公开(公告)号：US08466231B2

公开(公告)日：2013-06-18

申请号：US12420108

申请日：2009-04-08

申请人： Michael C. Dadalas ,  Klaus Hintzer ,  Ludwig Mayer ,  Tilman C. Zipplies ,  James Arthur McDonell

发明人： Michael C. Dadalas ,  Klaus Hintzer ,  Ludwig Mayer ,  Tilman C. Zipplies ,  James Arthur McDonell

IPC分类号： C08F2/16 ,  C08F14/18 ,  C08G18/22

CPC分类号： F16C17/12 ,  C02F1/42 ,  C02F2101/14 ,  C02F2209/06 ,  C08F6/16 ,  C08F6/22 ,  C08F14/18 ,  Y10T428/3154 ,  C08L27/12 ,  C08F2/24

摘要： A process of reducing the amount of fluorinated emulsifiers in fluoropolymer dispersions by contacting the fluoropolymer dispersion with an anion exchange resin in the presence of a pH-dependent surfactant, and fluoropolymer dispersion containing the pH-dependent surfactant and uses thereof.

摘要翻译： 通过在pH依赖性表面活性剂的存在下使含氟聚合物分散体与阴离子交换树脂接触，以及含有pH依赖性表面活性剂的含氟聚合物分散体及其用途，来降低含氟聚合物分散体中的氟化乳化剂的量的方法。

公开(公告)号：US07462667B2

公开(公告)日：2008-12-09

申请号：US11172345

申请日：2005-06-30

申请人： Michael C. Dadalas ,  Klaus Hintzer ,  Gernot Loehr ,  Tilman Zipplies

发明人： Michael C. Dadalas ,  Klaus Hintzer ,  Gernot Loehr ,  Tilman Zipplies

IPC分类号： C08L37/12

CPC分类号： C09D179/08 ,  C08L27/08 ,  C09D5/002 ,  C09D177/00 ,  C09D179/04 ,  C09D181/06 ,  Y10T428/3154 ,  C08L2666/14 ,  C08L2666/04

摘要： The present invention provides an aqueous coating composition comprising (i) particles of a non-melt processible polymer of tetrafluoroethylene and (ii) a non-fluorinated polymer selected from the group consisting of a polysulfone, a polyamide, a polyimide, a polyamide-imide, a polybismaleimide and mixtures thereof, wherein said particles are core-shell particles whereby the shell comprises a copolymer of tetrafluoroethylene and a partially fluorinated or non-fluorinated comonomer. The aqueous coating composition may be used for providing a primer coating on a substrate such as a metal or glass substrate. Such primer coating may provide good or excellent non-stick coatings combined with good or excellent scratch and wear resistance of the coating. Also, such primer coating may provide for good to excellent PTFE coatings that can resist hot salt water. The aqueous coating composition may also be used to provide other coating layers of a multi-layer coating.

摘要翻译： 本发明提供一种水性涂料组合物，其包含（i）四氟乙烯的不可熔融加成聚合物的颗粒和（ii）选自聚砜，聚酰胺，聚酰亚胺，聚酰胺 - 酰亚胺的非氟化聚合物 ，多双马来酰亚胺及其混合物，其中所述颗粒是核 - 壳颗粒，其中壳包含四氟乙烯和部分氟化或非氟化共聚单体的共聚物。 水性涂​​料组合物可以用于在诸如金属或玻璃基材的基材上提供底漆涂层。 这种底漆涂层可以提供良好或优异的不粘涂层，同时具有涂层的良好或优异的耐擦伤性和耐磨性。 此外，这种底漆涂层可以提供可耐受热盐水的良好至优异的PTFE涂层。 水性涂​​料组合物也可用于提供多层涂层的其它涂层。

公开(公告)号：US20080264864A1

公开(公告)日：2008-10-30

申请号：US11741289

申请日：2007-04-27

申请人： Michael C. Dadalas ,  Klaus Hintzer ,  Ludwig Mayer ,  Tilman C. Zipplies ,  James Arthur McDonell

发明人： Michael C. Dadalas ,  Klaus Hintzer ,  Ludwig Mayer ,  Tilman C. Zipplies ,  James Arthur McDonell

IPC分类号： C02F1/28 ,  C08F2/16

CPC分类号： F16C17/12 ,  C02F1/42 ,  C02F2101/14 ,  C02F2209/06 ,  C08F6/16 ,  C08F6/22 ,  C08F14/18 ,  Y10T428/3154 ,  C08L27/12 ,  C08F2/24

摘要： A process of reducing the amount of fluorinated emulsifiers in fluoropolymer dispersions by contacting the fluoropolymer dispersion with an anion exchange resin in the presence of a pH-dependent surfactant, and fluoropolymer dispersions containing the pH-dependent surfactant and uses thereof.

