The invention discloses a rapid curing type silicone structural adhesive and application. The structural adhesive is composed of a component A and a component B. The component A includes hydroxyl-terminated polydimethylsiloxane and inorganic filler, and the component B includes a coupling agent and a catalyst. Compared with a traditional silicone structure, the prepared silicone structural adhesive has the higher curing speed and short snapping and surface drying time, is applied to adhesion between materials such as glass, aluminum sectional materials, stainless steel and glass fiber reinforced plastics in photovoltaic assemblies and vehicles, and can greatly shorten the positioning and maintenance time, accelerate the technological process and improve the technological efficiency.