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公开(公告)号:US11090633B2
公开(公告)日:2021-08-17
申请号:US16743714
申请日:2020-01-15
Applicant: SABIC Global Technologies B.V.
Inventor: Wugeng Liang , David West , Hector Perez , Sagar Sarsani , Luanyi Elizabeth Li , Pankaj Gautam
Abstract: A catalyst composition, suitable for producing ethylene and other C2+ hydrocarbons from methane. The composition includes a blended product of two distinct catalyst components, blended at such synergistic proportions, that results in a catalyst having high C2+ hydrocarbon selectivity while maintaining an overall sufficient catalyst activity and low ethyne selectivity. Methods for preparing such a catalyst composition and a process for producing C2+ hydrocarbons using such a catalyst composition are provided.
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公开(公告)号:US10941088B1
公开(公告)日:2021-03-09
申请号:US16965370
申请日:2019-05-02
Applicant: SABIC Global Technologies B.V.
Inventor: Sagar Sarsani , David West , Vemuri Balakotaiah , Tian Gu
Abstract: A method of autothermal oxidative coupling of methane (OCM) utilizes introducing a methane-containing feedstock and an oxygen-gas-containing feedstock into a reactor (10) as a flowing mixture (18) with a space time of 500 ms or less. The reactor (10) contains a catalyst bed (20) of an OCM catalyst that contacts the flowing mixture and wherein the catalyst bed (20) has a heat Peclet number (Peh) of from 5 or less, a mass Peclet number (Pem) of from 5 or more, and a transverse Peclet number (P) of from 1 or less while contacting the flowing mixture. The methane and oxygen of the feedstocks are allowed to react within the reactor (10) to form methane oxidative coupling reaction products. A reactor (10) for carrying out the OCM reaction is also disclosed.
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公开(公告)号:US10995044B2
公开(公告)日:2021-05-04
申请号:US16946688
申请日:2020-07-01
Applicant: SABIC Global Technologies B.V.
Inventor: Sagar Sarsani , David West , Vemuri Balakotaiah , Wugeng Liang , Jonathan Banke
Abstract: Methods of performing a startup of an oxidative coupling of methane reaction to produce C2+ hydrocarbons are described. The methods can include incrementally varying startup parameters of the oxidative methane reactor and using the feed gas as a coolant such that high C2+ hydrocarbon selectivity is achieved.
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公开(公告)号:US10696607B2
公开(公告)日:2020-06-30
申请号:US15579385
申请日:2016-05-02
Applicant: SABIC Global Technologies B.V.
Inventor: Wugeng Liang , Sagar Sarsani , David West , James Lowrey , Aghaddin Mamedov , Istvan Lengyel
Abstract: Disclosed is a process for producing C2+ hydrocarbons, and systems for implementing the process, that includes providing a reactant feed that includes methane and an oxygen containing gas to a first reaction zone, wherein the temperature of the reactant feed is less than 700° C. contacting the reactant feed with a first catalyst capable of catalyzing an oxidative coupling of methane reaction (OCM) to produce a first product stream that includes C2+ hydrocarbons and heat, and contacting the first product stream with a second catalyst capable of catalyzing an OCM reaction to produce a second product stream that includes C2+ hydrocarbons, wherein the produced heat is at least partially used to heat the first product stream prior to or during contact with the second catalyst, wherein the amount of C2+ hydrocarbons in the second product stream is greater than the amount of C2+ hydrocarbons in the first product stream.
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公开(公告)号:US20170240488A1
公开(公告)日:2017-08-24
申请号:US15518930
申请日:2015-12-09
Applicant: SABIC Global Technologies B.V
Inventor: David West , Wugeng Liang , Sagar Sarsani , Vemuri Balakotaiah , Aghaddin Mamedov
CPC classification number: C07C2/84 , B01J8/0278 , B01J21/08 , B01J23/002 , B01J23/34 , B01J35/0006 , B01J2523/00 , C01B3/38 , C01B2203/0238 , C01B2203/0838 , C01B2203/1041 , C01B2203/1082 , C01B2203/1241 , C07C2521/04 , C07C2521/08 , C07C2521/10 , C07C2523/04 , C07C2523/10 , C07C2523/30 , C07C2523/34 , Y02P20/128 , Y02P20/52 , B01J2523/12 , B01J2523/3706 , B01J2523/41 , B01J2523/69 , B01J2523/72 , C07C11/04
Abstract: Disclosed is a method for production of ethylene by an oxidative coupling of methane process in the presence of a catalytic material. Heat generated from the oxidative coupling of methane can be transferred to an inert material in an amount sufficient to reduce thermal deactivation of the catalytic material.
