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公开(公告)号:US08772426B2
公开(公告)日:2014-07-08
申请号:US13519666
申请日:2011-01-18
IPC分类号: C08F210/16 , C08F2/12 , C08F4/6592 , C08F2/44
CPC分类号: C08F210/16 , C08F210/14 , C08F4/6592 , C08F2500/12 , C08F2500/17
摘要: Copolymers of ethylene and α-olefins having (a) a density (D) in the range 0.900-0.940 g/cm3, (b) a melt index MI2 (2.16 kg, 190° C.) in the range of 0.01-50 g/10 min, (c) a melt index MI2 (2.16 kg, 190° C.) and Dow Rheology Index (DRI) satisfying the equation [DRI/MI2]>2.65, and (d) a Dart Drop Impact (DDI) in g of a blown film having a thickness of 25 μm produced from the copolymer satisfying the equation DDI≧1900×{1−Exp [−750(D−0.908)2]}×{Exp [(0.919−D)/0.0045]}. The copolymers may be prepared using metallocene catalysis and are preferably prepared in multistage processes carried out in loop reactors in the slurry phase. The copolymers exhibit long chain branching as defined by Dow Rheology Index (DRI) and exhibit unexpected improvements in mechanical properties, in particular dart drop impact, when extruded into blown films.
摘要翻译: (a)密度(D)在0.900-0.940g / cm3范围内的乙烯和α-烯烃的共聚物,(b)在0.01-50g范围内的熔体指数MI2(2.16kg,190℃) /分钟,(c)满足方程[DRI / MI2]> 2.65的熔体指数MI2(2.16kg,190℃)和Dow流变指数(DRI),和(d)Dart Drop Impact g满足DDI≥10000×{1-Exp [-750(D-0.908)2]}×{Exp [(0.919-D)/0.0045]}的共聚物制成的厚度为25μm的吹塑薄膜 。 共聚物可以使用茂金属催化制备,并且优选以在淤浆相中的环管反应器中进行的多步法制备。 共聚物表现出由Dow Rheology Index(DRI)定义的长链支化,并且当挤出成吹塑薄膜时,其机械性能特别是飞镖降落冲击表现出意想不到的改进。
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公开(公告)号:US07897710B2
公开(公告)日:2011-03-01
申请号:US11660355
申请日:2005-08-12
IPC分类号: C08F10/02
CPC分类号: C08J3/247 , C08F210/16 , C08J5/18 , C08J2323/04 , C08L23/04 , C08L2205/02 , Y10T428/24975 , C08L2666/06 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F2500/07 , C08F2500/26 , C08F2/001 , C08F4/6555
摘要: Film formed from a polyethylene resin composition which obeys a dynamic rheological relationship at 190° C. between melt storage modulus G′, measured in Pa and at a dynamic frequency where the loss modulus G″=3000 Pa, and dynamic complex viscosity η*100, measured in Pa·s at 100 rad/s, such that (a) G′(G″=3000)>−0.86η*100+z where z=3800, and at the same time (b) G′(G″=3000)>0.875η*100−y where y=650, and having an impact strength (DDT) of at least 250 g, measured on 15 μm thick film (blown under conditions with BUR=5:1 and Neck Height=8×D) conditioned for 48 hours at 20°-25° C., according to ASTM D1709.
摘要翻译: 由聚乙烯树脂组合物形成的膜,其在190℃下遵循动态流变学关系,熔体储存模量G'(以Pa测量)和损耗模量G“= 3000Pa的动态频率和动态复数粘度* 100,以100rad / s的Pa·s测量,使得(a)G'(G“= 3000)> - 0.86&eegr; * 100 + z其中z = 3800,同时(b)G' (G“= 3000)> 0.875&egr; * 100-y,其中y = 650,并且在15μm厚的膜上测量具有至少250g的冲击强度(DDT)(在BUR = 5:1的条件下吹制; 颈部高度= 8×D)根据ASTM D1709在20°-25℃条件下调节48小时。
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公开(公告)号:US06642339B1
公开(公告)日:2003-11-04
申请号:US09695915
申请日:2000-10-26
IPC分类号: C08F21002
CPC分类号: C08J5/18 , C08F4/65908 , C08F4/65916 , C08F210/16 , C08F2410/02 , C08J2323/08 , C08L23/0815 , C08L23/0853 , C08L2314/06 , Y10S526/943 , C08F4/6592 , C08L2666/04 , C08F210/14 , C08F2500/03 , C08F2500/12 , C08F2500/20 , C08F2500/09 , C08F2500/26
摘要: Copolymers of ethylene and alpha olefins having from 3 to 10 carbon atoms and which have (a) a density in the range 0.900 to 0.940 (b) an apparent Mw/Mn of 2-3.4 (c) I21/I2 from 16 to 21.5 (d) activation energy of flow from 28 to 45 kJ/mol (e) a ratio Ea(HMW)/Ea(LMW)>1.1, and (f) a ratio g′(HMW/g′(LMW) from 0.85 to 0.95. The copolymers are particularly useful in film applications showing an excellent balance of processing, optical and mechanical properties. The novel polymers may suitably be prepared in the gas phase in the presence of metallocene complexes.
