osamu Isozaki

IPC分类号： B05D7/00 ,  C09D133/06 ,  C09D163/00 ,  C09D201/02 ,  B05D1/36

CPC分类号： B05D7/53 ,  C09D133/066 ,  C09D133/068 ,  C09D163/00 ,  C09D201/02

摘要： The invention provides a method of forming a top coat by forming in sequence a colored base coat on a substrate and a clear coat, the method being characterized in that at least one of the colored base coat and the clear coat is formed by a curable coating composition consisting essentially of:(a) (a-1) a resin having a hydroxyl group, a carboxyl group and an epoxy group in the same molecule, or (a-2) a mixture of a hydroxyl- and carboxyl-containing resin with a polyepoxide;(b) a silicon compound having, per molecule, at least one silanol group and/or at least one hydrolyzable group directly bound to a silicon atom; and(c) an organic solvent.

摘要翻译： 本发明提供一种通过在基材上形成有色底涂层和透明涂层来形成顶涂层的方法，其特征在于，着色底涂层和透明涂层中的至少一个通过可固化涂层形成 组合物基本上由以下组成：（a）（a-1）在同一分子中具有羟基，羧基和环氧基的树脂，或（a-2）含羟基和羧基的树脂与 聚环氧化物 （b）每分子具有至少一个硅烷醇基和/或至少一个与硅原子直接结合的可水解基团的硅化合物; 和（c）有机溶剂。

公开(公告)号：US5583246A

公开(公告)日：1996-12-10

申请号：US573545

申请日：1995-12-15

申请人： Haruhiko Aida ,  Noboru Nakai ,  Osamu Isozaki

发明人： Haruhiko Aida ,  Noboru Nakai ,  Osamu Isozaki

IPC分类号： C08G77/445 ,  C07F7/04 ,  C08G77/02 ,  C08G77/42 ,  C09D183/04 ,  C09D183/06 ,  C07F7/18 ,  C07F7/08

CPC分类号： C08G77/02 ,  C07F7/04

摘要： The invention provides a lactone-modified organopolysiloxane compound represented by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represents a methyl group, an ethyl group, a n-propyl group, an isopropyl group or a group represented by the formula ##STR2## wherein R.sub.5 is a methyl group, an ethyl group, a n-propyl group or an isopropyl group, X is a saturated divalent hydrocarbon group having 2 to 14 carbon atoms, and m is an integer of 1 to 3, provided that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a group represented by the formula ##STR3## wherein R.sub.5, X and m are as defined above, and n is an integer of 1 to 100. The polysiloxane compound of the invention is excellent in compatibility with various organic resins.

摘要翻译： 本发明提供由式（I）表示的内酯改性的有机聚硅氧烷化合物，其中R 1，R 2，R 3和R 4相同或不同，并且各自表示甲基，乙基，正丙基， 异丙基或由下式表示的基团：其中R 5为甲基，乙基，正丙基或异丙​​基，X为碳原子数2〜14的饱和二价烃基，m为 其中R 1，R 2，R 3和R 4中的至少一个是由下式表示的基团：其中R 5，X和m定义同上，n为1至100的整数。 本发明的聚硅氧烷化合物与各种有机树脂的相容性优异。

公开(公告)号：US5408001A

公开(公告)日：1995-04-18

申请号：US107580

申请日：1993-08-18

申请人： Akimasa Nakahata ,  Nobushige Numa ,  Masahiro Yamane ,  Osamu Isozaki ,  Noboru Nakai

发明人： Akimasa Nakahata ,  Nobushige Numa ,  Masahiro Yamane ,  Osamu Isozaki ,  Noboru Nakai

IPC分类号： C08L63/00 ,  C09D201/04 ,  C08L27/12 ,  C08L27/14 ,  C08L33/14 ,  C08L63/02

CPC分类号： C08L63/00 ,  C09D201/04

摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.

摘要翻译： 公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

公开(公告)号：US5374665A

公开(公告)日：1994-12-20

申请号：US110676

申请日：1993-08-09

申请人： Hisashi Isaka ,  Osamu Isozaki

发明人： Hisashi Isaka ,  Osamu Isozaki

IPC分类号： C09D5/00 ,  C09D5/14 ,  C09D5/16 ,  C09D151/00 ,  C08L51/00 ,  B32B9/04

CPC分类号： C09D151/003 ,  Y10S525/902 ,  Y10T428/31504

摘要： An antifouling paint composition comprising a resin vehicle, an antifouling agent and a liquid medium, at least part of the resin vehicle being composed of a nonaqueous dispersion-type resin of a skin-core structure having in the core component an acid group or an acid precursor group convertible into the acid group by hydrolysis, and said antifouling composition being capable of maintaining an effect of preventing adhesion of microorganisms over along term.

