Borosilicate glasses with low alkali content

    公开(公告)号:US10329186B2

    公开(公告)日:2019-06-25

    申请号:US15384687

    申请日:2016-12-20

    Abstract: According to one embodiment, a glass may include from about 50 mol. % to about 70 mol. % SiO2; from about 12 mol. % to about 35 mol. % B2O3; from about 4 mol. % to about 12 mol. % Al2O3; greater than 0 mol. % and less than or equal to 1 mol. % alkali metal oxide, wherein Li2O is greater than or equal to about 20% of the alkali metal oxide; from about 0.3 mol. % to about 0.7 mol. % of Na2O or Li2O; and greater than 0 mol. % and less than 12 mol. % of total divalent oxide, wherein the total divalent oxide includes at least one of CaO, MgO and SrO, and wherein a ratio of Li2O (mol. %) to (Li2O (mol. %)+(Na2O (mol. %)) is greater than or equal 0.4 and less than or equal to 0.6. The glass may have a relatively low high temperature resistivity and a relatively high low temperature resistivity.

    COLORED ALKALI ALUMINOSILICATE GLASS ARTICLES
    124.
    发明申请

    公开(公告)号:US20190071345A1

    公开(公告)日:2019-03-07

    申请号:US16180563

    申请日:2018-11-05

    Abstract: A glass article including at least about 40 mol % SiO2 and, optionally, a colorant imparting a preselected color is disclosed. In general, the glass includes, in mol %, from about 40-70 SiO2, 0-25 Al2O3, 0-10 B2O3; 5-35 Na2O, 0-2.5 K2O, 0-8.5 MgO, 0-2 ZnO, 0-10% P2O5 and 0-1.5 CaO. As a result of ion exchange, the glass includes a compressive stress (σs) at at least one surface and, optionally, a color. In one method, communicating a colored glass with an ion exchange bath imparts σs while in another; communicating imparts σs and a preselected color. In the former, a colorant is part of the glass batch while in the latter; it is part of the bath. In each, the colorant includes one or more metal containing dopants formulated to impart to a preselected color. Examples of one or more metal containing dopants include one or more transition and/or rare earth metals.

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