摘要翻译: 具有3至10个碳原子且具有(a)密度在0.900至0.940(b)中的乙烯和α-烯烃的共聚物(b)表观Mw / Mn为2-3.4(c)I21 / I2从16至21.5( d)流动的活化能为28至45kJ / mol(e)比值Ea(HMW)/ Ea(LMW)> 1.1,和(f)比例g'(HMW / g'(LMW)为0.85至0.95 该共聚物特别适用于显示加工,光学和机械性能优异平衡的膜应用中。新型聚合物可适当地在金属茂配合物存在下在气相中制备。
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公开(公告)号:US07956129B2
公开(公告)日:2011-06-07
申请号:US10567927
申请日:2004-08-12
申请人: Choon Kooi Chai
发明人: Choon Kooi Chai
CPC分类号: C09D123/0815 , C08L23/06 , C08L2205/02 , C08L2666/06
摘要: Novel polymer blends comprise (a) 1-99% by weight of a copolymer of ethylene and an alpha olefin having from 3 to 10 carbon atoms, said copolymer having (iv) a density in the range 0.905 to 0.940 g cm−3, (v) a melt elastic modulus G′ (G″=500 Pa) in the range 10 to 150 Pa, and (vi) a melt index in the range 5 to 50, and (b) from 1-99% by weight of a low density polyethylene (LDPE) polymer having a density from 0.914 to 0.928 g cm−3 wherein the sum of (a) and (b) is 100%. The copolymers of component (a) are typically prepared by use of metallocene catalysts. The blends exhibit advantageous melt elastic modulus in the range 30 to 200 Pa. The blends are particularly suitable for extrusion coating applications.
摘要翻译: 新型聚合物共混物包含(a)1-99重量%的乙烯和具有3至10个碳原子的α-烯烃的共聚物,所述共聚物具有(iv)密度在0.905至0.940g cm -3的密度, v)10〜150Pa范围内的熔体弹性模量G'(G“= 500Pa),(vi)5〜50的熔体指数,(b)1-99重量% 密度为0.914〜0.928gcm-3的低密度聚乙烯(LDPE)聚合物,其中(a)和(b)的总和为100%。 组分(a)的共聚物通常通过使用茂金属催化剂制备。 共混物在30至200Pa的范围内显示出有利的熔体弹性模量。共混物特别适用于挤出涂布应用。
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公开(公告)号:US20110086191A1
公开(公告)日:2011-04-14
申请号:US12736926
申请日:2009-06-04
申请人: Choon Kooi Chai , Dominique Jan
发明人: Choon Kooi Chai , Dominique Jan
IPC分类号: F16L9/12 , C08F210/16 , C08F4/76
CPC分类号: C08F210/16 , C08F4/65916 , C08F4/6592 , C08F2410/02 , F16L9/127 , Y10T428/139 , C08F4/65912 , C08F4/65908 , C08F210/14 , C08F2500/12 , C08F2500/19 , C08F2500/17
摘要: Novel copolymers are described comprising ethylene and alpha-olefins having (a) a density (D) in the range 930-960/g/m3 (b) a melt index (MI2) in the range 0.1-3.5 g/10 min (c) a melt elastic modulus G′ (G″=500 Pa) in the range 40 to 150 Pa, and (d) a ratio of complex dynamic shear viscosities η*(0.1)/η*(100) in the range 1.5 to 5.5. The novel copolymers are particularly suitable for use as Polyethylenes of Raised Temperature Resistance (PE-RT) for use in hot water piping systems. The novel copolymers may be prepared by use of meltallocene catalyst systems. Pipes having a time to failure of ≧500 hrs measured according to ISO 1167 at 110° C. and 2.6 MPa prepared in a single reactor are also disclosed.
