The invention relates to an ADC (azodicarbonamide) chlorine oxidation process with a self-priming stirring function. A self-priming hollow turbine agitator with a hollow turbine self-priming stirring paddle is arranged in a reaction kettle; more than one hollow stirring paddle is arranged on the upper part of the agitator; chlorine oxidation biurea is introduced by a gas inlet pipe; chlorine is sucked to a cavity of the self-priming hollow turbine agitator and is completely mixed with liquid; the escaped gas diffuses upward and is absorbed to the cavity by the hollow stirring paddle 2 on the upper part so as to continue to react with the liquid; the biurea and the chlorine are added in the self-priming reaction kettle at a molar ratio of 1:1-1.5; the reaction conditions are as follows: the reaction temperature is 106 DEG C, the reaction time is 4-6h, and the rotation speed is 400-500rmp. The ADC chlorine oxidation process has the beneficial effects that (1) the self-priming stirring reaction kettle is used for generating ADC foaming agent, so that the utilization rate of the chlorine is increased, the energy source is efficiently saved and the cost is lowered, and (2) the self-priming stirring reaction kettle is adopted, so that the reaction is easily operated and controlled and a product having a single crystal shape is obtained.