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21 条记录 (耗时 0.016 秒)

    Process for the preparation of an olefin polymer
    3.
    发明授权
    Process for the preparation of an olefin polymer 失效
    制备烯烃聚合物的方法

    公开(公告)号：US5204429A

    公开(公告)日：1993-04-20

    申请号：US228543

    申请日：1988-08-04

    申请人： Walter Kaminsky ,  Regina Spiehl

    发明人： Walter Kaminsky ,  Regina Spiehl

    IPC分类号： C08F4/64 ,  C08F4/60 ,  C08F4/642 ,  C08F4/6592 ,  C08F32/04

    CPC分类号： C08F32/04 ,  Y10S526/943

    摘要： Crystalline, isotactic homopolymers of cycloolefins or elastic copolymers made from cycloolefins and linear olefins are obtained, without ring opening of the cycloolefins, at industrially favorable polymerization temperatures by means of a catalyst which comprises a stereorigid, chiral metallocene compound of groups IVb to VIb of the Periodic Table of the Elements and an aluminoxane.

    摘要翻译： 通过催化剂，在工业上有利的聚合温度下，由环烯烃和直链烯烃制成的环状烯烃的全同立构均聚物或由环烯烃和直链烯烃制成的弹性共聚物得到，不用环烯烃开环，所述催化剂包含立体刚性的基团IVb至VIb的手性茂金属化合物 元素周期表和铝氧烷。

    Process for the preparation of polyolefins
    4.
    发明授权
    Process for the preparation of polyolefins 失效
    制备聚烯烃的方法

    公开(公告)号：US4542199A

    公开(公告)日：1985-09-17

    申请号：US559838

    申请日：1983-12-08

    申请人： Walter Kaminsky ,  Heinrich Hahnsen ,  Klaus Kulper ,  Rudiger Woldt

    发明人： Walter Kaminsky ,  Heinrich Hahnsen ,  Klaus Kulper ,  Rudiger Woldt

    IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65925 ,  Y10S526/943

    摘要： The invention relates to a process for the preparation of polyolefins by polymerizing olefins of the formula CH.sub.2 CHR in which R=H or C.sub.1 -C.sub.10 alkyl, on their own or as a mixture, if appropriate together with C.sub.4 -C.sub.12 .alpha.,.omega.-diolefins, in solvents, liquid monomers or the gas phase, at temperatures between -50.degree. and 200.degree. C., using a catalyst system composed of a soluble, halogen-containing transition metal compound of the general formula(cyclopentadienyl).sub.2 Me R Halin which R is cyclopentadienyl or a C.sub.1 -C.sub.6 alkyl radical or a halogen, in particular chlorine, Me is a transition metal, in particular zirconium, and Hal is a halogen, in particular chlorine, and a compound, containing aluminum, of the aluminoxane type having the general formulaeAl.sub.2 OR.sub.4 (Al(R)--O).sub.nfor a linear aluminoxane and/or(Al(R)--O).sub.n+2for a cyclic aluminoxane, in which n is a number from 4 to 20 and R is a methyl or ethyl radical, preferably a methyl radical.

    摘要翻译： 本发明涉及一种制备聚烯烃的方法，该方法通过将其中R = H或C 1 -C 10烷基的式CH 2 CHR的烯烃自身或作为混合物如果合适地与C4-C12α，ω-二烯烃， 在溶剂，液体单体或气相中，在-50℃和200℃之间的温度下，使用由可溶性的含卤素的通式（环戊二烯基）2 Me R Hal的过渡金属化合物组成的催化剂体系，其中 R是环戊二烯基或C 1 -C 6烷基或卤素，特别是氯，Me是过渡金属，特别是锆，Hal是卤素，特别是氯，以及含有铝的化合物，铝氧烷类具有 对于环状铝氧烷，线性铝氧烷和/或（Al（R）-O）n + 2的通式为Al 2 OR 4（Al（R）-O）n，其中n为4至20的数，R为 甲基或乙基，优选甲基。

    Oxygen-containing organoaluminium complexes as cocatalysts
    5.
    发明申请
    Oxygen-containing organoaluminium complexes as cocatalysts 失效
    含氧有机铝络合物作为助催化剂

    公开(公告)号：US20060199926A1

    公开(公告)日：2006-09-07

    申请号：US10527818

    申请日：2002-09-13

    申请人： Katrin Koehler ,  Eike Poetsch ,  Jens Eichhorn ,  Herbert Schumann ,  Birgit Wassermann ,  Sebastiain Dechert ,  Markus Hummert ,  Stefan Schutte ,  Walter Kaminsky ,  Andrea Eisenhardt ,  Manfred Arnold

    发明人： Katrin Koehler ,  Eike Poetsch ,  Jens Eichhorn ,  Herbert Schumann ,  Birgit Wassermann ,  Sebastiain Dechert ,  Markus Hummert ,  Stefan Schutte ,  Walter Kaminsky ,  Andrea Eisenhardt ,  Manfred Arnold

    IPC分类号： C08F4/44

    CPC分类号： C08F110/02 ,  C07F5/066 ,  C08F4/6543 ,  C08F4/642 ,  C08F2500/01

    摘要： The present invention relates to novel oxygen-containing organoaluminium complexes of the general formula (I) in which R1, independently of one another, denote branched or unbranched C1-C7-alkyl, -cycloalkyl, -alkenyl, -cycloalkenyl, -aryl or -alkynyl; R2 denotes unsubstituted, mono- or polyalkylated and/or mono- or polyfluorinated aromatic hydrocarbons from the group R3, R4, independently of one another, denote CH2, CF2 or C(R1)2; independently of one another, m denotes 0, 1, 2 n denotes 0, 1, 2. These compounds can serve as cocatalysts in olefinic polymerisation reactions. In particular, they can be employed for the preparation of novel Ziegler-Natta catalysts having improved properties, in particular having higher activities compared with conventional Ziegler-Natta catalysts with AlEt3, as cocatalyst, or of novel coordination catalyst systems which have higher activities than conventional Ziegler-Natta catalysts, even at low temperatures, such as 60° C., and a pressure of 2 bar.

