公开(公告)号：US09096562B2

公开(公告)日：2015-08-04

申请号：US13950973

申请日：2013-07-25

Applicant: Scientific Design Company, Inc.

Inventor： Andrzej Rokicki ,  Jason Durand ,  Rudy Anthony Morin ,  Wojciech Suchanek

IPC: C07D301/10 ,  B01J7/00 ,  B01J37/08 ,  B01J38/12 ,  B01J21/04 ,  B01J23/50 ,  B01J23/96 ,  B01J35/00 ,  B01J37/02 ,  B01J8/10 ,  B01J35/10

CPC classification number: C07D301/10 ,  B01J7/00 ,  B01J21/04 ,  B01J23/50 ,  B01J23/96 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/08 ,  B01J38/12 ,  Y02P20/52 ,  Y02P20/584

Abstract: A method for producing ethylene oxide comprising: providing one or more feed components, wherein the one or more feed components contains at least ethylene obtained by dehydrating ethanol; contacting the one or more feed components with a desulfurization catalyst comprising a high surface area support and an amount of silver, wherein at least 20% of the silver is present as oxidized silver; and contacting the one or more feed components with a silver-containing epoxidation catalyst disposed inside an ethylene oxide reactor to form a reaction gas comprising ethylene oxide.

Abstract translation: 一种生产环氧乙烷的方法，包括：提供一种或多种进料组分，其中所述一种或多种进料组分至少包含通过使乙醇脱水得到的乙烯; 使一种或多种进料组分与包含高表面积载体和一定量的银的脱硫催化剂接触，其中至少20％的银以氧化银的形式存在; 并使一种或多种进料组分与设置在环氧乙烷反应器内部的含银环氧化催化剂接触以形成包含环氧乙烷的反应气体。

公开(公告)号：US08975424B1

公开(公告)日：2015-03-10

申请号：US14143684

申请日：2013-12-30

Applicant: Scientific Design Company, Inc.

Inventor： Wojciech Suchanek ,  Andrzej Rokicki

IPC: C07D301/10 ,  B01J23/66

CPC classification number: B01J23/66 ,  B01J23/688 ,  C07D301/10

Abstract: A silver-based ethylene oxide catalyst is provided that has enhanced stability. The enhanced stability is obtained in the present invention by providing a silver-based ethylene oxide catalyst that includes from 100 ppm to 1000 ppm of zinc, and from greater than 450 ppm to less than 800 ppm of cesium. Zinc and cesium are promoters that are introduced to a finished carrier either prior to, coincidentally with, or subsequent to the deposition of the silver. The silver-based ethylene oxide catalyst can be used in the epoxidation of ethylene to ethylene oxide.

Abstract translation: 提供了具有增强的稳定性的银基环氧乙烷催化剂。 通过提供包含100ppm至1000ppm锌以及大于450ppm至小于800ppm的铯的银基环氧乙烷催化剂，在本发明中获得了增强的稳定性。 锌和铯是在银沉积之前，巧合地或之后引入成品载体的促进剂。 银基环氧乙烷催化剂可用于乙烯至环氧乙烷的环氧化。

公开(公告)号：US09321035B2

公开(公告)日：2016-04-26

申请号：US14175401

申请日：2014-02-07

Applicant: Scientific Design Company, Inc.

Inventor： Wojciech Suchanek ,  Andrzej Rokicki

IPC: B01J23/66 ,  B01J21/04 ,  B01J23/50

CPC classification number: B01J23/66 ,  B01J21/04 ,  B01J23/002 ,  B01J23/50 ,  B01J23/688 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/023 ,  B01J35/026 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1076 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/06 ,  B01J37/08 ,  C04B35/1115 ,  C04B35/117 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/3222 ,  C04B2235/3284 ,  C04B2235/3409 ,  C04B2235/3817 ,  C04B2235/3852 ,  C04B2235/40 ,  C04B2235/442 ,  C04B2235/446 ,  C04B2235/448 ,  C04B2235/52 ,  C04B2235/6021 ,  C07D301/08 ,  C07D301/10 ,  Y02P20/52

Abstract: Silver based ethylene oxide catalysts having enhanced stability are disclosed. The enhanced stability silver based ethylene oxide catalysts include an alumina carrier which has been modified to include cavities on the surface of the carrier. The presence of the cavities on the surface of the modified carrier stops or at least impedes the motion of silver particles on the surface of the carrier during an epoxidation process. In particular, the cavities on the surface of the alumina carrier effectively trap and/or anchor silver particles and prevent them from further motion.

