A method and an apparatus for performing synchronization by a first device in a Device-to-Device (D2D) network are provided. The method includes detecting a synchronization signal from at least one second device during one period, determining a phase adjustment value depending on a number of synchronization signals, which have been detected from the at least one second device during the one period, adjusting a phase value of a first device using the phase adjustment value, and transmitting a synchronization signal if the phase value of the first device reaches a predetermined specific value.