摘要翻译： 通过在pH依赖性表面活性剂的存在下使含氟聚合物分散体与阴离子交换树脂接触，以及含有pH依赖性表面活性剂的含氟聚合物分散体及其用途，来降低含氟聚合物分散体中氟化乳化剂的量的方法。

公开(公告)号：US07342066B2

公开(公告)日：2008-03-11

申请号：US10957898

申请日：2004-10-04

申请人： Michael C. Dadalas ,  Klaus Hintzer ,  Gernot Loehr ,  Tilman Zipplies

发明人： Michael C. Dadalas ,  Klaus Hintzer ,  Gernot Loehr ,  Tilman Zipplies

IPC分类号： C08L27/12

CPC分类号： C09D127/18 ,  C08L2666/28

摘要： The present invention provides an aqueous non-melt processible polytetrafluoroethylene dispersion comprising non-melt processible polytetrafluoroethylene particles in an amount between 30 and 70% by weight based on the total weight of the dispersion and one or more non-ionic surfactants and wherein at least a part of said non-melt processible polytetrafluoroethylene particles comprise polytetrafluoroethylene polymer chains having repeating units comprising ionic groups. The invention further provides a method for obtaining the dispersions.

摘要翻译： 本发明提供了一种含水不可熔融加工的聚四氟乙烯分散体，其包含基于分散体和一种或多种非离子表面活性剂的总重量为30-70重量％的不可熔融加工的聚四氟乙烯颗粒，并且其中至少一个 所述不可熔融加工的聚四氟乙烯颗粒的一部分包括具有包含离子基团的重复单元的聚四氟乙烯聚合物链。 本发明还提供了获得分散体的方法。

公开(公告)号：US08614265B2

公开(公告)日：2013-12-24

申请号：US13494260

申请日：2012-06-12

申请人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C. Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

发明人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C. Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

IPC分类号： C08L1/00

CPC分类号： C08L27/12 ,  C08L71/02 ,  Y02C20/30 ,  C08L2666/22

摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+  (I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear fully fluorinated aliphatic group or a linear fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.

摘要翻译： 首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示 线性全氟化亚烷基，Rf表示直链全氟化脂族基团或被一个氧原子间隔的直链全氟化脂肪族基团，Xi +表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于 分散体的总重量，同时保持或增加分散体中固体的量。

公开(公告)号：US08598267B2

公开(公告)日：2013-12-03

申请号：US11851431

申请日：2007-09-07

申请人： Michael C. Dadalas ,  Rebekka Epsch ,  Friedrich Kloos ,  Leonard W. Harvey

发明人： Michael C. Dadalas ,  Rebekka Epsch ,  Friedrich Kloos ,  Leonard W. Harvey

IPC分类号： C08L27/12

CPC分类号： C09D127/12 ,  C08K5/42

摘要： The present invention provides a fluoropolymer dispersion comprising fluoropolymer particles having an average particle size of 10 to 400 nm dispersed in water whereby the dispersion is free of fluorinated surfactant having a molecular weight of less than 1000 g/mol or contains the fluorinated surfactant having a molecular weight of less than 1000 g/mol in an amount of not more than 0.025% by weight based on the total weight of solids in the dispersion. The dispersion further comprises a non-ionic surfactant and an anionic surfactant selected from fluorinated anionic surfactants having a molecular weight of at least 1000 g/mol, non-fluorinated anionic surfactants and mixtures thereof.

摘要翻译： 本发明提供一种氟聚合物分散体，其含有平均粒径为10〜400nm的含氟聚合物颗粒，其分散在水中，由此该分散体不含分子量小于1000g / mol的氟化表面活性剂，或含有具有分子量 重量小于1000g / mol，其量不得大于0.025％（重量），基于分散体中固体的总重量。 分散体还包含非离子表面活性剂和选自分子量至少为1000g / mol的氟化阴离子表面活性剂，非氟化阴离子表面活性剂及其混合物的阴离子表面活性剂。

公开(公告)号：US20120252949A1

公开(公告)日：2012-10-04

申请号：US13494260

申请日：2012-06-12

申请人： Klaus Hintzer ,  Michael JÜRGENS ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C. Dadalas ,  George G.I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

发明人： Klaus Hintzer ,  Michael JÜRGENS ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C. Dadalas ,  George G.I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

IPC分类号： C08L27/18 ,  C08K5/095

CPC分类号： C08L27/12 ,  C08L71/02 ,  Y02C20/30 ,  C08L2666/22

摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+  (I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear fully fluorinated aliphatic group or a linear fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.

