Invention Grant
- Patent Title: Liquid containing polymer marker, use of a polymer marker as authentication tool, and method and device for detecting a polymer marker dissolved in a liquid
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Application No.: US15509680Application Date: 2015-09-25
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Publication No.: US10308869B2Publication Date: 2019-06-04
- Inventor: Mia Milos-Schouwink , Agnieszka Kapalka , Jean-Luc Dorier , Lorenzo Sirigu , Lucia Giovanola , Paolo Schina , Silvia Baldi , Irma Disegna , Silvano Tori
- Applicant: SICPA HOLDING SA
- Applicant Address: CH Prilly
- Assignee: SICPA HOLDING SA
- Current Assignee: SICPA HOLDING SA
- Current Assignee Address: CH Prilly
- Agency: Muncy, Geissler, Olds & Lowe, P.C.
- Priority: EP14187173 20140930
- International Application: PCT/EP2015/072110 WO 20150925
- International Announcement: WO2016/050637 WO 20160407
- Main IPC: C09K11/06
- IPC: C09K11/06 ; G01N21/76 ; G01N1/18 ; G01N1/00 ; C10L1/00 ; C10L1/16 ; G01N21/64 ; B01L3/00 ; G01N1/40 ; G01N33/28 ; G01N35/10 ; G01N35/00

Abstract:
The present invention relates to markers for liquids that can be used to authenticate the origin and genuineness of a liquid, preferably a bulk liquid such as fuel. For this purpose, the present invention teaches the use of a polymer capable of forming a semiconducting polymer particle (pdot) in the liquid in small amounts. The invention encompasses a liquid comprising a) a polymer that is capable of forming a semiconducting polymer particle (pdot), the concentration of the polymer being 10 ppm by weight or less, and b) an organic substance in an amount of 90% by weight or more. The invention furthermore envisages the use of such a polymer as an authenticating marker in a liquid, preferably a fuel, and a method for authenticating the genuineness and/or origin of a liquid comprising a polymer capable of forming a semiconducting polymer particle (pdot), comprising the steps i. concentrating, isolating and/or extracting the polymer capable of forming a semiconducting polymer particle (pdot); ii. aggregating the polymer or the polymer obtained in Step i. to form semiconducting polymer dots (pdots); iii. irradiating the formed pdots with electromagnetic radiation capable of exciting the pdots to emit electromagnetic radiation by fluorescence and/or phosphorescence, and iv. observing the electromagnetic radiation emitted in response to the exciting irradiation of step iii.
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