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    Copolymer of ethylene and ion pair compound
    11.
    发明授权
    Copolymer of ethylene and ion pair compound 有权

    公开(公告)号：US12269905B2

    公开(公告)日：2025-04-08

    申请号：US17627433

    申请日：2020-07-16

    Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

    Inventor： Jerome Vachon ,  Peter Neuteboom ,  Jonathan Tellers

    IPC: C08F210/02 ,  C07C57/04

    Abstract: The invention relates to an ethylene copolymer obtained by copolymerizing ethylene and an ion pair compound consisting of a cation of formula (I) and an anion selected from formulas (II), (III), (IV) and (V), wherein (I) where R1=H or C1-C10 alkyl; X═O or NH; R2=C1-C40 alkyl; R3, R4=H or C1-C10 alkyl which can be connected through a cyclic structure, R5=H or C1-C20, (II) (III) (IV) (V) where R6, R7, R9=H or C1-C10 alkyl; R8, R10=C1-C40 alkyl; Y, V, W═O or NH; n=1 to 20; Z═—SO3 or —C(O)O.

    Process for the production of ethylene polymers
    12.
    发明授权
    Process for the production of ethylene polymers 有权

    公开(公告)号：US10696763B2

    公开(公告)日：2020-06-30

    申请号：US15755123

    申请日：2016-07-14

    Applicant: SABIC Global Technologies B.V.

    Inventor： Diego Mauricio Castaneda Zuniga ,  Peter Neuteboom ,  Jan Nicolaas Eddy Duchateau ,  Carolina de los Angeles Toloza Porras ,  Franciscus Petrus Hermanus Schreurs ,  Jerome Vachon

    IPC: C08F210/02 ,  C08F2/02

    Abstract: The present invention relates to a process for the production of ethylene polymers in a tubular reactor comprising reacting in said tubular reactor a feed composition comprising ethylene and one or more composition comprising one or more cyclic olefin wherein the cyclic olefin is a compound having the structure of Formula (I): wherein R may be a moiety comprising ≥1 and ≤10 carbon atoms; wherein R1 and R2 may each individually be hydrogen or a moiety comprising ≥1 and ≤5 carbon atoms, R1 and R2 may be the same or different; wherein ⋅ the tubular reactor may be operated at a pressure of ≥200 and ≤280 MPa; ⋅ the average reaction peak temperature may be ≥220° C. and ≤300° C.; ⋅ the composition comprising one or more cyclic olefin may be fed to the reactor in one or more feed inlet of said tubular reactor; and ⋅ said cyclic olefin may be fed to the tubular reactor in quantities of ≤1.0 mol %, with regards to the total feed composition. Such process allows for the production of ethylene polymers having a high density and a high purity.

    Method for preparing ethylene copolymer
    13.
    发明授权
    Method for preparing ethylene copolymer 有权

    公开(公告)号：US10150826B2

    公开(公告)日：2018-12-11

    申请号：US15327526

    申请日：2015-07-23

    Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

    Inventor： Jan Nicolaas Eddy Duchateau ,  Peter Neuteboom ,  Diego Mauricio Castaneda Zuniga ,  Markus Busch ,  Sebastian Bruno Fries

    IPC: C08F210/02 ,  C08J5/18 ,  C08F2/38 ,  C08F238/00 ,  C08F4/34

    Abstract: A process for preparing an ethylene copolymer in the presence of free-radical polymerization initiator at pressures from 150 MPa to 350 MPa and temperatures from 100° C. to 350° C., by copolymerizing ethylene and a comonomer having a C≡C bond and optionally further comonomers, wherein the comonomer having the C≡C bond is represented by formula wherein R1 is hydrogen or methyl; X1 is —CO—O— or —CO—NH—; R2 is —CH2—O—, —O—CO—, —Si(CH3)2—, —Si(CH3)2—O— or —CR5R6— wherein R5 and R6 are independently selected from hydrogen, methyl, ethyl and hydroxyl; n is an integer from 1 to 32 and R2 is same or different from each other when n is 2 to 32; and R3 is —C≡C— and R4 is hydrogen, C1-C10 linear or branched alkyl, C1-C10 linear or branched hydroxyalkyl or phenyl, or the unit R3-R4 stands for wherein X2 is F, Cl, Br or I.

