摘要:
The invention provides a process for the fine division of pigments which comprises dissolving coarsely crystalline crude pigments in a solvent and precipitating them with a liquid precipitation medium by spraying the pigment solution and the precipitation medium through nozzles to a point of conjoint collision in a reactor chamber enclosed by a housing in a microjet reactor, a gas or an evaporating liquid being passed into the reactor chamber through an opening in the housing for the purpose of maintaining a gas atmosphere in the reactor chamber, and the resulting pigment suspension and the gas or the evaporated liquid being removed from the reactor through a further opening in the housing by means of overpressure on the gas entry side or underpressure on the product and gas exit side.
摘要:
The invention relates to novel quinacridone mixed crystal pigments consisting of a) from 82.5 to 99% by weight of unsubstituted &ggr;-phase quinacridone of the formula (I) in which R1 and R2 are hydrogen atoms and b) from 1 to 17.5% by weight of one or more 2,9- and/or 3,10-substituted quinacridones of the formula (I) in which the substituents R1 and R2 are identical or different and are chlorine, bromine or fluorine atoms or C1-C4-alkyl, C1-C4-alkoxy or carboxamido groups which can be substituted by C1-C6-alkyl groups, and R1 can additionally be a hydrogen atom, and to pigment preparations comprising said quinacridone mixed crystal pigments.
摘要:
Water-soluble perylene dyestuffs, their preparation and their useThe present Application relates to water-soluble perylene dyestuffs of the formula ##STR1## in which R.sup.1 and R.sup.2 independently of one another are the radicals A--X--COOM or A--X--SO.sub.3 M;R.sup.3 and R.sup.4 independently of one another are the radicals R.sup.1 or R.sup.2, or are OR.sup.5 or NR.sup.6 R.sup.7 ;A is NR.sup.8 or S;X is a straight-chain or branched alkylene radical, a straight-chain or branched alkylene radical which is substituted by hydroxyl, carboxyl or amino, an arylene radical or an arylene radical which is optionally substituted by hydroxyl, carboxyl or sulfo;R.sup.5, R.sup.6 and R.sup.7 independently of one another are hydrogen, (C.sub.1 -C.sub.4)-alkyl or (C.sub.1 -C.sub.4)-alkyl which is substitituted by one or more hydroxyl, 2-hydroxyethoxy, (C.sub.1 -C.sub.4)-alkoxy or amino groups;R.sup.8 is hydrogen, methyl or ethyl andM is a monovalent cation or one equivalent of a polyvalent cation,processes for their preparation, their use for dyeing and printing naturally occurring and synthetic fiber materials, and recording liquids, in particular for the ink-jet process, and liquid formulations for dyeing paper in the pulp which comprise the dyestuffs according to the invention.
摘要:
Process for preparing linear unsubstituted .beta.-phase quinacridone pigments A process for preparing linear unsubstituted .beta.-phase quinacridone pigments or pigment preparations, which comprises a) cyclizing 2,5-dianilinoterephthalic acid in polyphosphoric acid or polyphosphoric ester with a phosphorus pentoxide content of at least 84% by weight to form the quinacridone, b) subsequently hydrolyzing this quinacridone with water or with an aqueous mineral acid solution, preferably orthophosphoric acid solution, at a temperature of at least 40.degree. C., preferably from 60.degree. to 105.degree. C., to form the crude quinacridone pigment which is predominantly in the .alpha.-phase, c) then heating the crude .alpha.-phase quinacridone pigment to a temperature between 120.degree. and 200.degree. C. in the presence of a from 0.1 to 3% strength by weight, preferably from 0.2 to 2% strength by weight, inorganic base in water and alkali-stable organic solvents, for the change of phase into coarsely crystalline crude .beta.-phase pigment, and d) subjecting the coarsely crystalline crude .beta.-phase quinacridone pigment, for the fine division to form a pigment or prepigment, to dry or wet milling; and then isolating the resulting finely divided .beta.-phase pigment; e) or subjecting the finely divided .beta.-phase prepigment obtained in d) to a finish treatment in the presence of solvents, and then isolating the pigment.