摘要翻译： 首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示 线性全氟化亚烷基，Rf表示直链全氟化脂族基团或被一个氧原子间隔的直链全氟化脂肪族基团，Xi +表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于 分散体的总重量，同时保持或增加分散体中固体的量。

公开(公告)号：US07041728B2

公开(公告)日：2006-05-09

申请号：US10962633

申请日：2004-10-12

申请人： Tilman Zipplies ,  Klaus Hintzer ,  Michael C. Dadalas ,  Gernot Loehr

发明人： Tilman Zipplies ,  Klaus Hintzer ,  Michael C. Dadalas ,  Gernot Loehr

IPC分类号： C08L27/12 ,  D06M15/277

CPC分类号： C09D127/18 ,  C08F6/16 ,  C08F214/26 ,  C08L27/18 ,  C08L71/02 ,  C08L2666/02 ,  C08L2666/22

摘要： The present invention provides a method of making an aqueous dispersion of non-melt processible polytetrafluoroethylene, the method comprising:(a) an aqueous emulsion polymerization of an amount of tetrafluoroethylene to produce a final amount of polytetrafluoroethylene solids and optionally up to 1% by weight based on the amount of tetrafluoroethylene of a perfluorinated comonomer, wherein said aqueous emulsion polymerization is initiated with a free radical initiator and the polymerization is carried out in the presence of a fluorinated surfactant, and wherein before completing the feeding of said amount of tetrafluoroethylene but after feeding at least 80% by weight of said amount of tetrafluoroethylene, free radicals capable of introducing ionic end groups or precursors thereof in the polytetrafluoroethylene polymer are caused to be formed at a rate that without counter measures would cause an increase in the polymerization rate of at least 20%;(b) reducing the amount of fluorinated surfactant in the thus obtained aqueous dispersion to an amount of not more than 200 ppm, preferably not more than 100 ppm and more preferably not more than 50 ppm based on the amount of polytetrafluoroethylene solids. The invention further provides an aqueous dispersion of polytetrafluoroethylene particles and the use thereof in coating a substrate.

摘要翻译： 本发明提供了一种制备不熔融可加工聚四氟乙烯的水性分散体的方法，该方法包括：（a）一定量的四氟乙烯的水乳液聚合以产生最终量的聚四氟乙烯固体，并且任选地高达1重量％ 基于全氟化共聚单体的四氟乙烯的量，其中所述水性乳液聚合由自由基引发剂引发，并且聚合在氟化表面活性剂的存在下进行，并且其中在完成所述量的四氟乙烯之前但在 加入至少80重量％的所述量的四氟乙烯，使得能够在聚四氟乙烯聚合物中引入离子端基或其前体的自由基以不加对策的方式形成，导致聚四氟乙烯聚合速率的升高 至少20％; （b）将由此得到的水性分散体中的氟化表面活性剂的量减少到基于聚四氟乙烯固体量不超过200ppm，优选不超过100ppm，更优选不大于50ppm的量。 本发明还提供聚四氟乙烯颗粒的水分散体及其在涂布基材中的用途。

公开(公告)号：US07678859B2

公开(公告)日：2010-03-16

申请号：US11531745

申请日：2006-09-14

申请人： Peter Bissinger ,  Michael C. Dadalas ,  Klaus Hintzer ,  Ludwig Mayer ,  Werner Schwertfeger ,  Tilman C. Zipplies

发明人： Peter Bissinger ,  Michael C. Dadalas ,  Klaus Hintzer ,  Ludwig Mayer ,  Werner Schwertfeger ,  Tilman C. Zipplies

IPC分类号： C08L27/12

CPC分类号： C08F14/18 ,  C08F2/24 ,  C08F2/22

摘要： Provided is a method comprising polymerizing at least one fluorinated monomer in an aqueous emulsion polymerization in the presence of a carbosilane surfactant having at least one hydrophobic part, wherein the hydrophobic part has at least one silicon atom, and having at least one hydrophilic part, with the proviso that the carbosilane contains no Si—O bonds.

摘要翻译： 提供了一种方法，其包括在具有至少一个疏水部分的碳硅烷表面活性剂的存在下，在水性乳液聚合中聚合至少一种氟化单体，其中所述疏水部分具有至少一个硅原子，并且具有至少一个亲水部分， 条件是碳硅烷不含Si-O键。

公开(公告)号：US08222322B2

公开(公告)日：2012-07-17

申请号：US12684239

申请日：2010-01-08

申请人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

发明人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

IPC分类号： C08L1/00

CPC分类号： C08L27/12 ,  C08L71/02 ,  Y02C20/30 ,  C08L2666/22

摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+  (I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.

摘要翻译： 首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示 线性全氟化亚烷基，Rf表示直链部分或完全氟化的脂族基团或被一个氧原子间隔的直链部分或全氟化的脂族基团，X i +表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于 分散体的总重量，同时保持或增加分散体中固体的量。