The invention provides a silicone resin composition for producing a silicone laminated substrate by being impregnated in a glass cloth and cured therein, comprising: (A) an organopolysiloxane with a 3-dimensional network structure composed of an R1SiO1.5 unit and an R2SiO1.5 unit and a T unit represented by an RSiO1.5 unit; (B) an organohydrogenpolysiloxane composed of an R1SiO1.5 unit, an R12SiO unit and an R1aHbSiO(4-a-b)/2 unit; (C) a platinum group metal catalyst; and (D) a filler. There can be a silicone resin composition having a high glass transition temperature, a silicone laminated substrate excellent in properties such as heat resistance and weatherability having low thermal expansion coefficient and suppressed warp and deformation, a method for producing the same and an LED device.