发明授权
- 专利标题: Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
- 专利标题(中): 结晶聚丙烯和部分结晶的低分子量冲击改性剂的抗冲击聚合物共混物
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申请号: US10289122申请日: 2002-11-05
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公开(公告)号: US06943215B2公开(公告)日: 2005-09-13
- 发明人: James C. Stevens , Daniel D. Vanderlende , Patricia Ansems
- 申请人: James C. Stevens , Daniel D. Vanderlende , Patricia Ansems
- 申请人地址: US MI Midland
- 专利权人: Dow Global Technologies Inc.
- 当前专利权人: Dow Global Technologies Inc.
- 当前专利权人地址: US MI Midland
- 代理机构: Whyte Hirschboeck Dudek SC
- 主分类号: B32B27/32
- IPC分类号: B32B27/32 ; C07F7/00 ; C08F4/659 ; C08F4/6592 ; C08F10/00 ; C08F110/06 ; C08F210/06 ; C08F210/16 ; C08J5/18 ; C08L23/02 ; C08L23/10 ; C08L23/12 ; C08L23/14 ; C08L23/16 ; C08L101/00 ; C09K3/10 ; D01F6/06 ; D01F6/30 ; D01F6/46 ; C08F8/00 ; C08L23/00 ; C08L23/04 ; C08L27/00
摘要:
Polymer blends that exhibit good impact resistance comprise a crystalline polypropylene matrix and a partly crystalline copolymer impact modifier with a molecular weight lower than that of the matrix polymer. The matrix polymer can comprise any crystalline propylene homo- or copolymer. The impact modifying copolymers are characterized as comprising at least about 60 weight percent (wt %) of units derived from propylene and, in certain embodiments, as having at least one, preferably two or more, of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
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