公开(公告)号：US09751822B2

公开(公告)日：2017-09-05

申请号：US15027351

申请日：2014-10-07

申请人： Nippon Kayaku Kabushiki Kaisha

发明人： Tatsuhiko Kurakami ,  Hideomi Sakai ,  Toru Toki

IPC分类号： C07C51/25 ,  C07C51/215 ,  C07C51/235 ,  B01J31/36 ,  B01J37/08 ,  B01J23/00 ,  B01J23/888 ,  B01J35/10 ,  B01J37/00 ,  B01J27/199 ,  B01J27/24

CPC分类号： C07C51/252 ,  B01J23/002 ,  B01J23/8885 ,  B01J27/199 ,  B01J27/24 ,  B01J31/36 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/088 ,  B01J2523/00 ,  C07C51/215 ,  C07C51/235 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

摘要： The present invention relates to a method for producing an unsaturated carboxylic acid using a catalyst having both a high catalytic performance and a high mechanical strength, and in the method, a supported catalyst obtained by feeding a liquid binder component and a catalytic active component containing molybdenum and vanadium and/or a precursor thereof into a rolling granulator and conducting granulation at a relative centrifugal acceleration of 0.5 G or more and 30 G or less is used.

公开(公告)号：US20160244393A1

公开(公告)日：2016-08-25

申请号：US15027351

申请日：2014-10-07

申请人： NIPPON KAYAKU KABUSHIKI KAISHA

发明人： Tatsuhiko Kurakami ,  Hideomi Sakai ,  Toru Toki

IPC分类号： C07C51/25 ,  B01J27/24 ,  B01J27/199 ,  B01J23/888

CPC分类号： C07C51/252 ,  B01J23/002 ,  B01J23/8885 ,  B01J27/199 ,  B01J27/24 ,  B01J31/36 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/088 ,  B01J2523/00 ,  C07C51/215 ,  C07C51/235 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

摘要： The present invention relates to a method for producing an unsaturated carboxylic acid using a catalyst having both a high catalytic performance and a high mechanical strength, and in the method, a supported catalyst obtained by feeding a liquid binder component and a catalytic active component containing molybdenum and vanadium and/or a precursor thereof into a rolling granulator and conducting granulation at a relative centrifugal acceleration of 0.5 G or more and 30 G or less is used.

摘要翻译： 本发明涉及一种使用催化剂具有高催化性能和高机械强度的催化剂制备不饱和羧酸的方法，该方法是将含有钼的催化活性成分和含有钼的催化活性成分 钒和/或其前体加入到滚压造粒机中，并以0.5G以上至30G以下的相对离心加速度进行造粒。

公开(公告)号：US20150105583A1

公开(公告)日：2015-04-16

申请号：US14401560

申请日：2013-05-16

申请人： Nippon Kayaku Kabushiki Kaisha

发明人： Hideomi Sakai ,  Eiji Nishimura ,  Tomoyuki Ejiri

IPC分类号： B01J27/24 ,  C07C51/25

CPC分类号： B01J27/24 ,  B01J23/002 ,  B01J27/199 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/04 ,  B01J2523/00 ,  C07C51/235 ,  C07C51/252 ,  C07C51/377 ,  C07C57/04 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/68

摘要： An object of the present invention is to provide a process for producing a catalyst for gas-phase contact oxidation of methacrolein, isobutyraldehyde or isobutyric acid to produce methacrylic acid in a high yield and a high selectivity, and a catalyst wherein an alkali metal element, particularly cesium among alkali metal elements, is added by a specific method in a partially neutralized salt of a hetero polyacid which contains Mo, V, P, an alkali metal element and NH4 as essential active ingredients, the catalyst being characterized by having extremely high catalytic performance.

摘要翻译： 本发明的目的是提供一种制备用于甲基丙烯醛，异丁醛或异丁酸的气相接触氧化的催化剂以高产率和高选择性生产甲基丙烯酸的方法，以及催化剂，其中碱金属元素， 特别是碱金属元素中的铯通过特定方法在含有Mo，V，P，碱金属元素和NH 4作为必需活性成分的杂多酸的部分中和盐中加入，催化剂的特征在于具有极高的催化性 性能。