发明授权
- 专利标题: Method for oxidizing hydrocarbons
- 专利标题(中): 氧化烃的方法
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申请号: US10239215申请日: 2001-03-22
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公开(公告)号: US06852893B2公开(公告)日: 2005-02-08
- 发明人: Adolf Kühnle , Mark Duda , Carsten Jost , Guido Fries , Jochen Kirchhoff , Thomas Schiffer , Roger Arthur Sheldon , Sasidharan Manickam , Isabella W. C. E. Arends
- 申请人: Adolf Kühnle , Mark Duda , Carsten Jost , Guido Fries , Jochen Kirchhoff , Thomas Schiffer , Roger Arthur Sheldon , Sasidharan Manickam , Isabella W. C. E. Arends
- 申请人地址: DE Marl
- 专利权人: Creavis Gesellschaft fuer Technologie and Innovation mbH
- 当前专利权人: Creavis Gesellschaft fuer Technologie and Innovation mbH
- 当前专利权人地址: DE Marl
- 代理机构: Oblon, Spivak, McClelland, Maier & Neustadt, P.C.
- 优先权: DE10015880 20000330
- 国际申请: PCTEP01/03289 WO 20010322
- 国际公布: WO0174742 WO 20011011
- 主分类号: C07B41/00
- IPC分类号: C07B41/00 ; C07B61/00 ; C07C27/12 ; C07C29/50 ; C07C35/02 ; C07C35/20 ; C07C37/08 ; C07C45/28 ; C07C45/36 ; C07C47/54 ; C07C49/385 ; C07C49/78 ; C07C409/08 ; C07C409/10 ; C07C409/14 ; C07C45/00 ; C07C51/16 ; C07C309/00 ; C07D235/00
摘要:
The invention relates to a method for oxidizing substrates such as hydrocarbons, waxes or soot. The method involves the use of a compound of formula (I) in which: R1 and R2 represent H, an aliphatic or aromatic alkoxy radical, carboxyl radical, alkoxycarbonyl radical or hydrocarbon radical, each having 1 to 20 hydrocarbon atoms, SO3H, NH2, OH, F, Cl, Br, I and/or NO2, whereby R1 and R2 designate identical or different radicals or R1 and R2 can be linked to one another via a covalent bonding; Q1 and Q2 represent C, CH, N, CR5, each being the same or different; X and Z represent C, S, CH2, each being the same or different; Y represents O and OH; k=0, 1, 2; l=0, 1, 2; m=1 to 3, and; R5 represents one of the meanings of R1. Said compound is used as a catalyst in the presence of a radical initiator, whereby the molar ratio of the catalyst to the hydrocarbon is less than 10 mol %. Peroxy compounds or azo compounds can be used as the radical initiator. Preferred substrates are aliphatic or aromatic hydrocarbons.
公开/授权文献
- US20030176733A1 Method for oxidizing hydrocarbons 公开/授权日:2003-09-18
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