A thermal transfer receiving sheet having laminated, on one side of its support, an intermediate layer, a barrier layer and an image receiving layer in this order, wherein said intermediate layer comprises hollow particles, and said barrier layer comprises a polyvinyl alcohol derivative, and comprises, as further main components, a resin or a mixture of two or more resins selected from the group consisting of a styrene-maleic acid copolymer, a styrene-acrylic copolymer, an acrylic acid ester polymer and polyester, or wherein said barrier layer comprises, as main components, an ethylene vinyl alcohol copolymer and polyurethane.