公开(公告)号：US20150175436A1

公开(公告)日：2015-06-25

申请号：US14416674

申请日：2012-11-26

Applicant: SHENZHEN SUNXING LIGHT ALLOYS MATERIALS CO., LTD

Inventor： Xuemin Chen ,  Jun Yang ,  Zhihong Li ,  Weiping Wu ,  Shiming Wei

IPC: C01F7/54 ,  C25C3/06 ,  C22C21/00 ,  C22B21/06 ,  C22C1/02

CPC classification number: C01F7/54 ,  C22B21/062 ,  C22C1/026 ,  C22C21/00 ,  C25C3/06 ,  C25C3/18

Abstract: A method for preparing an aluminum-zirconium-boron alloy and synchronously preparing a cryolite is provided. The method includes the following steps: Step A: placing aluminum in a reactor, heating the reactor to 700-850 degrees centigrade, and adding a mixture consisting of fluorozirconate and fluoborate in a molar ratio of x: y into the reactor; Step B: stirring the reactants for 4-6 hours and extracting the upper molten liquid to obtain a cryolite, wherein the lower substance is an aluminum-zirconium-boron alloy, and aluminum is added in an excess amount. The method provided herein for preparing an aluminum-zirconium-boron alloy which is mild in reaction condition, easy to control and simple in technical flow can prepare a high-quality product through a complete reaction, besides, the use of the synchronously prepared low molecular ratio cryolites (KF.AlF3 and NaF.AlF3) in the aluminum electrolysis industry can achieve a proper electrical conductivity.

Abstract translation: 提供了制备铝 - 锆 - 硼合金并同时制备冰晶石的方法。 该方法包括以下步骤：步骤A：将铝置于反应器中，将反应器加热至700-850摄氏度，并将由氟锆酸盐和氟硼酸盐组成的混合物以x：y的摩尔比加入到反应器中; 步骤B：搅拌反应物4-6小时，提取上部熔融液体，得到冰晶石，其中低级物质为铝 - 锆 - 硼合金，并以过量的量加入铝。 本文提供的制备在反应条件温和，易于控制和工艺流程简单的铝 - 锆 - 硼合金的方法可以通过完全反应制备高品质的产品，此外，使用同步制备的低分子量 铝电解工业中的比例冰晶石（KF.AlF3和NaF.AlF3）可以实现适当的导电性。

公开(公告)号：US08709130B2

公开(公告)日：2014-04-29

申请号：US13709026

申请日：2012-12-09

Applicant: Shenzhen Sunxing Light Alloys Materials Co., Ltd

Inventor： Xuemin Chen ,  Jun Yang ,  Zhihong Li ,  Weiping Wu

IPC: C22B23/00 ,  C22B34/14

CPC classification number: C22B34/14 ,  C01F7/54 ,  Y02P10/234

Abstract: The invention provides a preparation method for producing metal zirconium industrially and producing low-temperature aluminum electrolyte as byproduct, which comprises the following steps: A) aluminum and fluorozirconate are put in a closed reactor, inert gas is fed into the reactor after evacuation, the reactor is heated up to 780° C. to 1000° C. and then the mixture in the reactor is stirred rapidly; and B) after reaction continues for 4 to 6 hours, the liquid molten at the upper layer is sucked out to obtain low-temperature aluminum electrolyte, and the product at the lower layer is subjected to acid dipping or distillation to remove surface residue to obtain metal zirconium.

Abstract translation: 本发明提供了一种在工业上生产金属锆并生产作为副产物的低温铝电解液的制备方法，其包括以下步骤：A）将铝和氟代锆酸盐放入封闭反应器中，撤离后将惰性气体送入反应器， 将反应器加热至780℃至1000℃，然后将反应器中的混合物快速搅拌; 和B）反应继续4〜6小时后，将上层熔融的液体吸出，得到低温铝电解质，将下层的产物进行酸浸或蒸馏除去表面残留物，得到 金属锆。

公开(公告)号：US10309021B2

公开(公告)日：2019-06-04

申请号：US14413473

申请日：2012-11-21

Applicant: SHENZHEN SUNXING LIGHT ALLOYS MATERIALS CO., LTD

Inventor： Xuemin Chen ,  Jun Yang ,  Zhihong Li ,  Weiping Wu ,  Shiming Wei

IPC: C25C3/18 ,  C01F7/54

Abstract: The disclosure provides a method for preparing an electrolyte and an electrolyte replenishment system during an electrolytic process. The method includes the following steps: Step A: placing aluminum in a reactor, vacuumizing the reactor and feeding an inert gas, heating the reactor to 700-850 degrees centigrade, and adding one or more of potassium fluozirconate, potassium fluoborate, sodium hexafluorozirconate and sodium fluoroborate; and Step B: stirring the reactants for 4-6 hours and extracting the upper molten liquid to obtain an electrolyte replenishment system during an aluminum electrolysis process. The disclosure has the following beneficial effects: when used in the aluminum electrolysis industry, the electrolyte system provided herein can be directly used as an aluminum electrolyte or a replenishment system in an electrolyte without changing existing electrolysis technology to significantly reduce an electrolysis temperature during an aluminum electrolysis process.