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公开(公告)号:US11666879B2
公开(公告)日:2023-06-06
申请号:US16981444
申请日:2019-04-18
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Wugeng Liang , Sagar Sarsani , David West , James Kauffman , Jonathan Banke , Hector Perez , Robert C. Schucker , Tian Gu , Vemuri Balakotaiah
CPC classification number: B01J8/0278 , B01J8/0285 , C07C2/84 , B01J2208/00115 , B01J2208/022 , C07C2523/10
Abstract: Disclosed herein are systems and processes for the conversion of a methane feedstock to C2+ hydrocarbons.
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公开(公告)号:US11091410B2
公开(公告)日:2021-08-17
申请号:US16491398
申请日:2018-03-05
Applicant: SABIC Global Technologies, B.V.
Inventor: Wugeng Liang , Sagar Sarsani , Aghaddin Mamedov , Hector Perez , David West , Istvan Lengyel
Abstract: A mixed oxide catalyst for the oxidative coupling of methane can include a catalyst with the formula AaBbCcDdOx, wherein: element A is selected from alkaline earth metals; elements B and C are selected from rare earth metals, and wherein elements B and C are different rare earth metals; the oxide of at least one of A, B, C, and D has basic properties; the oxide of at least one of A, B, C, and D has redox properties; and elements A, B, C, and D are selected to create a synergistic effect whereby the catalytic material provides a methane conversion of greater than or equal to 15% and a C2+ selectivity of greater than or equal to 70%. Systems and methods can include contacting the catalyst with methane and oxygen and purifying or collecting C2+ products.
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公开(公告)号:US10702856B2
公开(公告)日:2020-07-07
申请号:US16303278
申请日:2017-05-16
Applicant: SABIC Global Technologies B.V.
Inventor: Wugeng Liang , Sagar Sarsani , David West
IPC: B01J23/34 , C07C2/84 , B01J37/04 , B01J37/08 , B01J23/00 , B01J21/08 , B01J23/04 , C07C11/04 , C07C27/14 , C07C29/48 , C07C31/08 , B01J37/02 , B01J35/00
Abstract: Disclosed is a supported catalyst and methods to prepare and use the supported catalyst in an oxidative coupling of methane (OCM) reaction. The supported catalyst can contain MnWO4 or MnWO4 nanostructures that are in contact with the surface of a sodium containing silicon dioxide support material. The supported MnWO4 catalyst can have an active MnWO4 crystal phase.
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公开(公告)号:US20200048164A1
公开(公告)日:2020-02-13
申请号:US16343095
申请日:2017-10-17
Applicant: SABIC Global Technologies B.V.
Inventor: Sagar Sarsani , Wugeng Liang , Dick Nagaki , Krishnan Sankaranarayanan , David West , Aghaddin Mamedov
Abstract: A method of selecting a stable mixed metal oxide catalyst for an oxidative coupling of methane (OCM) reaction is disclosed. The method may include, obtaining a mixed metal oxide material having catalytically active metal oxides for the OCM reaction and identifying the Tammann temperature (TTam) of at least one of the catalytically active metals oxides of the mixed metal oxide material. The method further includes selecting the mixed metal oxide material for use as a catalyst in the OCM reaction if the at least one catalytically active metal oxides present in the mixed metal oxide material has a TTam greater than a predetermined temperature.
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公开(公告)号:US20180162785A1
公开(公告)日:2018-06-14
申请号:US15579385
申请日:2016-05-02
Applicant: SABIC Global Technologies B.V.
Inventor: Wugeng Liang , Sagar Sarsani , David West , James Lowrey , Aghaddin Mamedov , Istvan Lengyel
CPC classification number: C07C2/84 , B01J19/245 , B01J21/08 , B01J23/10 , B01J23/34 , B01J35/0006 , B01J35/002 , B01J37/0236 , B01J2219/00074 , B01J2219/24 , C07C2521/08 , C07C2523/04 , C07C2523/10 , C07C2523/30 , C07C2523/34 , Y02P20/52 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C11/08
Abstract: Disclosed is a process for producing C2+ hydrocarbons, and systems for implementing the process, that includes providing a reactant feed that includes methane and an oxygen containing gas to a first reaction zone, wherein the temperature of the reactant feed is less than 700° C. contacting the reactant feed with a first catalyst capable of catalyzing an oxidative coupling of methane reaction (OCM) to produce a first product stream that includes C2+ hydrocarbons and heat, and contacting the first product stream with a second catalyst capable of catalyzing an OCM reaction to produce a second product stream that includes C2+ hydrocarbons, wherein the produced heat is at least partially used to heat the first product stream prior to or during contact with the second catalyst, wherein the amount of C2+ hydrocarbons in the second product stream is greater than the amount of C2+ hydrocarbons in the first product stream.
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