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CN1396843A 模制催化剂、制造模制催化剂的方法及制造环氧乙烷化合物的方法 失效 - 权利终止

模制催化剂、制造模制催化剂的方法及制造环氧乙烷化合物的方法
摘要：
一种满足以下全部条件(1)－(4)的含钛氧化硅模制催化剂。(1)平均孔径等于10或更大；(2)全部孔体积的90％或更多具有5－200的孔径；(3)比孔体积为0.2cm3/g或更大；及(4)通过使用满足下面通式(I)：[NR1R2R3R4]+的季铵或通式(II)：NR5R6R7的胺作为模板，然后从所得到的模制物中移走所述模板而制得模制催化剂，在所述式(I)中，R1代表具有2－36个碳原子的直链或支链烃基，及R2到R4代表具有1－6个碳原子的烷基。在式(II)中，R5代表具有2－36个碳原子的直链或支链烃基，及R6和R7代表氢或具有1－6个碳原子的烷基。
摘要（英）：

A titanium-containing silicon oxide molded catalyst satisfying all of the following conditions (1) to (4): (1) an average pore diameter is 10 ANGSTROM or more, (2) 90% or more of the whole pore volume have pore diameters of 5 to 200 ANGSTROM , (3) a specific pore volume is 0.2 cm<3>/g or more, and (4) it is obtained by using as a template a quaternary ammonium ion of the following general formula (I) or an amine of the following general formula (II), then, removing the template. ÄNR<1>R<2>R<3>R<4>Ü<+> (in the formula (I), R<1> represents a linear or branched hydrocarbon group having 2 to 36 carbon atoms, and R<2> to R<4> represent an alkyl group having 1 to 6 carbon atoms.) NR<5>R<6>R<7> (in the formula (II), R<5> represents a linear or branched hydrocarbon group having 2 to 36 carbon atoms, and R<6> and R<7> represent hydrogen or an alkyl group having 1 to 6 carbon atoms.).

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