摘要翻译: 描述了包含乙烯和α-烯烃的新型共聚物,其具有(a)密度(D)在930-960 / g / m 3范围内(b)0.1-3.5g / 10min范围内的熔体指数(MI2)(c )在40至150Pa的范围内的熔体弹性模量G'(G“= 500Pa),和(d)复合动态剪切粘度和*(0.1)/ eegr * *(100)的比率在1.5 至5.5。 新型共聚物特别适用于热水管道系统中用作耐高温聚乙烯(PE-RT)。 新型共聚物可以通过使用茂金属催化剂体系来制备。 还公开了在单个反应器中制备的根据ISO 1167在110℃和2.6MPa下测量的具有≥500小时的故障时间的管道。
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公开(公告)号:US06518385B1
公开(公告)日:2003-02-11
申请号:US09600107
申请日:2000-07-06
申请人: Choon Kooi Chai
发明人: Choon Kooi Chai
IPC分类号: C08F1014
CPC分类号: C08J5/18 , C08F4/65908 , C08F4/65916 , C08F4/65927 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08J2323/04 , C08F2500/12 , C08F2500/20 , C08F2500/11 , C08F2500/26 , C08F2500/09 , C08F210/14
摘要: Ethylene homopolymers and copolymers having a broad molecular distribution, excellent toughness and improved processability. These polymers may be prepared by use of a single metallocene catalyst system in a single reactor in the gas phase. These polymers of density typically 0.85-0.95 are defined in particular by their melt strength (MS) and long chain branching (LCB) characteristics and are particularly suitable for use in low density film applications.
摘要翻译: 乙烯均聚物和共聚物具有广泛的分子分布,优异的韧性和改进的加工性能。 这些聚合物可以通过在气相中的单个反应器中使用单一茂金属催化剂体系来制备。 这些密度通常为0.85-0.95的聚合物特别是通过其熔体强度(MS)和长链支化(LCB)特性来定义,并且特别适用于低密度膜应用。
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公开(公告)号:US20120289665A1
公开(公告)日:2012-11-15
申请号:US13519666
申请日:2011-01-18
IPC分类号: C08F210/14 , C08F2/01 , C08F4/76
CPC分类号: C08F210/16 , C08F210/14 , C08F4/6592 , C08F2500/12 , C08F2500/17
摘要: Copolymers of ethylene and α-olefins are provided having (a) a density (D) in the range 0.900-0.940 g/cm3, (b) a melt index MI2 (2.16 kg, 190° C.) in the range of 0.01-50 g/10 min, (c) a melt index MI2 (2.16 kg, 190° C.) and Dow Rheology Index (DRI) satisfying the equation [DRI/MI2]>2.65, and (d) a Dart Drop Impact (DDI) in g of a blown film having a thickness of 25 μm produced from the copolymer satisfying the equation DDI≧1900×{1−Exp[−750(D−0.908)2]}×{Exp[(0.919−D)/0.0045]}. The copolymers may suitably be prepared by use of metallocene catalysis and are preferably prepared in multistage processes earned out in loop reactors in the slurry phase. The copolymers exhibit long chain branching as defined by Dow Rheology Index (DRI) and exhibit unexpected improvements in mechanical properties, in particular dart drop impact, when extruded into blown films.
摘要翻译: 提供乙烯和α-烯烃的共聚物,其具有(a)密度(D)在0.900-0.940g / cm3范围内,(b)熔体指数MI2(2.16kg,190℃)在0.01- 50g / 10min,(c)满足方程[DRI / MI2]> 2.65的熔体指数MI2(2.16kg,190℃)和Dow流变学指数(DRI),和(d)Dart Drop Impact )满足式DDI≥10000×{1-Exp [-750(D-0.908)2]}×{Exp [(0.919-D)/0.0045)的共聚物的厚度为25μm的吹塑薄膜 ]}。 共聚物可以适当地通过使用茂金属催化制备,并且优选以在淤浆相中的环管反应器中获得的多阶段方法制备。 共聚物表现出由Dow Rheology Index(DRI)定义的长链支化,并且当挤出成吹塑薄膜时,其机械性能特别是飞镖降落冲击表现出意想不到的改进。
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公开(公告)号:US20080249262A1
公开(公告)日:2008-10-09
申请号:US11883162
申请日:2006-01-27
申请人: Choon Kooi Chai
发明人: Choon Kooi Chai
CPC分类号: C08F210/16 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/20 , C08F2500/09 , C08F2500/26
摘要: Copolymers of ethylene and alpha-olefins having (a) a density in the range 0.900-0.940 g/cm3, (b) a molecular weight distribution (Mw/Mn) in the range 3.5 to 4.5, (c) a melt elastic modulus G′ (G″=500 Pa) in the range 40 to 150 Pa and (d) an activation energy of flow (Ea) in the range 28-45 kJ/mol. are suitably prepared in the gas phase by use of a supported metallocene catalyst system. The novel copolymers show improved processability and are particular suitable for use in blown film applications.
