公开(公告)号：US12264123B2

公开(公告)日：2025-04-01

申请号：US17436753

申请日：2020-03-05

Applicant: SABIC Global Technologies B.V. ,  Saudi Arabian Oil Company

Inventor： Guillermo Leal ,  Naif Mohammed Al-Naddah Al-Otaibi ,  Kareemuddin Mahaboob Shaik ,  Mohammed Bismillah Ansari ,  Vijay Dinkar Bodas

IPC: C07C29/04 ,  B01D3/00 ,  C07C4/06 ,  C07C5/03 ,  C07C5/05 ,  C07C7/00 ,  C07C7/04 ,  C10L1/02 ,  C10L1/182

Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a first hydrogenation unit producing a first process stream; passing the first process stream through a distillation unit; withdrawing a 2-butene stream from the distillation unit: passing the 2-butene stream through a second hydrogenation unit producing a 1-butene stream; passing at least a portion of the 1-butene stream through a separation unit; and passing the 1-butene stream through a hydration unit producing the fuel additive.

公开(公告)号：US12017165B2

公开(公告)日：2024-06-25

申请号：US17608224

申请日：2020-05-05

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Vijay Dinkar Bodas ,  Mohammed Bismillah Ansari

IPC: B01D3/22

CPC classification number: B01D3/22

Abstract: This disclosure describes one or more trays for use in distillation columns. The trays include a plate having a plurality of through holes that extend between a first surface of the plate and a second surface of the plate. The plurality of through holes include a first set of through holes each having substantially a first diameter and a second set of through holes each having substantially a second diameter that is different from the first diameter. The trays also include a weir coupled to the plate and extending from the first surface. The weir is positioned between the first set of through holes and the second set of through holes.

公开(公告)号：US11865533B2

公开(公告)日：2024-01-09

申请号：US17435451

申请日：2020-03-10

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Vijay Dinkar Bodas ,  Guillermo Leal Canelon ,  Mohammed Bismillah Ansari

IPC: B01J8/02 ,  B01J8/00 ,  B01J19/00 ,  B01J19/24 ,  C07C5/327 ,  G05B19/05

CPC classification number: B01J8/0278 ,  B01J8/001 ,  B01J19/002 ,  B01J19/2445 ,  C07C5/327 ,  G05B19/05 ,  G05B2219/15052

Abstract: Houdry lumps can be reduced by controlling the reactors in a fixed bed dehydrogenation process for producing olefins according to defined rules. A programmable logic controller can apply the rules to the operation of the dehydrogenation unit and control the operation of individual reactors according to the rules. By doing so, the performance of dehydrogenation units can be improved without adding any heat generating inerts, such as CuO-α alumina For example, the dehydrogenation units can be operated according to combinatorics in the programmable logic controller such that the farthest two reactors in the dehydrogenation unit never operate in parallel in the dehydrogenation or air regeneration steps.

公开(公告)号：US11613717B2

公开(公告)日：2023-03-28

申请号：US16633311

申请日：2018-07-27

Applicant: SABIC GLOBAL TECHNOLOGIES B.V. ,  SAUDI ARABIAN OIL COMPANY

Inventor： Guillermo Leal ,  Kareemuddin Mahaboob Shaik ,  Mohammed Bismillah Ansari ,  Hiren Shethna ,  Zhonglin Zhang

IPC: C07C6/04 ,  C07C29/04 ,  C07C41/06 ,  C10L10/10 ,  C10L1/182 ,  C07C5/25

Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a methyl tertiary butyl ether unit producing a first process stream; passing the first process stream through a selective hydrogenation unit producing a second process stream; passing the second process stream through an isomerization unit producing a third process stream; and passing the third process stream through a hydration unit producing the fuel additive and a recycle stream.

公开(公告)号：US11505516B2

公开(公告)日：2022-11-22

申请号：US16631633

申请日：2018-07-17

Applicant: SABIC Global Technologies B.V.

Inventor： Guillermo Leal ,  Mohammed Bismillah Ansari

IPC: C07C6/04 ,  C07C5/25 ,  C07C7/04 ,  C07C7/13 ,  C07C41/06 ,  C07C9/12 ,  C07C11/06

Abstract: Systems and methods for producing propylene using an MTBE synthesis raffinate are disclosed. An MTBE synthesis raffinate stream first passes through a molecular sieve to separate n-butane and isobutane from the rest of C4 hydrocarbons of the MTBE synthesis raffinate. The 1-butene in the rest of C4 hydrocarbons of the MTBE synthesis raffinate is then isomerized to form 2-butene. Therefore, the concentration of 2-butene in the subsequent propylene production process increases due to the separation of n-butane and isobutane and the isomerization of 1-butene, resulting in an improved reaction rate and reaction efficiency for propylene production.

