摘要:
The present invention provides core-shell type metal nanoparticles having a high surface coverage of the core portion with the shell portion, and a method for producing the same. Disclosed is core-shell type metal nanoparticles comprising a core portion comprising a core metal material and a shell portion covering the core portion, wherein the core portion substantially has no {100 } plane of the core metal material on the surface thereof.
摘要:
Core-shell type metal nanoparticles including a core portion and a shell portion covering the core portion, wherein the core portion includes a core metal material selected from metals and alloys, and wherein the shell portion includes an alloy of a first shell metal material and a second shell metal material.
摘要:
A fuel cell 10 includes an MEA 200, an anode separator 100 and a cathode separator 300. The anode separator 100 forms alternate first and second flow channels 110 and 120. The first flow channel 110 is blocked in the middle. The second flow channel 120 is blocked in the both ends. The anode separator 300 forms alternate first and second flow channels 310 and 320. The first flow channel 310 is blocked in the middle. The second flow channel 320 is blocked in the both ends.
摘要:
The present invention provides a fuel cell which is capable of improving electric power generation efficiency at a time of high-temperature operation. The fuel cell 10 comprising: a membrane electrode assembly 4; and a pair of gas separators 7, 8 sandwiching the membrane electrode assembly 4 therebetween, wherein at least one of the gas separator(s) 7 and/or 8 comprises a compact layer(s) 7c and/or 8c which is capable of preventing permeation of fluid and a porous layer (s) 7d and/or 8d which allows permeation of fluid, and the porous layer(s) 7d and/or 8d is impregnated with a water-soluble liquid having higher boiling point than that of water.
摘要:
The present invention provides core-shell type metal nanoparticles having a high surface coverage of the core portion with the shell portion, and a method for producing the same. Disclosed is core-shell type metal nanoparticles comprising a core portion comprising a core metal material and a shell portion covering the core portion, wherein the core portion substantially has no {100} plane of the core metal material on the surface thereof.
摘要:
A fuel cell including a single fuel cell which includes a membrane electrode including a polymer electrolyte membrane, an anode electrode on one surface of the polymer electrolyte membrane, and a cathode electrode on another surface of the polymer electrolyte membrane, the anode electrode including an anode catalyst layer and a gas diffusion layer and the cathode electrode including a cathode catalyst layer and a gas diffusion layer. At least one of the anode cathode catalyst layers includes core-shell type catalyst particles, each having a core and a shell covering the core and including a shell metallic material. At least one of the polymer electrolyte membrane, anode catalyst layer, gas diffusion layer at the anode side, cathode catalyst layer and gas diffusion layer at the cathode side includes metallic nanoparticles having an average particle diameter different from that of the core-shell type catalyst particles and including the shell metallic material.
摘要:
A particle size distribution creating method includes a particle size range determining step, an integrating step of integrating the frequency of appearance of particles within the particle size range determined in the particle size range determining step, a division point determining step of determining particle sizes that provide division points, using the integral of the frequency of appearance obtained in the integrating step, and a typical point determining step of determining the minimum particle size, maximum particle size and the particle sizes of the division points as typical points. This method is characterized by assuming a particle size distribution which contains particles having the particle sizes of the respective typical points and is plotted such that the frequency of appearance of the particles having the particle size of each of the typical points is equal to the integral over each of the regions defined by the typical points, and obtaining the assumed particle size distribution as a particle size distribution model.
摘要:
An object of the present invention is to provide a method for producing fine catalyst particles, a method for producing carbon-supported fine catalyst particles, a method for producing a catalyst mix, and a method for producing an electrode, all of which are configured to inhibit, when used in fuel cells, etc., performance deterioration during operation at especially high temperature. Disclosed is a method for producing fine catalyst particles each comprising a core particle and an outermost layer, the core particle containing palladium and the outermost layer containing platinum and covering the core particle, the method comprising the steps of: preparing palladium-containing particles; preparing an acid solution configured to dissolve palladium more preferentially than platinum; covering each palladium-containing particle with an outermost layer containing platinum; and bringing the palladium-containing particles each covered with the outermost layer into contact with the acid solution.
摘要:
A particle size distribution creating method includes a particle size range determining step, an integrating step of integrating the frequency of appearance of particles within the particle size range determined in the particle size range determining step, a division point determining step of determining particle sizes that provide division points, using the integral of the frequency of appearance obtained in the integrating step, and a typical point determining step of determining the minimum particle size, maximum particle size and the particle sizes of the division points as typical points. This method is characterized by assuming a particle size distribution which contains particles having the particle sizes of the respective typical points and is plotted such that the frequency of appearance of the particles having the particle size of each of the typical points is equal to the integral over each of the regions defined by the typical points, and obtaining the assumed particle size distribution as a particle size distribution model.
摘要:
An object of the present invention is to provide a method for producing fine catalyst particles, a method for producing carbon-supported fine catalyst particles, a method for producing a catalyst mix, and a method for producing an electrode, all of which are configured to inhibit, when used in fuel cells, etc., performance deterioration during operation at especially high temperature. Disclosed is a method for producing fine catalyst particles each comprising a core particle and an outermost layer, the core particle containing palladium and the outermost layer containing platinum and covering the core particle, the method comprising the steps of: preparing palladium-containing particles; preparing an acid solution configured to dissolve palladium more preferentially than platinum; covering each palladium-containing particle with an outermost layer containing platinum; and bringing the palladium-containing particles each covered with the outermost layer into contact with the acid solution.