公开(公告)号：US06833467B2

公开(公告)日：2004-12-21

申请号：US10291389

申请日：2002-11-12

申请人： Chong Ma ,  Wen-Yo Chen ,  Yuen-Hsin Peng

发明人： Chong Ma ,  Wen-Yo Chen ,  Yuen-Hsin Peng

IPC分类号： C07F96571

CPC分类号： C07F9/657145

摘要： Mechanochemical synthesis of pentaerythritol phosphate alcohol is disclosed. The synthesis is carried out by ball milling a mixture containing P2O5, pentaerythritol, an alkyl benzene having one or two C1-C5 alkyl groups, and a metal halide catalyst, in a ball mill as a reactor and at a temperature of 70-150° C.

公开(公告)号：US06455722B1

公开(公告)日：2002-09-24

申请号：US09896710

申请日：2001-06-29

申请人： Frederick J. Vyverberg ,  Robert W. Chapman

发明人： Frederick J. Vyverberg ,  Robert W. Chapman

IPC分类号： C07F96571

CPC分类号： C07F9/65748

摘要： A process for the production of pentaerythritol phosphate alcohol (PEPA) comprising reacting in the liquid phase phosphorus oxychloride (POCl3) with pentaerythritol (PE) at a reaction temperature of at least about 100° C. in the presence of a solvent which is an alkane substituted with at least one halogen atom and having an atmospheric boiling point of about 40 to about 150° C., e.g., 1,2-dichloroethane (ethylene dichloride). The reaction pressure is sufficiently high to maintain the solvent in the liquid phase.

摘要翻译： 一种制备季戊四醇磷酸酯（PEPA）的方法，包括在液相中的磷酰氯（POCl 3）与季戊四醇（PE）在至少约100℃的反应温度下，在溶剂为烷烃的条件下 被至少一个卤素原子取代并具有约40至约150℃的常压沸点，例如1,2-二氯乙烷（二氯乙烷）。 反应压力足够高以使溶剂保持在液相中。

公开(公告)号：US06355833B1

公开(公告)日：2002-03-12

申请号：US09782762

申请日：2001-02-14

申请人： Jakob Fischer ,  Wolfgang Siegel

发明人： Jakob Fischer ,  Wolfgang Siegel

IPC分类号： C07F96571

摘要： A catalyst comprising at least one nickel(O) complex which comprises at least one mono-, bi- or multidentate phosphonite ligand of the formula I or salts and mixtures thereof, is prepared as described, and the catalysts are used to prepare mixtures of monoolefinic C5 mononitriles with nonconjugated C═C and C≡N bonds by catalytic hydrocyanation of butadiene or of a 1,3-butadiene-containing hydrocarbon mixture in the presence of a catalyst of this type.