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公开(公告)号：US07082787B2
公开(公告)日：2006-08-01
申请号：US10796608
申请日：2004-03-09
申请人： Guang-Chung Lee , Rian Reyneke , Michael J. Foral , Christos Papadopoulos , Wayne W. Y. Eng , Jeff Logsdon
发明人： Guang-Chung Lee , Rian Reyneke , Michael J. Foral , Christos Papadopoulos , Wayne W. Y. Eng , Jeff Logsdon
CPC分类号： F25J3/0219 , F25J3/0233 , F25J3/0238 , F25J3/0252 , F25J3/0655 , F25J2200/74 , F25J2205/04 , F25J2210/12 , F25J2215/60 , F25J2215/62 , F25J2270/04 , F25J2270/12 , F25J2270/18 , F25J2270/66 , F25J2270/902
摘要： The recovery of ethylene from light gases at low temperature by the use of a mixed refrigeration system comprising methane, ehtylene and/or ethane, and propylene and/or propane.
摘要翻译： 通过使用包含甲烷，乙炔和/或乙烷以及丙烯和/或丙烷的混合制冷系统在低温下从轻质气体中回收乙烯。
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公开(公告)号：US20230390722A1
公开(公告)日：2023-12-07
申请号：US17829818
申请日：2022-06-01
申请人： Rian Reyneke , Gautham Krishnaiah , Manoj Nagvekar , Mitchell Biondi , Steven Arthur Tragesser , Akhilesh Pratap , Froylan Guzman , Matthew James Griffiths , Christopher Brian Scharf
发明人： Rian Reyneke , Gautham Krishnaiah , Manoj Nagvekar , Mitchell Biondi , Steven Arthur Tragesser , Akhilesh Pratap , Froylan Guzman , Matthew James Griffiths , Christopher Brian Scharf
CPC分类号： B01J8/008 , B01J8/0055 , C10G11/18 , B01J8/1863 , C10G2300/4018 , C10G2300/70 , B01J2208/00557 , B01J2208/06 , C10G2400/20
摘要： A reactor system and method for catalytic dehydrogenation of saturated C3-C6 hydrocarbons within a reactor placed within a reactor disengager, where the reactor is open at the bottom thereof and open to the disengager, and the exit riser from the reactor is not hard coupled to at least one downstream cyclone. This configuration permits controlling the amount of catalyst within the reactor by varying the level of catalyst in the reactor disengager outside the reactor and permits controlling total catalyst hold-up and/or weight hourly space velocity (WHSV) independently from catalyst flow from the catalyst regenerator.
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13.发明申请公开(公告)号：US20210077967A1
公开(公告)日：2021-03-18
申请号：US16570029
申请日：2019-09-13
摘要： A process where external fuel oil is used to wash entrained catalyst from a fluidized-bed propane dehydrogenation reactor effluent, where the fuel oil and catalyst mixture is returned to the reactor to provide the net fuel required for catalyst regeneration. Optionally the fluidized-bed propane dehydrogenation reactor effluent and the fuel oil are contacted in a direct contact inline device before entering a flash zone in the reactor vessel.
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公开(公告)号：US20210070676A1
公开(公告)日：2021-03-11
申请号：US17016530
申请日：2020-09-10
申请人： Rian Reyneke
发明人： Rian Reyneke
摘要： A method to recover refrigeration credit from propane feed to a propane dehydrogenation reactor by fully condensing a Depropanizer overhead stream, letting the condensed stream down in pressure, and vaporizing the stream at lower pressure against process streams to recover refrigeration credit.