Abstract translation: 公开了具有增强的稳定性的银基环氧乙烷催化剂。 增强稳定性的银基环氧乙烷催化剂包括氧化铝载体，其已被改性以在载体的表面上包括空腔。 在环氧化过程中，改性载体表面上的空腔的存在停止或至少阻止银颗粒在载体表面上的运动。 特别地，氧化铝载体表面上的空穴有效地俘获和/或锚定银颗粒并防止它们进一步运动。

公开(公告)号：US20140031568A1

公开(公告)日：2014-01-30

申请号：US13950973

申请日：2013-07-25

Applicant: Scientific Design Company, Inc.

Inventor： Andrzej Rokicki ,  Jason Durand ,  Rudy Anthony Morin ,  Wojciech Suchanek

IPC: C07D301/10 ,  B01J7/00

CPC classification number: C07D301/10 ,  B01J7/00 ,  B01J21/04 ,  B01J23/50 ,  B01J23/96 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/08 ,  B01J38/12 ,  Y02P20/52 ,  Y02P20/584

Abstract: A method for producing ethylene oxide comprising: providing one or more feed components, wherein the one or more feed components contains at least ethylene obtained by dehydrating ethanol; contacting the one or more feed components with a desulfurization catalyst comprising a high surface area support and an amount of silver, wherein at least 20% of the silver is present as oxidized silver; and contacting the one or more feed components with a silver-containing epoxidation catalyst disposed inside an ethylene oxide reactor to form a reaction gas comprising ethylene oxide.

Abstract translation: 一种生产环氧乙烷的方法，包括：提供一种或多种进料组分，其中所述一种或多种进料组分至少包含通过使乙醇脱水得到的乙烯; 使一种或多种进料组分与包含高表面积载体和一定量的银的脱硫催化剂接触，其中至少20％的银以氧化银的形式存在; 并使一种或多种进料组分与设置在环氧乙烷反应器内部的含银环氧化催化剂接触以形成包含环氧乙烷的反应气体。

公开(公告)号：US20140221196A1

公开(公告)日：2014-08-07

申请号：US14175401

申请日：2014-02-07

Applicant: Scientific Design Company, Inc.

Inventor： Wojciech Suchanek ,  Andrzej Rokicki

IPC: B01J23/66 ,  B01J23/50 ,  B01J21/04

CPC classification number: B01J23/66 ,  B01J21/04 ,  B01J23/002 ,  B01J23/50 ,  B01J23/688 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/023 ,  B01J35/026 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1076 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/06 ,  B01J37/08 ,  C04B35/1115 ,  C04B35/117 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/3222 ,  C04B2235/3284 ,  C04B2235/3409 ,  C04B2235/3817 ,  C04B2235/3852 ,  C04B2235/40 ,  C04B2235/442 ,  C04B2235/446 ,  C04B2235/448 ,  C04B2235/52 ,  C04B2235/6021 ,  C07D301/08 ,  C07D301/10 ,  Y02P20/52

Abstract: Silver based ethylene oxide catalysts having enhanced stability are disclosed. The enhanced stability silver based ethylene oxide catalysts include an alumina carrier which has been modified to include cavities on the surface of the carrier. The presence of the cavities on the surface of the modified carrier stops or at least impedes the motion of silver particles on the surface of the carrier during an epoxidation process. In particular, the cavities on the surface of the alumina carrier effectively trap and/or anchor silver particles and prevent them from further motion.

Abstract translation: 公开了具有增强的稳定性的银基环氧乙烷催化剂。 增强稳定性的银基环氧乙烷催化剂包括氧化铝载体，其已被改性以在载体的表面上包括空腔。 在环氧化过程中，改性载体表面上的空腔的存在停止或至少阻止银颗粒在载体表面上的运动。 特别地，氧化铝载体表面上的空穴有效地俘获和/或锚定银颗粒并防止它们进一步运动。