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    Method for the preparation of an alcohol from hydrocarbon
    11.
    发明授权
    Method for the preparation of an alcohol from hydrocarbon 失效
    从烃制备醇的方法

    公开(公告)号：US5104504A

    公开(公告)日：1992-04-14

    申请号：US588095

    申请日：1990-09-21

    申请人： Masato Tanaka ,  Toshiyasu Sakakura ,  Fujio Abe

    发明人： Masato Tanaka ,  Toshiyasu Sakakura ,  Fujio Abe

    IPC分类号： B01J31/24 ,  C07B61/00 ,  C07C27/00 ,  C07C29/36 ,  C07C33/22 ,  C07C45/49 ,  C07C47/54

    CPC分类号： C07C29/36 ,  Y02P20/52

    摘要： A efficient photochemical method for the preparation of an alcohol compound, e.g., benzyl alcohol, from a non-olefin hydrocarbon compound, e.g., benzene, was proposed in which a mixture of the non-olefin hydrocarbon compound as the starting material and a hydrogen donor compound, which is a cycloalkane of 5 to 16 carbon atoms in a molecule, e.g., cyclooctane, or an aliphatic alcohol of up to 10 carbon atoms in a molecule, e.g., isopropyl alcohol, is irradiated with light under an atmosphere of carbon monoxide in the presence of a complex compound of rhodium or iridium, of which at least one of the ligands is preferably a monophosphine or bisphosphine compound. The method is advantageous in that the reaction can proceed under mild reaction conditions and that the amount of the aldehyde compound formed in the reaction mixture as a by-product is very small as compared with conventional methods so as to greatly facilitate isolation of the desired alcohol product from the reaction mixture.

    摘要翻译： 提出了一种用于制备来自非烯烃烃化合物例如苯的醇化合物（例如苄醇）的有效光化学方法，其中以非烯烃烃化合物作为原料的混合物和氢供体 化合物，其是分子中具有5至16个碳原子的环烷烃，例如环辛烷或分子中具有至多10个碳原子的脂族醇，例如异丙醇，在一氧化碳气氛下用光照射 存在铑或铱的复合化合物，其中至少一种配体优选为单膦或双膦化合物。 该方法的优点在于反应可以在温和的反应条件下进行，并且与常规方法相比，作为副产物的反应混合物中形成的醛化合物的量非常小，以便极大地促进所需醇的分离 反应混合物中的产物。

    Catalyst for Cyclic Carbonate Synthesis
    14.
    发明申请
    Catalyst for Cyclic Carbonate Synthesis 审中-公开
    环状碳酸酯合成催化剂

    公开(公告)号：US20080214386A1

    公开(公告)日：2008-09-04

    申请号：US11597932

    申请日：2005-03-01

    申请人： Toshikazu Takahashi ,  Tsutomu Watahiki ,  Hiroyuki Yasuda ,  Toshiyasu Sakakura

    发明人： Toshikazu Takahashi ,  Tsutomu Watahiki ,  Hiroyuki Yasuda ,  Toshiyasu Sakakura

    IPC分类号： B01J31/00

    CPC分类号： B01J31/0269 ,  B01J31/0234 ,  B01J31/0239 ,  B01J31/0268 ,  B01J31/069 ,  C07D317/38

    摘要： Provided are a solid catalyst which gives a cyclic carbonate at a high yield and a high selectivity, which is stable and which may be readily separated after reaction; and a method of industrially advantageous, inexpensive and safe production of a cyclic carbonate by the use of the catalyst. The catalyst contains an inorganic solid substance having a surface modified with an ionic substance containing a Group 15 element; or contains an ionic substance containing a Group 15 element, and an inorganic solid substance. The modifying group for surface modification of an inorganic solid substance is an ionic substance containing a Group 15 element. The ionic substance containing a Group 15 element is at least one substance selected from organic phosphonium salts, organic ammonium salts, organic arsonium salts and organic antimonium salts.

    摘要翻译： 提供一种固体催化剂，其以高产率和高选择性得到环状碳酸酯，其是稳定的并且可以在反应后容易地分离; 以及通过使用催化剂工业上有利，廉价且安全地生产环状碳酸酯的方法。 该催化剂含有具有由含有第15族元素的离子性物质改性的表面的无机固体物质; 或含有含有第15族元素的离子物质和无机固体物质。 无机固体物质的表面改性改性基团是含有第15族元素的离子性物质。 含有第15族元素的离子物质是选自有机鏻盐，有机铵盐，有机ium盐和有机锑盐中的至少一种物质。

    Process for preparing polysilane by catalytic dehydrogenative condensation of organosilane and metal complex catalyst therefor
    15.
    发明授权
    Process for preparing polysilane by catalytic dehydrogenative condensation of organosilane and metal complex catalyst therefor 失效
    通过有机硅烷和金属络合物催化剂的催化脱氢缩合制备聚硅烷的方法

    公开(公告)号：US06610872B1

    公开(公告)日：2003-08-26

    申请号：US09633871

    申请日：2000-08-07

    申请人： Nami Choi ,  Shun-ya Onozawa ,  Toshiyasu Sakakura ,  Masato Tanaka

    发明人： Nami Choi ,  Shun-ya Onozawa ,  Toshiyasu Sakakura ,  Masato Tanaka

    IPC分类号： C08F464

    CPC分类号： C08G77/60

    摘要： A polysilane is produced by subjecting a trihydrosilane to hydrogenative condensation in the presence of a titanium or zirconim complex catalyst having a first group selected from a dialkylaminoalkylcyclopentadienyl group, an &agr;-[(dialkylamino)alkyl]indenyl group and a &bgr;-[(dialkylamino)alkyl]indenyl group and a second group selected from a cyclopentadienyl group and a pentamethylcyclopentadienyl group. The above dialkylaminoalkyl group may be replaced by a branched alkyl group. The zirconium complexes are novel compounds.

    摘要翻译： 在具有选自二烷基氨基烷基环戊二烯基，α - [（二烷基氨基）烷基]茚基和β - [（二烷基氨基）茚基的第一组的钛或锆石复合催化剂存在下，使三氢硅烷进行氢化缩合， 烷基]茚基和选自环戊二烯基和五甲基环戊二烯基的第二基团。 上述二烷基氨基烷基可以被支链烷基取代。 锆络合物是新化合物。