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公开(公告)号：US20090193846A1
公开(公告)日：2009-08-06
申请号：US11922951
申请日：2005-07-28
申请人： Michael J. Foral , Rian Reyneke , Wayne W.Y. Eng , Graeme Parker
发明人： Michael J. Foral , Rian Reyneke , Wayne W.Y. Eng , Graeme Parker
CPC分类号： C01B3/506 , C01B32/40 , C01B2203/044 , C01B2203/046 , C01B2203/048 , C07C7/04 , C07C7/09 , F25J3/0219 , F25J3/0223 , F25J3/0233 , F25J3/0238 , F25J3/0252 , F25J3/0261 , F25J2200/70 , F25J2200/74 , F25J2200/76 , F25J2200/78 , F25J2200/80 , F25J2205/02 , F25J2205/04 , F25J2205/30 , F25J2210/12 , F25J2245/02 , F25J2270/04 , F25J2270/08 , F25J2270/24 , F25J2270/90 , Y02C10/12 , C07C11/02
摘要： A process is described for the recovery of CO and optionally hydrogen from a stream containing CO, H2, methane, and hydrocarbons heavier than methane. The process is characterized by a two-stage removal (3, 6) of C2+ hydrocarbons from the feed. In a first step the feed gas (1) is separated (3) into a first C2+ depleted stream (5) and a first C2+ enriched stream (4). The first C2-enriched stream (4) is rectified (6) to produce a second C2+ depleted stream. The first and second C2+ depleted streams (5, 9) are fed to a cryogenic system (10) fro recovery of CO (12) and optionally hydrogen (11).
摘要翻译： 描述了从含有CO，H2，甲烷和比甲烷重的烃的流中回收CO和任选的氢的方法。 该方法的特征在于从进料中两步除去（3,6）的C2 +烃。 在第一步骤中，将进料气体（1）分离（3）到第一C2 +贫化流（5）和第一C2 +富集流（4）中。 第一个C2富集流（4）被整流（6）以产生第二个C2 +耗尽的流。 通过CO（12）和任选的氢（11）的回收，将第一和第二C2 +贫化物流（5,9）进料到低温系统（10）。
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16.发明申请公开(公告)号：US20090133437A1
公开(公告)日：2009-05-28
申请号：US11922760
申请日：2005-07-28
申请人： Rian Reyneke , Michael J. Foral
发明人： Rian Reyneke , Michael J. Foral
CPC分类号： C01B3/506 , C01B2203/046 , C01B2203/047 , C01B2203/048 , F25J3/0219 , F25J3/0233 , F25J3/0238 , F25J3/0252 , F25J3/0261 , F25J3/0271 , F25J2200/70 , F25J2200/74 , F25J2200/78 , F25J2200/90 , F25J2205/02 , F25J2205/04 , F25J2205/30 , F25J2205/40 , F25J2205/60 , F25J2210/12 , F25J2245/02 , F25J2270/02 , F25J2270/24 , F25J2290/40 , Y02P20/124
摘要： A novel process is disclosed which produces a CO-rich stream from a stream containing hydrogen, carbon monoxide, methane, and components heavier than methane. The process utilizes a combined CO purification and demethanizer column (5) which reduces the overall capital cost of the process, and efficient heat integration which reduces the energy required by the process. This process is useful in recovering a CO-rich stream (10) from the effluent (1) of an autothermal cracking reactor. It is particularly useful when one or more of the heavy components (6) has a higher value as pure product than when admixed with methane (11), and when product of a purified hydrogen stream (8) is also desirable.
摘要翻译： 公开了一种从含有氢，一氧化碳，甲烷和比甲烷重的组分的流产生富CO的流的新方法。 该方法利用组合的CO净化和脱甲烷塔（5），降低了该方法的总体资本成本，以及有效的热积分，降低了该过程所需的能量。 该方法可用于从自热裂解反应器的流出物（1）中回收富CO流（10）。 当一种或多种重组分（6）与纯产物相比具有比与甲烷（11）混合时更高的值，并且当还需要纯化氢气流（8）的产物时，这是特别有用的。
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17.发明申请Process for Recovering Ethylene From an Autothermal Cracking Reactor Effluent 审中-公开从热裂解反应器废水中回收乙烯的方法公开(公告)号：US20090112037A1
公开(公告)日：2009-04-30
申请号：US11922761
申请日：2005-07-28
申请人： Rian Reyneke , Michael J. Foral , Graeme Parker , Wayne W.Y. Eng
发明人： Rian Reyneke , Michael J. Foral , Graeme Parker , Wayne W.Y. Eng
IPC分类号： C07C4/04
CPC分类号： F25J3/0252 , C07C4/025 , C07C7/04 , C10G2400/20 , F25J3/0219 , F25J3/0233 , F25J3/0238 , F25J2200/04 , F25J2200/70 , F25J2200/74 , F25J2205/04 , F25J2210/12 , F25J2215/62 , F25J2270/04 , F25J2270/12 , F25J2270/60 , F25J2270/66 , Y02P20/132 , Y02P30/446 , Y02P30/462 , C07C11/02
摘要： The process of this invention represents an improved method for recovering a purified ethylene product and optionally a purified hydrogen product from the effluent of an autothermal cracking reactor. The process consists of cracked gas chilling, rough separation of a hydrogen-rich stream, demethanization, separation of ethylene from the demethanizer bottoms product, and final purification of the ethylene product. Hydrocarbons heavier than ethylene, including ethane, propylene, and propane are recycled to the ATC reactor. Optionally a purified hydrogen product can be obtained from the hydrogen-rich stream. The invention is particularly useful when the fresh hydrocarbons feed to the autothermal cracking reactor is ethane or a mixture of ethane and propane.