摘要:
The use of sulfuric monoesters of the formulae (I) and (II) R.sup.1 --O--(CH.sub.2 O).sub.n --SO.sub.3 .sup.- M.sup.+ (I) R.sup.1 --CO--NR.sup.2 --(CH.sub.2 O)(.sub.n+1)--SO.sub.3 .sup.- M.sup.+ (II) in which R.sup.1 is a straight-chain or branched alkyl group of 10 to 24 carbon atoms, R.sup.2 is a hydrogen atom or a C.sub.1 -C.sub.6 -alkyl group, M.sup.+ is a hydrogen ion, an alkali metal ion, 1/2 an alkaline earth metal ion, or an ammonium ion of the formula N.sup.+ R.sup.3 R.sup.4 R.sup.5 R.sup.6, where the substituents R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another are each hydrogen atoms or C.sub.1 -C.sub.6 -alkyl groups, which alkyl groups can be substituted by 1 to 3 hydroxyl groups, and n is a number from 0 to 4; or of a mixture of at least two sulfuric monoesters of the formulae (I) and/or (II), for preparing surface-treated pigments from the classes of the quinacridones and dioxazines.
摘要:
The deliveries to the printing ink industry of pigment preparations in the form of flushed pastes increasingly take the form of containers. Given the required high pigment content of the pastes and the attendant high viscosity and thixotropy, there are very frequent problems with filling the containers and complaints concerning the emptying of the containers. There is a demand for a homogeneous, pumpable pigment paste having a long shelf life. According to the invention, this demand is met in the case of pigments based on arylpararosanillnesulfonic acids by the use of specific aids of the type of the condensation products of aliphatic amines or ammonium compounds with polyesters of hydroxy fatty acids as part of the flushing process of the pigment using the customary or slightly modified binder systems which for the same pigment contents bring about a distinctly lower viscosity and thixotropy. The printing properties are not adversely affected.
摘要:
The invention provides a process for preparing azo colorants which comprises spraying one or more coupling components individually or in a mixture and one or more compatible diazonium salts individually or in a mixture, in their solution or suspension form through nozzles to a point of conjoint collision in a reactor chamber enclosed by a housing in a microjet reactor, a gas or an evaporating liquid being passed into the reactor chamber through an opening in the housing for the purpose of maintaining a gas atmosphere in the reactor chamber, and the resulting product solution or suspension and the gas or the evaporated liquid being removed from the reactor through a further opening in the housing by means of overpressure on the gas entry side or underpressure on the product and gas exit side.
摘要:
The use of mixed-crystal pigments of the quinacridone series consisting of a) from 85 to 99% by weight of unsubstituted &bgr;-phase quinacridone of the formula (I) in which R1 and R2 are hydrogen atoms, and b) from 1 to 15% by weight of one or more substituted quinacridones of the formula (I) in which the substituents R1 and R2 are identical or different and are chlorine, bromine or fluorine atoms or C1-C4-alkyl, C1-C4-alkoxy or carboxamido groups, which can be substituted by C1-C6-alkyl groups, and R1 can additionally be hydrogen, as colorants in electrophotographic toners and developers, powder coating materials, inkjet inks, electret fibers, and color filters.
摘要:
Process for the preparation of pigment preparations, which comprises wet milling the crude pigments which are present in coarsely crystalline state, or prepigments or pigments which are present in a form in which they are difficult to disperse, in a concentration of from 20 to 60% by weight based on the total weight of the pigment preparation, in a flocculation-stable liquid medium and in a stirred ball mill which is operated with a peripheral stirrer speed of more than 12 m/s, under the action of nonmetallic grinding media with a diameter of less than or equal to 1.0 mm, until the desired degree of fine division is reached, and then isolating the pigment preparation.
摘要:
The invention relates to mixtures of nitrogen-containing surface-active agents which are obtained by esterification of oxyalkylates based on modified or nonmodified naturally occurring resin acids or resin amines or resin alcohols derived therefrom with dicarboxylic acids or anhydrides thereof and subsequent reaction with alkylenediamines or alkylenepolyamines. These nitrogen-containing surface-active agents are suitable as coupling auxiliaries, emulsifiers, dispersing agents, preparation agents for solids dispersions, corrosion protection and metal-working agents and as wetting agents and dyeing auxiliaries.