摘要翻译： 一种防污涂料组合物，其包含树脂载体，防污剂和液体介质，所述树脂载体的至少一部分由在芯组分中具有酸基或酸的皮芯结构的非水分散型树脂 前体基团可通过水解转化成酸基，并且所述防污组合物能够保持防止微生物粘附的效果。

公开(公告)号：US5079312A

公开(公告)日：1992-01-07

申请号：US522401

申请日：1990-05-11

申请人： Osamu Isozaki ,  Noboru Nakai ,  Koichiro Murata

发明人： Osamu Isozaki ,  Noboru Nakai ,  Koichiro Murata

IPC分类号： C08F30/08 ,  C08F283/12 ,  C08F290/00 ,  C08F299/08 ,  C08G77/20 ,  C08G77/22 ,  C08G77/42

CPC分类号： C08F283/124 ,  C08G77/20

摘要： The invention provides a process for preparing a polysiloxane-containing resin which comprises copolymerizing a polysiloxane-type macromonomer with a vinyl monomer, characterized in that the polysiloxane-type macromonomer is one prepared by reacting about 70 to about 99.999 mole % of a compound (A) represented by the formula ##STR1## wherein R.sub.1 represents aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl group, and R.sub.2, R.sub.3 and R.sub.4 each represent alkoxyl group having 1 to 4 carbon atoms or hydroxyl group with about 30 to about 0.001 mole % of a compound (B) represented by the formula ##STR2## wherein R.sub.5 represents hydrogen atom or methyl group, R.sub.6, R.sub.7 and R.sub.8 each represent hydroxyl group, alkoxyl group having 1 to 4 carbon atoms or aliphatic hydrocarbon group having 1 to 8 carbon atoms with the proviso that R.sub.6, R.sub.7 and R.sub.8 can not be aliphatic hydrocarbon groups having 1 to 8 carbon atoms at the same time, and n is an integer of 1 to 6, the polysiloxane-type macromonomer having at least two free functional groups selected from hydroxyl groups and alkoxyl groups per molecule, and the macromonomer having a number-average molecular weight of about 400 to about 100,000.

摘要翻译： 本发明提供一种制备含聚硅氧烷的树脂的方法，其包括将聚硅氧烷型大分子单体与乙烯基单体共聚，其特征在于，所述聚硅氧烷型大分子单体是通过使约70-约99.999摩尔％的化合物（A ），其中R 1表示具有1至8个碳原子的脂族烃基或苯基，R 2，R 3和R 4各自表示具有1至4个碳原子的烷氧基或羟基，其中约30至 约0.001摩尔％的由式（II）表示的化合物（B），其中R5表示氢原子或甲基，R6，R7和R8各自表示羟基，具有1至4个碳原子的烷氧基或脂族烃 具有1至8个碳原子的基团，条件是R 6，R 7和R 8不能同时为具有1至8个碳原子的脂族烃基，n为1至6的整数，聚硅氧烷型大分子量 具有至少两个选自每个分子的羟基和烷氧基的游离官能团，并且大分子单体的数均分子量为约400至约100,000。

公开(公告)号：US4965312A

公开(公告)日：1990-10-23

申请号：US924477

申请日：1986-10-29

申请人： Noboru Nakai ,  Osamu Isozaki ,  Susumu Midogohchi

发明人： Noboru Nakai ,  Osamu Isozaki ,  Susumu Midogohchi

IPC分类号： C08F2/14 ,  C08F2/00 ,  C08F2/08 ,  C08F2/18 ,  C08F2/24 ,  C08F2/44 ,  C08L83/04 ,  C09D133/06 ,  C09D157/00 ,  C09D183/04 ,  C09D201/00

CPC分类号： C09D133/06 ,  C09D157/00 ,  C09D183/04 ,  C08L83/04

摘要： A vehicle composition for coating materials is disclosed. The vehicle composition includes an organic liquid, finely divided particles of a vinyl polymer dispersed in the organic liquid and a polymer of alkoxysiloxane having an alkoxy group of 3 to 5 carbon atoms dissolved in the organic liquid. The vehicle composition is prepared by polymerizing at least one vinyl monomer in the organic liquid which has the alkoxysiloxane polymer dissolved therein, the organic liquid being capable of dissolving the vinyl monomer but incapable of dissolving the vinyl polymer obtained therefrom.

摘要翻译： 公开了一种用于涂料的载体组合物。 车辆组合物包括有机液体，分散在有机液体中的细分散的乙烯基聚合物颗粒和溶解在有机液体中的具有3至5个碳原子的烷氧基的烷氧基硅氧烷的聚合物。 载体组合物通过使溶解有烷氧基硅氧烷聚合物的有机液体中的至少一种乙烯基单体聚合而制备，有机液体能够溶解乙烯基单体，但不能溶解由其获得的乙烯基聚合物。