摘要:
A solid-phase polymerization method of high-molecular-weight aliphatic polyester conducts the solid-phase polymerization of aliphatic polyester prepolymer under a gas stream containing sulfonic acid catalyst. The method features preparing metal free aliphatic polyester with high molecular weight, good color and luster and perfect thermal stability efficiently. The non-metal-ion aliphatic polyester is not only applicable to common use, but is also suitable as high value-added medical material and packing material which contacts with food directly than other metal-containing polyester.
摘要:
A polyester composition comprises a polyester component (a) and polymer particles (b). At least an outermost layer of the polymer particles (b) is of a polymer having hydroxyl groups. The composition can be made into a film especially suitable for use as a substrate in a magnetic recording medium.
摘要:
A polyester composition produced without using an antimony compound as a polycondensation catalyst and including (I) composition containing, on a weight basis, 30 ppm or less of antimony, 0.5 to 50 ppm of titanium, and 0.1 to 100 ppm of phosphorus, in which the number density of titanium-containing particles, the equivalent circular diameter of which is 1μm or more, is less than 100/0.02 mg; and (II) a composition containing, on a weight basis, antimony, titanium and phosphorous as defined above, in which organic polymer particles are contained in amount of 0.1 to 5 wt%, the organic polymer particles having an average particle diameter determined by dynamic light scattering of 0.05 to 3μm and containing 0.01% or less of coarse particles relative to the total number of the particles, the coarse particles having a diameter at least twice the average particle diameter.
摘要:
In a polyester production method, a titanium compound having a radical selected from a carbonyl group, a carboxyl group, or an ester group, and a phosphorous compound having a structure illustrated in Formula (I), are added This yields a polyester composition which does not exhibit increased filter pressure when forming, which has excellent filament and film forming properties, and which has a polymer color tone superb to that of conventional products.
摘要:
The present invention relates to a polyester polymerization catalyst, comprising a solution containing an aluminum compound and an alkali compound, with water or an organic solvent or a mixture consisting of water and an organic solvent as the medium, a production method thereof, and a polyester production method, in which the product obtained by the esterification reaction or ester interchange reaction between an aromatic dicarboxylic acid or any of its ester forming derivative and a diol is polycondensed, to produce a polyester, comprising the use of said polymerization catalyst containing an aluminum compound.The present invention can provide a polyester excellent in processability and can overcome such problems as spinneret contamination, filtration pressure rise, filament breaking, film breaking and foreign matter production in the production process of products such as fibers, films, resins and bottles.
摘要:
Disclosed are a thermoplastic polyester composition comprising a thermoplastic polyester (A) prepared from an acid component mainly comprising an aromatic dicarboxylic acid and a glycol component mainly comprising an aliphatic glycol and .theta.-type aluminum oxide particles (B); a thermoplastic polyester composition comprising the thermoplastic polyester (A) and a mixture (C) of two or more kinds of aluminum oxide particles different from each other in crystal structure; and films made from these compositions. Particularly, the films formed from the compositions can have excellent slipping property, abrasion resistance, and scratch resistance in repeated high-speed running.
摘要:
Disclosed is a biaxially oriented film and a laminated film containing specified organic particles at a content of 0.001 to 20% by weight. The strength when deformed by 10% (S.sub.10) of the organic particles is in the range of 3 to 30 kgf/mm.sup.2, the thermal decomposition temperature for causing 10% loss in weight thereof is not lower than 350.degree. C. The weight average diameter thereof is in the range of 0.005 to 5 .mu.m. Since the organic particles have a good affinity with the matrix resin of the film and a good thermal resistance and the hardness of the particles is appropriate, desired protrusions hardly chipped and having an appropriate hardness for hardly scratching a magnetic surface can be formed on a film surface easily and uniformly. Therefore, a film excellent in abrasion resistance and scratch resistance at a high running speed and excellent in running durability can be obtained, which is useful particularly as a base film of a magnetic tape.
摘要翻译:公开了含有0.001〜20重量%的特定有机粒子的双轴取向膜和层叠膜。 当有机颗粒变形10%(S10)时的强度在3〜30kgf / mm 2的范围内,其重量减少10%的热分解温度不低于350℃。重量平均直径 为0.005〜5μm的范围。 由于有机颗粒与膜的基质树脂具有良好的亲和性,并且具有良好的耐热性,并且颗粒的硬度是合适的,因此可以在薄膜上形成难以切割并且具有难以刮擦磁性表面的适当硬度的所需突起 表面容易均匀。 因此,可以获得在高运行速度下具有优异的耐磨性和耐擦伤性的膜,并且可以获得特别用作磁带的基膜的运行耐久性优异的运行耐久性优异的膜。