Abstract:
To provide a good and simple method for decomposing and detoxifying a hardly decomposable fluorinated organic compound.Specifically, a fluorinated organic compound is decomposed by bringing an aqueous solution of the fluorinated organic compound into contact with a catalyst containing a metal oxide. The metal oxide may preferably be an oxide of at least one metal selected from the group consisting of Ni, Pd, Cu, Mn, Fe and Co, and more preferably be nickel oxide. The contact temperature is preferably within the range of from 0 to 100° C. Preferably, the fluorinated organic compound to be decomposed is an organic fluorocarboxylic acid, an organic fluorosulfonic acid or a salt thereof, which is used as a surfactant or an surface treatment agent.
Abstract:
In order to remove fluorine from a zinc containing solution before zinc electro-refining in lower cost, fluorine is removed by adsorption from a zinc containing solution (leached solution) utilizing the character of the predetermined iron compound or zinc compound which can adsorb fluorine in an acid solution and desorb fluorine in an alkaline solution. The fluorine adsorbent/desorbent having adsorbed fluorine is treated in an alkaline solution, to desorb the fluorine. This makes it possible to regenerate the fluorine adsorbent/desorbent. Further, an electrolytic solution for zinc electro-refining can be prepared in lower cost, thus total zinc refining costs can be reduced.
Abstract:
A method for the treatment of waste water from florfenicol production is provided, which mainly comprises the steps as follows: adding iron chips or steel slag to waste water from a copper salt workshop, regulating the pH value, filtering, then adding limestone, lime or Ca(OH)2 and having a solid-liquid separation; blending the treated waste water and waste water from a splitting workshop, oxidizing the residual reductive matter by ozone and removing NH3-N by blowing; blending the treated water and waste water from esterifying or florfenicol workshops and diluting the blended water, adding phosphate and microelement, regulating the pH value, then having an anaerobic treatment in an anaerobic reactor; diluting the treated waste water, then having an aerobic treatment in an aerobic reactor. The method also can comprise the steps as follows: blending the waste water from all workshops, adding phosphate and microelement, regulating the pH value, blending the treated waste water with recycling anaerobic water and having a settling treatment, then having an anaerobic treatment in an anaerobic granular sludge bed reactor, diluting the treated waste water and having an aerobic treatment in a SBR.
Abstract:
A method for removing fluorine from wastewater includes the steps of: adding a fluorine-reactive agent, that comprises a water-soluble sodium compound and a water-soluble aluminum compound, into the wastewater so as to form sodium ions and aluminum ions in the wastewater and so as to precipitate sodium aluminum fluoride by reaction of the sodium ions and the aluminum ions with fluorine ions in the wastewater; and removing the precipitate of sodium aluminum fluoride from the wastewater.