公开(公告)号：US20220185750A1

公开(公告)日：2022-06-16

申请号：US17436753

申请日：2020-03-05

Applicant: SABIC Global Technologies B.V. ,  Saudi Arabian Oil Company

Inventor： Guillermo Leal ,  Naif Mohammed Al-Naddah Al-Otaibi ,  Kareemuddin Mahaboob Shaik ,  Mohammed Bismillah Ansari ,  Vijay Dinkar Bodas

IPC: C07C29/04 ,  C07C5/03 ,  C07C7/04 ,  C07C7/00 ,  C07C4/06 ,  C10L1/02 ,  C10L1/182 ,  B01D3/00

Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a first hydrogenation unit producing a first process stream; passing the first process stream through a distillation unit; withdrawing a 2-butene stream from the distillation unit: passing the 2-butene stream through a second hydrogenation unit producing a 1-butene stream; passing at least a portion of the 1-butene stream through a separation unit; and passing the 1-butene stream through a hydration unit producing the fuel additive.

公开(公告)号：US20210024843A1

公开(公告)日：2021-01-28

申请号：US16981189

申请日：2019-03-18

Applicant: SABIC Global Technologies B.V. ,  Saudi Arabian Oil Company

Inventor： Guillermo Leal ,  Naif Mohammed Al-Naddah Al-Otaibi ,  Kareemuddin Mahaboob Shaik ,  Mohammed Bismillah Ansari ,  Vijay Dinkar Bodas

IPC: C10L1/16 ,  C07C5/05 ,  C07C7/00 ,  C07C7/04 ,  C07C7/13 ,  C07C29/04 ,  C10L1/182 ,  C10L10/10

Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a hydrogenation unit producing a hydrogenated stream; passing the hydrogenated stream through a distillation unit producing a first stream and a second stream; producing an isobutylene stream by passing the first stream through a molecular sieve unit; passing the isobutylene stream to a hydration unit as a feedstock for the fuel additive; and forming the fuel additive in the hydration unit.

公开(公告)号：US20210024837A1

公开(公告)日：2021-01-28

申请号：US17042614

申请日：2019-04-11

Applicant: SABIC Global Technologies B.V. ,  Saudi Arabian Oil Company

Inventor： Guillermo Leal ,  Kareemuddin Mahaboob Shaik ,  Hiren Shethna ,  Naif Mohammed Al-Naddah Al-Otaibi ,  Mohammed Bismillah Ansari ,  Zhonglin Zhang

IPC: C10G67/04 ,  C07C7/08 ,  C10G69/06 ,  C10G69/04 ,  C07C5/22 ,  C10L1/182 ,  C10L1/185

Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a butadiene extraction unit producing a first process stream; passing the first process stream through a methyl tertiary butyl ether unit producing a second process stream and a methyl tertiary butyl ether product; passing the second process stream through a hydration unit producing the fuel additive and a recycle stream; passing the recycle stream through a hydrogenation unit; and recycling the recycle stream to a steam cracker unit and/or to the feed stream

公开(公告)号：US12240793B2

公开(公告)日：2025-03-04

申请号：US18005589

申请日：2021-07-16

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Vijay Dinkar Bodas ,  Mohammed Bismillah Ansari

IPC: C07C2/76 ,  C07C4/04 ,  C07C5/27 ,  C07C5/333 ,  C07C5/42 ,  C07C41/06

Abstract: Systems and methods for processing a C3 and C4 hydrocarbon mixture have been disclosed. The C3 and C4 hydrocarbon mixture is separated to remove propane from C4 hydrocarbons. The resulting C4 hydrocarbons are then processed in an isomerization unit to produce additional isobutane. The isobutane of the isomerization unit effluent is dehydrogenated in a dehydrogenation unit to produce isobutene. The resulting isobutene is reacted with an alkanol to produce an alkyl tert-butyl ether.

公开(公告)号：US11697626B2

公开(公告)日：2023-07-11

申请号：US17054906

申请日：2019-05-06

Applicant: SABIC Global Technologies B.V.

Inventor： Mohammed Bismillah Ansari ,  Guillermo Leal ,  Vijay Dinkar Bodas ,  Naif Mohammed Al-Naddah Al-Otaibi

IPC: C07C5/05 ,  C07C7/08 ,  C07C29/08 ,  C10G11/00 ,  C10L1/16

CPC classification number: C07C5/05 ,  C07C7/08 ,  C07C29/08 ,  C10G11/00 ,  C10L1/1608 ,  C10L2200/0423 ,  C10L2230/22

Abstract: A method of producing a fuel additive includes: passing a raffinate stream comprising C4 hydrocarbons through a hydrogenation unit, forming a first process stream; passing the first process stream through an extractive distillation unit, forming a C4 olefin stream; passing the C4 olefin stream through a stripper column, forming a purified C4 olefin stream; and forming the fuel additive by passing the purified C4 olefin stream through a hydration unit.