公开(公告)号：US09611151B2

公开(公告)日：2017-04-04

申请号：US14160660

申请日：2014-01-22

Applicant: SHENZHEN SUNXING LIGHT ALLOYS MATERIALS CO., LTD

Inventor： Xuemin Chen ,  Jun Yang ,  Zhihong Li ,  Weiping Wu

IPC: C25C3/18 ,  C01D3/02 ,  C01F7/54 ,  C01F1/00

CPC classification number: C01D3/02 ,  C01F1/00 ,  C01F7/54 ,  C25C3/18

Abstract: The disclosure provides an electrolyte supplement system in an aluminum electrolysis process, which includes low-molecular-ratio cryolite, wherein the low-molecular-ratio cryolite is selected from mKF.AlF3, nNaF.AlF3 or mixture thereof, where m=1˜1.5 and n=1˜1.5. When the electrolyte supplement system provided by the disclosure is applied to the aluminum electrolytic industry, electrolytic temperature can be reduced obviously in the aluminum electrolysis process without changing the existing electrolytic process; thus, power consumption is reduced, volatilization loss of fluoride is reduced and the comprehensive cost of production is reduced.

公开(公告)号：US20150211096A1

公开(公告)日：2015-07-30

申请号：US14420538

申请日：2012-11-21

Applicant: SHENZHEN SUNXING LIGHT ALLOYS MATERIALS CO., LTD

Inventor： Xuemin Chen ,  JUN Yang ,  Zhihong Li ,  Weiping Wu ,  Shiming Wei

IPC: C22C21/00 ,  B22D11/116 ,  C22C23/00 ,  C22C1/02 ,  C22B9/00

CPC classification number: C22C21/00 ,  B22D11/116 ,  C22B9/00 ,  C22C1/02 ,  C22C1/03 ,  C22C1/06 ,  C22C23/00

Abstract: The present invention provides an alloy for magnesium and magnesium alloy grain refinement, and a preparation method thereof, the alloy as a grain refiner being an aluminum-zirconium-boron intermediate alloy comprising the following chemical compositions by weight percent: 5-20% of Zr, 0.5-4% of B, and the balance being Al. The invention can achieve the following technical effect: an intermediate alloy with strong nucleation capability and excellent capability of magnesium and magnesium alloy grain refinement is invented and its preparation method is provided. This kind of grain refiner can be applied to casting deformation plastic processing of magnesium and magnesium alloy profiles, with high degree of refinement, to promote the extensive industrial applications of magnesium.

Abstract translation: 本发明提供一种用于镁和镁合金晶粒细化的合金及其制备方法，所述合金作为晶粒细化剂是铝 - 锆 - 硼中间合金，其包含以下化学组成按重量百分比计：ZrO 2的5-20％ ，B的0.5-4％，余量为Al。 本发明可以实现以下技术效果：发明了具有强的成核能力和优异的镁和镁合金晶粒细化能力的中间合金，并提供了其制备方法。 这种晶粒细化剂可以应用于镁和镁合金型材的铸造变形塑性加工，具有高度的精细化，促进镁的广泛工业应用。

公开(公告)号：US20150183645A1

公开(公告)日：2015-07-02

申请号：US14416677

申请日：2012-11-26

Applicant: SHENZHEN SUNXING LIGHT ALLOYS MATERIALS CO., LTD

Inventor： Xuemin Chen ,  Jun Yang ,  Zhihong Li ,  Weiping Wu ,  Shiming Wei

IPC: C01B35/04 ,  C01F7/54

CPC classification number: C01B35/04 ,  C01F7/54 ,  C25C3/18

Abstract: A method for preparing zirconium boride and synchronously preparing a cryolite is provided which includes the following steps: Step A: placing aluminum in a reactor, heating the reactor to 700-850 degrees centigrade, and adding the mixture of fluorozirconate and fluoborate; and Step B: stirring the reactants for 4-6 hours and extracting the upper molten liquid to obtain a cryolite, wherein the lower substance is zirconium boride. The disclosure has the following beneficial effects: the new zirconium boride preparation method provided herein is simple in preparation flow and the device used, short in preparation period and high in reaction efficiency, the prepared zirconium boride with many contact angles has a large specific surface area and contains a controllable amount of aluminum.

Abstract translation: 提供了制备硼化锆并同步制备冰晶石的方法，其包括以下步骤：步骤A：将铝置于反应器中，将反应器加热至700-850摄氏度，加入氟锆酸盐和氟硼酸盐的混合物; 和步骤B：将反应物搅拌4-6小时并萃取上部熔融液体，得到冰晶石，其中下部物质为硼化锆。 本发明具有以下有益效果：本文提供的新的硼化锆制备方法制备流程简单，使用的装置，制备周期短，反应效率高，制备的接触角很大的硼化锆具有较大的比表面积 并含有可控量的铝。