摘要翻译: (a)密度在0.900-0.940g / cm 3范围内的乙烯和α-烯烃的共聚物,(b)3.5至4.5的分子量分布(Mw / Mn) (c)在40至150Pa的范围内的熔体弹性模量G'(G“= 500Pa)和(d)流动活化能(Ea)在28-45kJ / mol的范围内。 通过使用负载型金属茂催化剂体系在气相中适当地制备。 新型共聚物显示出改进的加工性,特别适用于吹塑薄膜应用。
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公开(公告)号:US06919414B2
公开(公告)日:2005-07-19
申请号:US10647278
申请日:2003-08-26
IPC分类号: C08F2/34 , C08F4/02 , C08F4/64 , C08F4/646 , C08F4/659 , C08F210/16 , C08J5/18 , C08L23/08 , C08L23/14 , C08L101/00 , G06F7/72 , C08F4/42
CPC分类号: C08J5/18 , C08F4/65908 , C08F4/65916 , C08F210/16 , C08F2410/02 , C08J2323/08 , C08L23/0815 , C08L23/0853 , C08L2314/06 , Y10S526/943 , C08F4/6592 , C08L2666/04 , C08F210/14 , C08F2500/03 , C08F2500/12 , C08F2500/20 , C08F2500/09 , C08F2500/26
摘要: Novel copolymers comprise ethylene and alpha olefins having from 3 to 10 carbon atoms and which have (a) a density in the range 0.900 to 0.940 (b) Mw/Mn of 2-3.4 (c) I21/I2 from 16 to 24 (d) activation energy of flow from 28 to 45 kJ/mol (e) a ratio Ea(HMW)/Ea(LMW)>1.1, and (f) a ratio g′(HMW)/g′(LMW) from 0.85 to 0.95 The copolymers are particularly useful in film applications showing an excellent balance of processing, optical and mechanical properties. The novel polymers may suitably be prepared in the gas phase in the presence of metallocene complexes.
摘要翻译: 新型共聚物包含具有3至10个碳原子的乙烯和α-烯烃,并且其具有(a)0.900至0.940(b)的密度,Mw / Mn为2-3.4(c)I 21 (d)流动的活化能为28〜45kJ / mol(e)比例Ea(HMW)/ Ea(LMW)> 1.1,(f)a 比例g'(HMW)/ g'(LMW)从0.85至0.95。共聚物特别适用于显示加工,光学和机械性能优异平衡的膜应用中。 新型聚合物可以适当地在气相中在茂金属络合物的存在下制备。
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公开(公告)号:US09587055B2
公开(公告)日:2017-03-07
申请号:US12736926
申请日:2009-06-04
申请人: Choon Kooi Chai , Dominique Jan
发明人: Choon Kooi Chai , Dominique Jan
IPC分类号: F16L9/12 , C08F210/16 , C08F4/76 , F16L9/127 , C08F4/659 , C08F4/6592
CPC分类号: C08F210/16 , C08F4/65916 , C08F4/6592 , C08F2410/02 , F16L9/127 , Y10T428/139 , C08F4/65912 , C08F4/65908 , C08F210/14 , C08F2500/12 , C08F2500/19 , C08F2500/17
摘要: Copolymers comprising ethylene and alpha-olefins having (a) a density (D) in the range 930-960/g/m3 (b) a melt index (MI2) in the range 0.1-3.5 g/10 min (c) a melt elastic modulus G′ (G″=500 Pa) in the range 40 to 150 Pa, and (d) a ratio of complex dynamic shear viscosities η*(0.1)/η(100) in the range 1.5 to 5.5. The copolymers are suitable for use as Polyethylenes of Raised Temperature Resistance (PE-RT) for use in hot water piping systems. The copolymers may be prepared by use of meltallocene catalyst systems. Pipes having a time to failure of ≧500 hrs measured according to ISO 1167 at 110° C. and 2.6 MPa prepared in a single reactor are also disclosed.
摘要翻译: 包含乙烯和α-烯烃的共聚物具有(a)密度(D)在930-960 / g / m 3范围内(b)熔体指数(MI2)在0.1-3.5g / 10min的范围内(c)熔体 弹性模量G'(G“= 500Pa)在40〜150Pa的范围内,(d)复数动态剪切粘度η*(0.1)/η(100)在1.5〜5.5的范围内的比例。 该共聚物适用于热水管道系统中用作耐高温聚乙烯(PE-RT)。 共聚物可以通过使用茂金属催化剂体系来制备。 还公开了在单个反应器中制备的根据ISO 1167在110℃和2.6MPa下测量的具有≥500小时的故障时间的管道。
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