    Polyolefin composition
    14.
    发明授权
    Polyolefin composition 有权

    公开(公告)号：US10047218B2

    公开(公告)日：2018-08-14

    申请号：US15106432

    申请日：2014-12-10

    Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

    Inventor： Peter Neuteboom ,  Pieter Valkier

    IPC: C08L23/14 ,  C08L23/12 ,  B29C45/00 ,  B29K23/00 ,  B29L31/30

    CPC classification number: C08L23/14 ,  B29C45/0001 ,  B29K2023/10 ,  B29L2031/3055 ,  C08K3/34 ,  C08L23/0815 ,  C08L23/12 ,  C08L23/16 ,  C08L2205/025 ,  C08L2207/02 ,  C08L2308/00 ,  C08L2314/02

    Abstract: The present invention relates to a polyolefin composition comprising a first heterophasic propylene copolymer and a second heterophasic propylene copolymer, wherein the first heterophasic propylene copolymer comprises: from 70-90 wt % of a first polypropylene having a melt flow index of from 55-85 g/10 min as measured according to ISO 1133 (2.16 kg and 230° C.), from 10-30 wt % of a first ethylene α-olefin copolymer having a melt flow index of from 2.5-5.0 g/10 min in accordance with ISO 1133 (2.16 kg and 230° C.), the respective amounts of first polypropylene and first ethylene α-olefin copolymer being based on the weight of the first heterophasic propylene copolymer and wherein the second heterophasic propylene copolymer comprises: from 60-85 wt % of a second polypropylene having a melt flow index of from 50-100 g/10 min as measured according to ISO 1133 (2.16 kg, 230° C.), from 15-40 wt % of a second ethylene α-olefin copolymer having a melt flow index of from 0.050-0.30 g/10 min in accordance with ISO 1133 (2.16 kg and 230° C.), the respective amounts of second polypropylene and second ethylene α-olefin copolymer being based on the weight of the second heterophasic propylene copolymer, and wherein a weight ratio of said first and second heterophasic propylene copolymer is from 1 to 10. The invention further relates to automotive parts comprising said composition and having good tiger stripe performance.

    Process for the preparation of polyolefin particles
    18.
    发明授权
    Process for the preparation of polyolefin particles 有权

    公开(公告)号：US11136438B2

    公开(公告)日：2021-10-05

    申请号：US15743865

    申请日：2016-06-30

    Applicant: SABIC Global Technologies B.V.

    Inventor： Diego Mauricio Castaneda Zuniga ,  Jan Nicolaas Eddy Duchateau ,  Peter Neuteboom ,  Zeljko Knez

    IPC: C08J3/00 ,  B01J2/00 ,  D06N7/00 ,  C08J3/12 ,  B01J2/04 ,  C08J3/22

    Abstract: A process for producing polyolefin particles from a polyolefin composition, comprising the steps of:
    a) providing a melted composition of a polyolefin and
    b) providing particles from the melted composition by:
    b1) mixing a first flow of a supercritical fluid in the melted composition in a pressure vessel to obtain a solution saturated with the supercritical fluid and
    b2) passing the solution from the pressure vessel through a throttling device to a spraying tower to expand the solution to obtain the polyolefin particles in the spraying tower, wherein a second flow of a supercritical fluid is injected in the throttling device, wherein the supercritical fluid is a supercritical fluid of a substance selected from the group consisting of CO2, NH3, H2O, N2O, CH4, ethane, propane, propylene, n-butane, i-butane, n-pentane, benzene, methanol, ethanol, isopropanol, isobutanol, chlorotrifluoromethane, monofluoromethane, 1,1,1,2-Tetrafluoroethane, toluene, pyridine, cyclohexane, cyclohexanol, o-xylene, dimethyl ether and SF6 and combinations thereof.

    Process for recycling polyolefin
    19.
    发明授权
    Process for recycling polyolefin 有权

    公开(公告)号：US11130850B2

    公开(公告)日：2021-09-28

    申请号：US16474849

    申请日：2017-12-12

    Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

    Inventor： Diego Mauricio Castaneda Zuniga ,  Jerome Vachon ,  Jan Nicolaas Eddy Duchateau ,  Peter Neuteboom ,  Zeljko Knez

    IPC: B29B17/02 ,  C08J11/08 ,  B29B17/00

    Abstract: The present invention relates to a process for recycling polyolefin, comprising the steps of: 1) feeding a solid post-consumer polyolefin composition comprising polyolefin and contaminants and a flow of an extraction fluid to an extractor having a pressure of 100-1000 bar and a temperature of 20-80° C. to obtain a solid extracted composition, 2) melting the solid extracted composition to obtain a melted composition, 3) providing particles from the melted composition by: 3a) mixing a flow of a supercritical fluid in the melted composition in a pressure vessel to obtain a solution saturated with the supercritical fluid and 3b) passing the solution from the pressure vessel through a throttling device to a spraying tower to expand the solution to obtain polyolefin particles in the spraying tower.

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