Abstract:
A purified 2-hydrocarbyl-3-(dihydroxyfluoresceinyl)phthalimidine compound of formula (I): wherein R is a C1-25 hydrocarbyl; each occurrence of R2 and R3 is independently a halogen or a C1-25 hydrocarbyl; p is 0 to 4; and each q is independently 0 to 3; and wherein the purified 2-hydrocarbyl-3-(dihydroxyfluoresceinyl)phthalimidine compound of formula (I) has a purity of greater than 99.4%, as determined by high performance liquid chromatography.
Abstract:
An endcapped polycarbonate, comprising thioether carbonyl endcaps of the formula wherein L is a C1-12 aliphatic or aromatic linking group, and R is a C1-20 alkyl, C6-18 aryl, or C7-24 arylalkylene.
Abstract:
A method of preparing a poly(ester-carbonate) includes contacting an aqueous solution including a dicarboxylic acid with a first solution including phosgene and a first organic solvent in a tubular reactor to provide a first reaction mixture. A dihydroxy aromatic compound, the corresponding dialkali metal salt of the dihydroxy aromatic compound, or a combination comprising at least one of the foregoing, water, and a second organic solvent are combined to provide a second reaction mixture. The method further includes introducing the first reaction mixture, the second reaction mixture, and a second solution comprising phosgene to a tank reactor, wherein the tank reactor has a first pH of 7 to 10. The pH is optionally raised to 9 to 11 to provide a third reaction mixture including the poly(ester-carbonate). Poly(ester-carbonate)s prepared according to the method described herein are also disclosed.
Abstract:
A film comprising a copolycarbonate, wherein the film is a uniaxially-stretched, extruded film comprising at least one film region having: an average thickness of more than 0 and less than 14 micrometers with a standard deviation of 0.8 micrometer to 1.6 micrometers, a surface having a surface roughness average of less than 0.04 micrometer as measured by optical profilometry, a dielectric constant at 1 kHz and room temperature of at least 2.7, a dissipation factor at 1 kHz and room temperature of 1% or less, and a breakdown strength of at least 620 Volt/micrometer; and the copolycarbonate has a Tg of greater than 180° C. and comprises carbonate units derived from a bisphenol compound of the formula (3).
Abstract:
A bisphenol polyether oligomer composition comprising greater than 90 wt. % of an oligomer of the formula wherein Ra, Rb, and Rc are each independently a C1-12 alkyl, C1-12 alkoxy, or C1-12 alkylarylene, each Xa is independently a single bond, —O—, —S—, —S(O)—, —S(O)2—, —C(O)—, or a C1-18 organic group, G is H or p, q, and t are each independently integers of 0 to 4, n is 1 to 10; and wherein the bisphenol polyether oligomer composition comprises: a total halide content of less than 1000 ppm, less than 1000 ppm of —CH2OH groups, less than 5 wt. % cyclic oligomers, and less than 100 ppm of a bisphenol of the formula wherein Ra, Rb, Xa, p and q are the same as in the oligomer.
Abstract:
A film comprises a phthalimidine copolycarbonate comprising first repeating units and second repeating units different from the first repeating units, wherein the first repeating units are phthalimidine carbonate units and the second repeating units comprise bisphenol carbonate units that are not the same as the first repeating phthalimidine carbonate units; and a second polycarbonate that is not a phthalimidine copolycarbonate; wherein the film has: a glass transmission temperature of greater than 170° C.; a dielectric constant at 1 kHz, 23° C. and 50% relative humidity of at least 3.0; a dissipation factor at 1 kHz, 23° C. and 50% relative humidity of 1% or less; and a breakdown strength of at least 800 Volt/micrometer.
Abstract:
A polymer blend including 5 to 95 weight percent of a poly(ester-carbonate-carbonate) comprising 40 to 95 mole percent of ester units comprising low heat bisphenol groups and high heat bisphenol groups, wherein the ester units comprise 20 to 80 mole percent of the low heat bisphenol groups and 20 to 80 mole percent of the high heat bisphenol groups, based on the total moles of ester units in the poly(ester-carbonate-carbonate), and 5 to 60 mole percent of carbonate units comprising the low heat bisphenol groups and the high heat bisphenol groups, wherein the carbonate units comprise 20 to 80 mole percent of the low heat bisphenol groups and 20 to 80 mole percent of the high heat bisphenol groups, based on the total moles of carbonate units in the poly(ester-carbonate-carbonate); and 5 to 95 weight percent of a poly(etherimide), wherein the weight percent of each polymer is based on the total weight of the polymers in the blend, and a molded 0.125-inch thick ASTM tensile bar comprising the polymer blend has a haze value of less than 25% as determined according to ASTM D1003 using the color space CIE1931 with Illuminant C and a 2° observer.
Abstract:
A thermoplastic composition comprising a copolycarbonate comprising bisphenol A carbonate units and second carbonate units of formula (1a) wherein R is a C1-25 hydrocarbyl; each occurrence of R2 and R3 is independently a halogen or a C1-25 hydrocarbyl; p is 0 to 4; and each q is independently 0 to 3; and optionally a bisphenol A homopolycarbonate.