- 专利标题: Acrolein scavenging in PTF and other 1,3-propanediol derived polymers
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申请号: US16347353申请日: 2017-11-03
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公开(公告)号: US11708454B2公开(公告)日: 2023-07-25
- 发明人: Robert M. Kriegel , Ronald D. Moffitt , Steven F. Sukits , Vidhu Nagpal, Jr. , Christopher R. Mubarak , Marlon Salvador Morales
- 申请人: THE COCA-COLA COMPANY
- 申请人地址: US GA Atlanta
- 专利权人: THE COCA-COLA COMPANY
- 当前专利权人: THE COCA-COLA COMPANY
- 当前专利权人地址: US GA Atlanta
- 代理机构: Eversheds Sutherland (US) LLP
- 国际申请: PCT/US2017/059877 2017.11.03
- 国际公布: WO2018/085628A 2018.05.11
- 进入国家日期: 2019-05-03
- 主分类号: C08G63/90
- IPC分类号: C08G63/90 ; C08G63/78 ; C08J5/18 ; C08K5/17 ; C08K5/20
摘要:
This disclosure provides a process for removing acrolein or allyl alcohol from a polyester composition, the process comprising: combining a polyester composition derived from 1,3-propanediol with an amino amide or a primary amine; wherein the amino amide or the primary amine is combined in sufficient quantities to scavenge acrolein or allyl alcohol produced from degradation of the polyester composition. An analysis of reactions between anthranilamide (AAA) and acrolein demonstrates how amines or amino amides can scavenge acrolein from thermally processed poly(trimethylene terephthalate) and poly(trimethylene furan-2,5-dicarboxylate), and thermodynamic models are presented as guidance for matching targets with scavenging agent.
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