    摘要翻译： 本发明涉及通式（I）的新型含氧有机铝络合物，其中R 1彼此独立地表示支链或非支链C 1 -C - 烷基， - 环烷基， - 烯基， - 环烯基， - 芳基或 - 炔基; R 2表示未取代的单或多烷基化和/或单烷基化和/或单氟化或多氟化芳族烃，其中R 3，R 4，R 4， 另一个，表示CH 2，CF 2或C（R 1）2个2。 彼此独立地，m表示0,1,2表示0,1,2。这些化合物可用作烯烃聚合反应中的助催化剂。 特别地，它们可以用于制备具有改进性能的新型齐格勒 - 纳塔催化剂，特别是与具有AlEt 3 3的常规齐格勒 - 纳塔催化剂作为助催化剂或具有新协同作用的活性相比具有更高的活性 具有比常规齐格勒 - 纳塔催化剂更高活性的催化剂体系，即使在低温下，例如60℃，压力为2巴。

    Process for reprocessing waste material
    6.
    发明授权
    Process for reprocessing waste material 失效
    废物后处理工艺

    公开(公告)号：US4871426A

    公开(公告)日：1989-10-03

    申请号：US289608

    申请日：1988-12-23

    申请人： Hans Lechert ,  Volkert Woebs-Gosch ,  Song Qun ,  Walter Kaminsky ,  Hansjorg Sinn

    发明人： Hans Lechert ,  Volkert Woebs-Gosch ,  Song Qun ,  Walter Kaminsky ,  Hansjorg Sinn

    IPC分类号： B29B17/00 ,  C10B53/07 ,  C10G1/00 ,  C10G1/10

    CPC分类号： C10G1/002

    摘要： A liquid fraction and a gas fraction produced during the reprocessing of waste material containing CH compounds by pyrolysis, have a mass ratio approximately equal to 1. Since the liquid fraction is more suitable for further processing than the gas fraction, there is an incentive to augment the liquid fraction at the expense of the gas fraction. In order to achieve this object, the pyrolysis gas is cooled until the benzene and the higher-boiling gaseous constituents of the pyrolysis gas pass into the liquid phase, so that a benzene-containing liquid fraction is produced. A gas mixture containing benzene and toluene is stripped out of the benzene-containing liquid fraction, passed together with the gas fraction at a temperature of 300.degree. to 450.degree. C. over a zeolitic catalyst and then separated by cooling into both a fraction which is liquid at atmospheric pressure and a residual gas fraction. As a result, the proportion of the liquid fraction is substantially increased and the economics of the process are substantially improved.

    摘要翻译： 在通过热解对含有CH化合物的废料进行后处理时产生的液体馏分和气体馏分的质量比近似等于1.由于液体馏分比气体馏分更适合于进一步加工，因此有助于增加 以液体馏分为代价的气体馏分。 为了达到这个目的，将热解气体冷却直到热解气体的苯和较高沸点的气态成分进入液相，从而产生含苯的液体馏分。 将含有苯和甲苯的气体混合物从含苯液体馏分中汽提出来，与气体馏分在300-450℃的温度下通过沸石催化剂一起通过冷却分离成两部分 大气压下的液体和残留气体馏分。 结果，液体部分的比例显着增加，并且该方法的经济性显着提高。

    Process for the preparation of oligomeric aluminoxanes
    7.
    发明授权
    Process for the preparation of oligomeric aluminoxanes 失效
    制备低聚铝氧烷的方法

    公开(公告)号：US4544762A

    公开(公告)日：1985-10-01

    申请号：US546862

    申请日：1983-10-31

    申请人： Walter Kaminsky ,  Heinrich Hahnsen

    发明人： Walter Kaminsky ,  Heinrich Hahnsen

    IPC分类号： C08F4/00 ,  C07F5/06 ,  C08F4/12 ,  C08F4/60 ,  C08F4/6192 ,  C08F10/00 ,  C08G79/10 ,  C08L67/06

    CPC分类号： C08G79/10 ,  C07F5/068 ,  C08F10/00

    摘要： The present invention relates to a process for the preparation of oligomeric alkylaluminoxanes of the general formulae: ##STR1## in which R=C.sub.1 -C.sub.6 -alkyl, preferably methyl, and n=2-40, preferably 10-20, by reacting aluminum salts containing water of crystallization, preferably aluminum sulfate containing water of crystallization, with an aluminum trialkyl, preferably aluminum trimethyl. Aluminoxanes of this type can be used as a catalyst component in the preparation of high-activity, homogeneous Ziegler catalysts.

    摘要翻译： 本发明涉及制备下列通式的低聚烷基铝氧烷的方法：其中R = C1-C6-烷基，优选甲基，n = 2-40，优选为10-20 通过使含有结晶水的铝盐，优选含有结晶水的硫酸铝与三烷基铝，优选三甲基铝反应。 这种类型的氧化铝可用作制备高活性齐齐齐格勒催化剂的催化剂组分。