摘要翻译： 本发明的方法代表从自热裂解反应器的流出物中回收纯化的乙烯产物和任选的纯化氢产物的改进方法。 该方法包括裂化气体冷却，富氢流的粗分离，脱甲烷化，乙烯脱甲烷塔底产物的分离和乙烯产物的最终纯化。 比乙烯（包括乙烷，丙烯和丙烷）重的烃再循环到ATC反应器中。 任选地，可以从富氢流中获得纯化的氢产物。 当自热裂化反应器的新鲜烃进料为乙烷或乙烷和丙烷的混合物时，本发明特别有用。
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公开(公告)号：US20060135840A1
公开(公告)日：2006-06-22
申请号：US11017159
申请日：2004-12-20
申请人： Rian Reyneke , Michael Foral , Guang-Chung Lee , Wayne Eng , Iain Sinclair , Jeffery Logsdon
发明人： Rian Reyneke , Michael Foral , Guang-Chung Lee , Wayne Eng , Iain Sinclair , Jeffery Logsdon
IPC分类号： C07C7/00
CPC分类号： F25J3/0219 , C07C7/005 , C07C7/04 , C07C7/167 , F25J3/0233 , F25J3/0238 , F25J3/0242 , F25J3/0252 , F25J2205/04 , F25J2210/12 , F25J2215/62 , F25J2270/04 , F25J2270/90 , Y02P20/132 , Y02P30/462 , Y10S62/932 , C07C11/04
摘要： A process for the recovery and purification of ethylene and optionally propylene from a stream containing lighter and heavier components that employs an ethylene distributor column and a partially thermally coupled distributed distillation system.
摘要翻译： 从含有较轻和较重组分的流中回收和纯化乙烯和任选的丙烯的方法，其使用乙烯分配器柱和部分热分散蒸馏系统。
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公开(公告)号：US11530172B2
公开(公告)日：2022-12-20
申请号：US16951384
申请日：2020-11-18
摘要： Methods and systems for steam cracking a mixed butane containing feed stream are disclosed. The feed stream includes n-butane and isobutane. The disclosed methods and systems entail splitting the feed into an enriched n-butane fraction and an enriched isobutane fraction. The enriched n-butane fraction is provided to the cracking furnaces, which yield the olefin products and also yield C4 species. The C4 species are partially hydrogenated and provided as a reactant feed to an alkylation reaction. The enriched isobutane fraction is also provided to the alkylation reaction, whereby high value alkylate product is produced. The disclosed methods and systems have increase olefins (especially ethylene) yield because the feed to the cracking process is enriched in n-butane. The economics are also improved because high value alkylate product is produced from a portion of the isobutane.
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公开(公告)号：US20220153658A1
公开(公告)日：2022-05-19
申请号：US16951384
申请日：2020-11-18
摘要： Methods and systems for steam cracking a mixed butane containing feed stream are disclosed. The feed stream includes n-butane and isobutane. The disclosed methods and systems entail splitting the feed into an enriched n-butane fraction and an enriched isobutane fraction. The enriched n-butane fraction is provided to the cracking furnaces, which yield the olefin products and also yield C4 species. The C4 species are partially hydrogenated and provided as a reactant feed to an alkylation reaction. The enriched isobutane fraction is also provided to the alkylation reaction, whereby high value alkylate product is produced. The disclosed methods and systems have increase olefins (especially ethylene) yield because the feed to the cracking process is enriched in n-butane. The economics are also improved because high value alkylate product is produced from a portion of the isobutane.
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